Effaliza Misran

Photocatalytic magnetic separable beads for chromium (VI) reduction

Magnetically separable photocatalyst beads containing nano-sized iron oxide in alginate polymer were prepared. This magnetic photocatalyst beads are used in slurry-type reactors. The magnetism of the catalyst arises from the nanostructured particles gamma-Fe(2)O(3), by which the catalyst can be easily recovered by the application of an external magnetic field. These synthesized beads are sunlight-driven photocatalyst. In the system without magnetic photocatalyst beads, no chromium reduction was observed under sunlight irradiation due to the stability of the chromium (VI). Upon the addition of magnetic photocatalyst beads, the photo-reduction of Cr(VI) was completed in just after only 50min under sunlight irradiation due to the photocatalytic activity of the beads. However when placed away from sunlight, the reduction rate of the chromium is just about 10%. These observations were explained in terms of absorption occurrence of chromium (VI) onto the catalyst surface which took place in this reaction. In addition, photo-reduction rate of chromium (VI) was more significant at lower pH. The results suggest that the use of magnetic separable photocatalyst beads is a feasible strategy for eliminating Cr(VI).

Modified PVA-alginate encapsulated photocatalyst ferro photo gels for Cr(VI) reduction.

In this study magnetic separable photocatalyst beads containing maghemite nanoparticles (γ-Fe(2)O(3)) in polyvinyl alcohol (PVA) polymer were prepared and used in the reduction of Cr(VI) to Cr(III) in an aqueous solution under sunlight. The unique superparamagnetic property of the photocatalyst contributed by the γ-Fe(2)O(3) and robust property of PVA polymer allow the magnetic beads to be recovered easily and reused for at least 7 times without washing. The concentration of γ-Fe(2)O(3) was varied from 8% (v/v) to 27% (v/v) and the results revealed that the beads with 8% (v/v) γ-Fe(2)O(3) exhibited the best performance where Cr(VI) was reduced to Cr(III) in only 30 min under sunlight. The use of the PVA has improved the bead properties and life cycle of beads which is in line with sustainable practices.

Development of highly porous biodegradable γ-Fe2O3/polyvinyl alcohol nanofiber mats using electrospinning process for biomedical application

The use of electrospinning process in fabricating tissue engineering scaffolds has received great attention in recent years due to its simplicity. The nanofibers produced via electrospinning possessed morphological characteristics similar to extracellular matrix of most tissue components. Porosity plays a vital role in developing tissue engineering scaffolds because it influences the biocompatibility performance of the scaffolds. In this study, maghemite (γ-Fe2O3) was mixed with polyvinyl alcohol (PVA) and subsequently electrospun to produce nanofibers. Five factors; nanoparticles content, voltage, flow rate, spinning distance, and rotating speed were varied to produce the electrospun nanofibrous mats with high porosity value. Empirical model was developed using response surface methodology to analyze the effect of these factors to the porosity. The results revealed that the optimum porosity (90.85%) was obtained using 5% w/v nanoparticle content, 35kV of voltage, 1.1ml/h volume flow rate of solution, 8cm spinning distance and 2455rpm of rotating speed. The empirical model was verified successfully by performing confirmation experiments. The properties of optimum PVA/γ-Fe2O3 nanofiber mats such as fiber diameter, mechanical properties, and contact angle were investigated. In addition, cytocompatibility test, in vitro degradation rate, and MTT assay were also performed. Results revealed that high porosity biodegradable γ-Fe2O3/polyvinyl alcohol nanofiber mats have low mechanical properties but good degradation rates and cytocompatibility properties. Thus, they are suitable for low load bearing biomedical application or soft tissue engineering scaffold.

Enhanced Removal of Cu(II) by Photocatalytic Reduction Using Maghemite PVA-Alginate Separable Beads: Kinetic and Equilibrium Studies

The feasibility of Cu(II) removal by photoreduction using maghemite polyvinylalcohol-alginate beads was investigated. Photoreduction experiments were performed to investigate the influence of initial concentration and pH on the removal of copper(II) metallic ions. The fate of Cu(II) during the photoreduction process was investigated using the X-ray photoelectron spectroscopy. It was observed that the Cu(II) removal rate was faster under sunlight than without sunlight due to the reduction process of Cu(II) to Cu(I). The photoreduction results showed that the adsorption of Cu(II) ions followed a Langmuir Hinshelwood model with the photoreduction rate constant and adsorption coefficient values of 24.1 ppm/min and 0.0098 ppm−1, respectively.

Effect of PAO-Based γ-Fe2O3 and Surfactant Concentration on Viscosity Characteristic

This is a preliminary study on the viscosity characteristics of polyalphaolefin (PAO)-based γ-Fe2O3 under zero magnetic fields. By varying the concentration of magnetic nanoparticles (MNPs), PAO-based γ-Fe2O3 with different concentrations were synthesized by co-precipitation method. The effect of this factor on the viscosity characteristic of γ-Fe2O3 (< 30 nm) was investigated on the basic of a series of rheological measurement. The use of oleic acid (OA) as a coating agent and surfactant was also investigated by varying its concentration. The results show the concentration of MNPs and the amount of OA has obvious effect on viscosity characteristics of PAO-based γ-Fe2O3. In the case of comparison between the concentrations of MNPs, higher concentration of MNPs increased the viscosity of the PAO-based γ-Fe2O3 and exhibit nearly Newtonian behavior. The large amount of OA also exhibits the increment on viscosity characteristic of MNPs. The experimental data were compared with the Bingham and Casson model and the results revealed that the rheology of the polyalphaolefin (PAO)-based γ-Fe2O3 fitted the Casson model better.