Elza Kovács

Assessing element distribution and speciation in a stream at abandoned Pb–Zn mining site by combining classical, in-situ DGT and modelling approaches

The distribution and speciation of elements along a stream subjected to neutralised acid mine drainage (NAMD) effluent waters (Mátra Mountain, Hungary; Toka stream) were studied by a multi-methodological approach: dissolved and particulate fractions of elements were determined by HR-ICPMS, whereas speciation was carried out by DGT, supported by speciation modelling performed by Visual MINTEQ. Before the NAMD discharge, the Toka is considered as a pristine stream, with averages of dissolved concentrations of elements lower than world averages. A considerable increase of element concentrations caused by effluent water inflow is followed by a sharp or gradual concentration decrease. A large difference between total and dissolved concentrations was found for Fe, Al, Pb, Cu, Zn and As in effluent water and at the first downstream site, with high correlation factors between elements in particulate fraction, indicating their common behaviour, governed by the formation of ferri(hydr)oxides (co)precipitates. In-situ speciation by the DGT technique revealed that Zn, Cd, Ni, Co, Mn and U were predominantly present as a labile, potentially bioavailable fraction (>90%). The formation of strong complexes with dissolved organic matter (DOM) resulted in a relatively low DGT-labile concentration of Cu (42%), while low DGT-labile concentrations of Fe (5%) and Pb (12%) were presumably caused by their existence in colloidal (particulate) fraction which is not accessible to DGT. Except for Fe and Pb, a very good agreement between DGT-labile concentrations and those predicted by the applied speciation model was obtained, with an average correlation factor of 0.96. This study showed that the in-situ DGT technique in combination with model-predicted speciation and classical analysis of samples could provide a reasonable set of data for the assessment of the water quality status (WQS), as well as for the more general study of overall behaviour of the elements in natural waters subjected to high element loads.

Vegetation Pattern and Heavy Metal Accumulation at a Mine Tailing at Gyöngyösoroszi, Hungary

Abstract Vegetation at an abandoned heavy metal bearing mine tailing may have multifunctional roles such as modification of water balance, erosion control and landscape rehabilitation. Research on the vegetation of mine tailings can provide useful information on tolerance, accumulation and translocation properties of species potentially applicable at moderately contaminated sites. Analyses of the relationship between heavy metal content (Pb, Zn and Cu) and vegetation in a mine tailing were carried out. These analyses included: (1) spatial analysis of relationship among heavy metal distribution, pH and vegetation patterns, and (2) analysis of heavy metal accumulation and translocation in some plant species. Presence of vegetation was found to be significantly dependent on pH value, which confirms that phytotoxicity is a function of element concentration in solution, which is primarily controlled by pH value in mine tailings. Among the most abundant plant species, dewberry (Rubus caesius), vipersbugloss (Echium vulgare), scarlet pimpernel (Anagallis arvensis) and narrowleaf plantain (Plantago lanceolata) accumulate significant amounts of Pb, Cu and Zn, while in the case of annual bluegrass (Poa annua) only Pb can be measured in elevated contents. Considering the translocation features, scarlet pimpernel, narrowleaf plantain, and dewberry accumulate heavy metals primarily in their roots, while heavy metal concentration in vipersbugloss and annual bluegrass is higher in the shoots.

Spatial decision support for crop structure adjustment – a case study for selection of potential areas for sorghum (Sorghum bicolor (L.) Moench) production

One option for adaptation to climate change is to grow a wider variety of plant species. Sorghum (Sorghum bicolor (L.) Moench) is known to tolerate unfavourable environmental conditions, so it may be feasible to grow it on areas with extreme conditions to replace other species such as maize. Nowadays, spatial decision supporting systems primarily support the crop production process rather than crop structure adjustment. In this study, potential sorghum production sites in the Great Hungarian Plain were selected based on soil characteristics including genetic soil type, parent material, physical soil type, clay composition, water management, pH, organic matter content, topsoil thickness and fertility, as well as climatic data, particularly precipitation. For all the parameters the aim was to find the extreme values at which sorghum, which is less sensitive than maize, may still give an acceptable yield. By combining map layers of soil characteristics, it could be concluded that although the soil is suitable for sorghum on 40.46% of the Great Hungarian Plain, maize is generally a better choice economically. On the other hand, the soil conditions on 0.65% of the land are still suitable for sorghum but unfavourable for maize. As regards the precipitation demand of sorghum, May is the critical period; on 698,968 ha the precipitation required for germination was only recorded once in the period 1991-2010, so these areas cannot be considererd for sorghum. As a consequence, in an alternative crop rotation system sorghum could be competitive with maize, but both the soil and climate conditions and the demands of the crop need to be assessed. The lack of precipitation in critical phenophases significantly decreases the area where maize can survive. Sorghum, however, may produce an acceptable yield, as it is a drought-resistant species.