Elizabeth H. Griffith

The adamantane structure in polynuclear Cu4S6 cores: the crystal and molecular structures of Cu4[SC(NH2)2]6(NO3)4·4H2O and Cu4[SC(NH2)2]9(NO3)4·4H2O

The compounds Cu4[SC(NH2)2]6(NO3)4·4H2O and Cu4[SC(NH2)2]9(NO3)4·4H2O have been prepared, their structures determined, and are shown to contain a central Cu4S6 core with four trigonal planar Cu atoms in the former, but only one trigonal planar Cu in the latter.

Crystal structure and 48113Cd n.m.r. spectrum of di-µ-chloro-dichlorobis-(6-mercaptopurine)diaquodicadmium(II)

The 113Cd n.m.r. spectrum of di-µ-chloro-dichlorobis-(6-mercaptopurine)diaquodicadmium(II) has been observed and the crystal structure determined to consist of dimers with relatively long Cd–S and Cd–N(7) distances.

X-Ray crystal structure and 113Cd n.m.r. spectrum of αβγδ-tetraphenyl-porphinatocadmium(II)-bis(dioxan) solvate

The 113Cd Fourier transform n.m.r. spectrum of the title compound is characterized by a single resonance at ca. 422 p.p.m. deshielded from 0·1 M CdClO4 solution; its crystal structure shows an almost planar CdN4 system with only very weak axial interactions to dioxan molecules.

The crystal and molecular structure of dinitratobis(2- methylmercaptoaniline)Cd(II) monohydrate: A trigonal bipyramidal Cd SN2O2 polyhedron wit

Abstract The single crystal X-ray structure determination of dinitratobis-(2-methylmercaptoaniline) has been carried out. The structure consists of neutral mole

Crystal and molecular structure of K2(PdCl3)2·4(1-propylthymine)

The crystal and molecular structure of an unusual complex between K2PdCl4 and 1-propylthymine, [K2Pd2Cl6·4(1-propylthymine)], has been determined by X-ray diffraction and shown to contain the structural features of Watson–Crick base stacking, significant hydrogen bonding, K+⋯ O interactions connecting the bases, and a Pd2Cl62– dimer.

A six-membered Cu3S3 ring in decakis(thiourea)tetracopper(I) hexafluorosilicate monohydrate: X-ray crystallographic structure determination

The crystal structure of Cu4[SC(NH2)2]10-(SiF6)2,H2O has been determined and found to consist of six-membered rings of alternating Cu and S atoms connected by sulphur bridges to form chains, which are in turn interconnected via a Cu2S2 four-membered ring to form a three-dimensional polymer.

Reaction of PtCl42– with theophylline: X-ray crystal structures of bis(theophyllinium) tetrachloroplatinate(II) and theophyllinium trichlorotheophyllineplatinate(II)

The crystal structures of bis(theophyllinium) tetrachloroplatinate(II)(A) and theophyllinium trichlorotheophyllineplatinate(II)(B) have been determined; the PtII atom is bound to N(9) in the complex (B).