Edward A. Cherney

Chemical changes at the surface of RTV silicone rubber coatings on insulators during dry-band arcing

Under wet and contaminated conditions dry band arcing occurs on the surface of HV outdoor insulators coated with room temperature vulcanizing (RTV) silicone rubber. The thermal impact of the arcing on the surface of the RTV causes chemical changes. The gradual loss of hydrophobicity due to dry band arcing is of considerable concern because it results in a reduction of the withstand voltage and subsequent failure of the insulator and power outage. In this study the RTV coatings were subjected simultaneously to salt-fog and electrical stress. Attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy and electron spectroscopy for chemical analysis (ESCA) were then employed to investigate the chemical changes. Possible chemical reactions and processes occurring under dry band arcing are suggested. The results of ATR-FTIR and ESCA indicate the formation of low molecular weight polydimethylsiloxane (PDMS), the reduction in the surface density of CH3 groups and crosslinking of the PDMS backbone chains at the surface. Chemical derivative analysis was also carried out to further elucidate the chemical changes on the surface of RTV coating. >

Fundamental and low frequency harmonic components of leakage current as a diagnostic tool to study aging of RTV and HTV silicone rubber in salt-fog

The paper presents the results of using the fundamental and the low frequency harmonic components of leakage current to study aging of silicone rubber in salt-fog. Experiments have been conducted on RTV and HTV coated rods at different fields (0.25-0.6 kV/cm) and conductivities (1000 to 2500 /spl mu/S/cm). The onset of dry-band arcing on samples could be determined by measuring the low frequency harmonic components. A correlation has been found between the fundamental and low harmonic components of leakage current and different forms of aging. Where erosion could be associated with an increase in the level of both the fundamental and low frequency harmonic components of leakage current. For example, surface damage for HTV rods occurred when the fundamental component of leakage current was greater than 2 mA. On the other hand, when the samples approached failure, the fundamental component of leakage current reached relatively high values ( > 6 mA for HTV rods and > 2 mA for RTV rods) and the low frequency harmonic components of the leakage current tended to decrease. The results suggest that both the fundamental and low frequency harmonics of leakage current can be used as a tool to determine both the beginning of aging and end of life of silicone rubber in salt-fog.

The role of inorganic fillers in silicone rubber for outdoor insulation alumina tri-hydrate or silica

A systematic study to understand how alumina tri-hydrate (ATH) and silica fillers improve the erosion resistance of silicone rubber during dry band arcing showed that the thermal conductivity of the resulting composite material is the main criterion governing material erosion. The thermal conductivity of the composite material is dependent on the thermal conductivity, concentration, particle size, and bonding of the filler particles to the silicone matrix. In this context, either filler can be shown to perform better than the other, depending on the formulation, in the ASTM inclined plane tracking and erosion test. Therefore, the industry perception that ATH filler imports better erosion resistance than silica in silicone rubber can be misleading. The release of water of hydration from ATH appears to have a secondary effect that may be more relevant in silicone compositions having a low concentration of a filler.

Erosion resistance of nano-filled silicone rubber

The paper presents the experimental results obtained on the erosion resistance of silicone rubber (SIR) filled with 12 nm size fumed silica (nano filler) to those filled with 5 /spl mu/m size silica filler (micro filler). The ASTM 2303 inclined plane tracking and erosion test was used in the comparison as well as an infrared laser as the source of heat to erode the SIR samples. The erosion resistance of the SIR materials increased with increasing percentage of the fillers, and it was observed that 10% by weight of nano-filled SIR gives a performance that is similar to that obtained with 50% by weight of micro-filled SIR. The low frequency components of leakage current and the eroded mass are used to evaluate the relative erosion resistance of the composites and the third harmonic component of the leakage current shows good correlation to the measured eroded mass. The paper discusses the possible reasons for the improvement in the erosion resistance of nano-filled silicone composites.

Electric Fields on AC Composite Transmission Line Insulators

This paper provides an overview of the electric field (E-field) distribution on transmission line composite insulators applied in alternating current applications. Factors that affect the E-field distribution are discussed as well as the influence of the E-field distribution on the short and long term performance. Modeling and measurement methods are reported and examples of calculated E-field magnitudes determined are presented together with corona ring application information. This paper was developed by the IEEE Task force on electric fields and composite insulators.

Thermal conductivity of filled silicone rubber and its relationship to erosion resistance in the inclined plane test

Silicone rubber samples having various concentrations and mean particle sizes of either alumina tri-hydrate or silica filters, prepared by room temperature and heat cured under pressure (hot pressed), are tested for erosion resistance in the ASTM D2303 inclined plane tracking and erosion test. Their corresponding thermal conductivities are determined using a transient temperature technique in which an infrared laser is employed as the heat source and a thermal imaging camera as a temperature detection device. Scanning electron microscope observations show greater filler bonding to the silicone matrix in the hot pressed samples than in the room temperature vulcanized samples leading higher thermal conductivity and increased resistance to erosion, for both ATH and silica filled samples. The correlation study shows a strong relationship between the erosion resistance and the thermal conductivity of the tested samples, highlighting the importance of an outdoor insulating material to have high thermal conductivity in order to withstand dry band arcing. The results can be used to provide guidance on filler selection for silicone rubber compounding for outdoor insulation applications.

Silicone rubber dielectrics modified by inorganic fillers for outdoor high voltage insulation applications

The paper discusses the mechanisms by which inorganic fillers in silicone rubber dielectrics enhance the properties of thermal conductivity, relative permittivity, and electrical conductivity making them useful in outdoor high voltage insulation applications. The addition of alumina trihydrate or silica fillers to silicone elastomers, forming binary composites with enhanced thermal conductivity, is discussed in relation to filler type, particle size, shape, and concentration, and its use as a housing material for non-ceramic insulators to minimize material erosion at dry band arcing sites by lowering hot spot temperature. Also discussed is the enhanced relative permittivity of silicone dielectrics that is obtained through the addition of barium titanate powder which can be further increased with the addition of aluminium powder forming a tertiary composite, resulting in a significant grading of the surface electric field when applied as a housing material to high voltage bushings. Controlled electrical conductivity of silicone dielectrics is discussed through the use of antimony-doped tin oxide filler binary composites and when applied as a housing material to outdoor bushings, the pollution performance is greatly enhanced.

A study of partial discharges from water droplets on a silicone rubber insulating surface

This paper presents measurements of partial discharge (PD) from water droplets on a silicone rubber insulating surface in an ac field. Tests are done by placing droplets on the surface using a micro-pipette, and by condensing water in a controlled humidity chamber. The field enhancement factor due to droplets placed on the insulation surface is experimentally and numerically determined. Values in the range of 3.8 to 6.3 are obtained depending on the size and number of droplets. The time resolved analysis of PD from water condensation indicates a threshold field, between 3.0 and 3.5 kV/cm, above which the PD activity increases with time, and brings the insulation to a surface breakdown. The corresponding field enhancement factor obtained for the condensation experiments is between 5.8 and 6.8. The results therefore suggest that the PD activity on the hydrophobic surface can be used effectively to learn about the insulation surface conditions.

Impact of inverter drives employing fast-switching devices on form-wound AC machine stator coil stress grading

The conventional stress-grading system of form-wound motor coils has been found to perform well under sinusoidal, power-frequency voltage. However, when the motor is fed by inverter-based drives employing fast switching, a significant impact on the electric stress-grading system occurs. Simulations of the stress-grading systems using finite element analysis indicate that, during the fast rise-time, a high electric stress can develop right at the slot exit of the stator if the conductivity of the conductive armor tape (CAT) is not high enough. Increasing the conductivity of the CAT alleviates the problem but increases the eddy current loss in the stator laminations. To address this problem, the conductivity of the area just beyond the slot exit needs to be increased by coating the surface of the CAT with a high-conductive material. The stress-grading at the end of this conductive paint section then is achieved by two coordinated layers, which help to distribute the electric field and heat that is produced

Effectiveness of stress grading coatings on form wound stator coil groundwall insulation under fast rise time pulse voltages

In this paper, the effectiveness of stress grading coatings (SGCs) on form wound stator coil groundwall insulation under fast rise time pulses is analyzed. The combined performance of the stress grading coating and the semiconductive slot coating is studied under fast rise time transient voltages. During the rapid rise of voltage, the high stress moves from the stress grading coating to the semiconductive coating at the end of the slot. According to the results, it is evident that the design of both the stress grading and semiconductive slot coatings must be done together for effective stress relief. The use of materials with varistor behavior in the stress grading coating, combined with a high conductivity semiconductive slot coating, is analyzed as a solution to the high stress that develops at the slot end of form wound stator coil groundwall insulation of inverter fed drive (IFD) motors.