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Dive into the research topics where Eduardo J. Nassar is active.

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Featured researches published by Eduardo J. Nassar.


Journal of Colloid and Interface Science | 2010

New synthesis strategies for effective functionalization of kaolinite and saponite with silylating agents

Lilian R. Avila; Emerson H. de Faria; Katia J. Ciuffi; Eduardo J. Nassar; Paulo S. Calefi; Miguel A. Vicente; Raquel Trujillano

Functionalization of Brazilian São Simão kaolinite and Spanish Yunclillos saponite with the alkoxysilanes 3-aminopropyltriethoxysilane and 3-mercaptopropyltrimethoxysilane is reported. The resulting hybrids were characterized by X-ray diffraction, thermal analysis, infrared absorption spectroscopy, and scanning electron microscopy, which demonstrated the effectiveness of the interlamellar grafting process. The X-ray diffractograms revealed incorporation of the alkoxide molecules into the interlayer space of the clays. The displacement of the stretching bands of interlayer hydroxyls in the infrared spectra of the modified kaolinites and the increased intensity of the Mg-OH vibrations in the spectra of the modified saponites confirmed the functionalization of the clays. The thermal behavior of the organoclays confirmed the stability of the hybrids, which was dependent on the clay used for preparation of the materials.


ACS Applied Materials & Interfaces | 2009

Porphyrin-kaolinite as efficient catalyst for oxidation reactions.

Natalia Bizaia; Emerson H. de Faria; Gustavo P. Ricci; Paulo S. Calefi; Eduardo J. Nassar; Kelly A. D. F. Castro; Shirley Nakagaki; Katia J. Ciuffi; Raquel Trujillano; Miguel A. Vicente; Antonio Gil; S.A. Korili

The preparation, characterization, and application in oxidation reactions of new biomimetic catalysts are reported. Brazilian Sao Simao kaolinite clay has been functionalized with [meso-tetrakis(pentafluorophenyl)porphinato]iron(III), Fe(TPFPP). To obtain the functionalized clay, the natural clay was purified by dispersion-sedimentation, expanded by insertion of dimethyl sulfoxide (DMSO), and functionalized with amino groups by substitution of DMSO with ethanolamine. These previous steps allowed clay functionalization with Fe(TPFPP), leading to a layered material with a basal spacing of 10.73 A. Clay functionalization with the porphyrin was confirmed by formation of the secondary amine, as demonstrated by FTIR bands at 3500-3700 cm(-1). UV-vis spectroscopy revealed a red shift in the Soret band of the iron porphyrin in the functionalized material as compared to the parent iron porphyrin catalyst in solution, indicating Fe(III)P --> Fe(II)P reduction. The catalytic performance of the functionalized clay was evaluated in the epoxidation of cyclooctene, with complete selectivity for the epoxide (100% epoxide yield), and ketonization of cyclohexane, cyclohexanone being the major product. The novel catalyst was also evaluated in the Baeyer-Villiger (BV) oxidation of cyclohexanone, with 85% conversion of cyclohexanone in epsilon-caprolactone, with total selectivity to epsilon-caprolactone.


ACS Applied Materials & Interfaces | 2011

New highly luminescent hybrid materials: terbium pyridine-picolinate covalently grafted on kaolinite.

Emerson H. de Faria; Eduardo J. Nassar; Katia J. Ciuffi; Miguel A. Vicente; Raquel Trujillano; V. Rives; Paulo S. Calefi

Luminescent hybrid materials derived from kaolinite appear as promising materials for optical applications due to their specific properties. The spectroscopic behavior of terbium picolinate complexes covalently grafted on kaolinite and the influence of the secondary ligand and thermal treatment on luminescence are reported. The resulting materials were characterized by thermal analysis, element analysis, X-ray diffraction, infrared absorption spectroscopy, and photoluminescence. The thermogravimetric curves indicated an enhancement in the thermal stability up to 300 °C for the lanthanide complexes covalently grafted on kaolinite, with respect to the isolated complexes. The increase in the basal spacing observed by X-ray diffraction confirmed the insertion of the organic ligands into the basal space of kaolinite, involving the formation of a bond between Al-OH and the carboxylate groups, as evidenced by infrared spectroscopy. The luminescent hybrid material exhibited a stronger characteristic emission of Tb(3+) compared to the isolated complex. The excitation spectra displayed a broad band at 277 nm, assigned to a ligand-to-metal charge transfer, while the emission spectra presented bands related to the electronic transitions characteristic of the Tb(3+) ion from the excited state (5)D(4) to the states (7)F(J) (J=5, 4, and 3), with the 4→5 transition having high intensity with green emission.


Journal of Colloid and Interface Science | 2009

Hybrid materials prepared by interlayer functionalization of kaolinite with pyridine-carboxylic acids

Emerson H. de Faria; Omar J. de Lima; Katia J. Ciuffi; Eduardo J. Nassar; Miguel A. Vicente; Raquel Trujillano; Paulo S. Calefi

This paper presents the results of the functionalization of Brazilian São Simão kaolinite with pyridine-2-carboxylic and pyridine-2,6-dicarboxylic acids. The functionalization involved refluxing of the pyridine-carboxylic acid in the presence of kaolinite previously intercalated with dimethyl sulfoxide; both acids effectively displaced dimethyl sulfoxide from the clay interlayer. The resulting materials were characterized by X-ray diffraction, thermal analysis, infrared absorption spectroscopy, and C and N elemental analysis. The X-ray diffractograms revealed the incorporation of the acid molecules into the interlayer space of kaolinite. The thermogravimetric curves of the kaolinite samples functionalized with the pyridine-carboxylic acids indicated that the materials were thermally stable up to 300 degrees C. The displacements of the bands due to interlayer hydroxyls in the infrared absorption spectra also confirmed the functionalization of the kaolinite with the pyridine-carboxylic acids.


Journal of Alloys and Compounds | 2002

Titania-based organic-inorganic hybrid planar waveguides

Eduardo J. Nassar; Rogéria Rocha Gonçalves; M. Ferrari; Younes Messaddeq; Sidney José Lima Ribeiro

Abstract Eu 3+ -doped titania–silica planar waveguides were prepared from tetraethylorthotitanate (TEOT) and modified silane 3-aminopropyltriethoxysilane (APTS). Films were deposited on borosilicate glass substrates by a dip-coating technique. The refractive index, the thickness and the total attenuation coefficient of the waveguides were measured at 632.8 and 1550 nm by prism coupling technique. Starting from pure titania films, the addition of modified silane leads to a decrease in the refractive index and an increase in thickness. Squared electric field simulation has shown that the light confinement in the waveguide increases with the silane content of the sol. Emission spectra present a broad emission band due to the modified silane and Eu 3+ emission transitions arising mainly from the 5 D 0 level to the 7 F J ( J =0–4) manifolds. The dependence of transition intensities and excited state lifetimes on the initial composition and also on the heat treatment performed was interpreted in terms of structural changes occurring during the preparation process.


Materials Research-ibero-american Journal of Materials | 2003

Europium incorporated in silica matrix obtained by sol-gel: luminescent materials

Eduardo J. Nassar; Katia J. Ciuffi; Sidney José Lima Ribeiro; Younes Messaddeq

In this work we report some aspects of the chemistry involved in the preparation of modified silicon oxide by the sol-gel process. Europium III compounds were used as luminescent probe. An organic-inorganic hybrid was obtained by hydrolysis of tetraethylorthosilicate (TEOS) and 3-aminopropyltriethoxysilane (APTS). The Eu III compounds were added in different ways. In the first, silica was prepared in the presence of Eu III, and in the second, Eu III was added on the silica surface. These materials were studied by luminescence, infrared spectroscopy and termogravimetric analysis. The results obtained for the hybrid material show different behavior for Eu III emission, which could be excited by the antenna effect and the influence of the surrounding in the luminescence quenching. The thermogravimetric data present different mass loss in samples to range temperature 50 - 150 °C. Thermogravimetric and infrared spectra showed that inorganic polymers incorporated the organic part.


Química Nova | 2002

Influência da catálise ácida e básica na preparação da sílica funcionalizada pelo método sol-gel

Eduardo J. Nassar; Younes Messaddeq; Sidney José Lima Ribeiro

Some aspects of the chemistry involved in the preparation and characterization of functionalized silicon oxide by sol-gel method are considered in this work. The synthesis was performed with different silicon alcoxide precursors and the influence of the acid and basic catalyst was investigated. Characterization was performed by infrared absorption spectroscopy, elemental analysis and 29Si NMR. Infrared data show Si-C and -CH2- vibrational modes at 1250 to 1280 and 2920 to 2940 cm-1, respectively. The elemental analysis confirmed the presence of organic groups in the inorganic silica network. 29Si NMR results show different hydrolisys depending on the acid or base catalysis.


Química Nova | 2011

Estudo das condições de estocagem do bagaço de cana-de-açúcar por análise térmica

Moacyr L. dos Santos; Omar J. de Lima; Eduardo J. Nassar; Katia J. Ciuffi; Paulo S. Calefi

An evaluation was made of the properties of sugarcane bagasse during the storage process for subsequent burning in a boiler. Samples of bagasse were collected over a period of 150 days from the Caete sugar mill (MG) at various points of the stockpile soon after the sugarcane was pressed to extract its juice, as well as from natural bagasse, dry and damp. Thermal analyses of the samples were carried out and the results indicated that, during the storage of bagasse, dry or damp, the biomass loses up to 32% of its calorific power, due to decomposition of the hemicellulose.


ACS Applied Materials & Interfaces | 2015

Organically Modified Saponites: SAXS Study of Swelling and Application in Caffeine Removal

Liziane Marçal; Emerson H. de Faria; Eduardo J. Nassar; Raquel Trujillano; Nuria Martín; Miguel A. Vicente; V. Rives; Antonio Gil; S.A. Korili; Katia J. Ciuffi

This study aimed to assess the capacity of saponite modified with n-hexadecyltrimethylammonium bromide (CTAB) and/or 3-aminopropyltriethoxysilane (APTS) to adsorb and remove caffeine from aqueous solutions. Powder X-ray diffraction (PXRD) revealed increased basal spacing in the modified saponites. Small-angle X-ray scattering (SAXS) confirmed the PXRD results; it also showed how the different clay layers were stacked and provided information on the swelling of natural saponite and of the saponites functionalized with CTAB and/or APTS. Thermal analyses, infrared spectroscopy, scanning electron microscopy, element chemical analysis, and textural analyses confirmed functionalization of the natural saponite. The maximum adsorption capacity at equilibrium was 80.54 mg/g, indicating that the saponite modified with 3-aminopropyltriethoxysilane constitutes an efficient and suitable caffeine adsorbent.


Polymer Chemistry | 2013

Tri-ureasil gel as a multifunctional organic–inorganic hybrid matrix

Eduardo F. Molina; Liziane Marçal; Hudson W.P. Carvalho; Eduardo J. Nassar; Katia J. Ciuffi

We report on a novel transparent, flexible, rubbery, and insoluble tri-ureasil organic–inorganic hybrid material with multifunctional characteristics and potential application in drug delivery, water purification, and photochromic materials. We obtained the tri-ureasil gels by the one-pot sol–gel route using 3-isocyanatopropyltriethoxysilane and glyceryl poly(oxypropylene)triamine of molecular weight 5000 g mol−1 (Jeffamine® T5000). This approach generated a silica backbone covalently connected with poly(oxyalkylene) chains PPO(OCH–CH3CH2)n through urea bridges. We characterized the obtained materials by DSC, swelling tests, XRD, 29Si NMR, and small-angle X-ray scattering (SAXS). The results attested that the tri-ureasil hybrids are potentially applicable as photochromic devices, drug delivery systems, and adsorbents of pollutants from contaminated waters.

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Paula F. S. Pereira

Federal University of São Carlos

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S.A. Korili

Universidad Pública de Navarra

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V. Rives

University of Salamanca

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