Emiliano R. Martins

Determining the optimum morphology in high-performance polymer-fullerene organic photovoltaic cells

The morphology of bulk heterojunction organic photovoltaic cells controls many of the performance characteristics of devices. However, measuring this morphology is challenging because of the small length-scales and low contrast between organic materials. Here we use nanoscale photocurrent mapping, ultrafast fluorescence and exciton diffusion to observe the detailed morphology of a high-performance blend of PTB7:PC71BM. We show that optimized blends consist of elongated fullerene-rich and polymer-rich fibre-like domains, which are 10–50 nm wide and 200–400 nm long. These elongated domains provide a concentration gradient for directional charge diffusion that helps in the extraction of charge pairs with 80% efficiency. In contrast, blends with agglomerated fullerene domains show a much lower efficiency of charge extraction of ~45%, which is attributed to poor electron and hole transport. Our results show that the formation of narrow and elongated domains is desirable for efficient bulk heterojunction solar cells.

Deterministic quasi-random nanostructures for photon control

Controlling the flux of photons is crucial in many areas of science and technology. Artificial materials with nano-scale modulation of the refractive index, such as photonic crystals, are able to exercise such control and have opened exciting new possibilities for light manipulation. An interesting alternative to such periodic structures is the class of materials known as quasi-crystals, which offer unique advantages such as richer Fourier spectra. Here we introduce a novel approach for designing such richer Fourier spectra, by using a periodic structure that allows us to control its Fourier components almost at will. Our approach is based on binary gratings, which makes the structures easy to replicate and to tailor towards specific applications. As an example, we show how these structures can be employed to achieve highly efficient broad-band light trapping in thin films that approach the theoretical (Lambertian) limit, a problem of crucial importance for photovoltaics.

Dual gratings for enhanced light trapping in thin-film solar cells by a layer-transfer technique

Thin film solar cells benefit significantly from the enhanced light trapping offered by photonic nanostructures. The thin film is typically patterned on one side only due to technological constraints. The ability to independently pattern both sides of the thin film increases the degrees of freedom available to the designer, as different functions can be combined, such as the reduction of surface reflection and the excitation of quasiguided modes for enhanced light absorption. Here, we demonstrate a technique based on simple layer transfer that allows us to independently pattern both sides of the thin film leading to enhanced light trapping. We used a 400 nm thin film of amorphous hydrogenated silicon and two simple 2D gratings for this proof-of-principle demonstration. Since the technique imposes no restrictions on the design parameters, any type of structure can be made.

Theoretical analysis of supercontinuum generation in a highly birefringent D-shaped microstructured optical fiber

This paper carries out a rigorous analysis of supercontinuum generation in an improved highly asymmetric microstructured fiber (MF) design. This geometry, defined simply as D-MF, has the advantage of being produced with a regular stacking and drawing technology. We have obtained birefringence values on the order of 4.87x10(-3) at the adopted pump wavelength and a significantly smaller effective area when compared to a whole MF, which makes this fiber quite attractive for SCG. Therefore, this D-MF design is a promising alternative for SCG since it provides new degrees of freedom to control field confinement, birefringence, and dispersion characteristics of MFs.

High speed e-beam writing for large area photonic nanostructures - a choice of parameters.

Photonic nanostructures are used for many optical systems and applications. However, some high-end applications require the use of electron-beam lithography (EBL) to generate such nanostructures. An important technological bottleneck is the exposure time of the EBL systems, which can exceed 24 hours per 1 cm2. Here, we have developed a method based on a target function to systematically increase the writing speed of EBL. As an example, we use as the target function the fidelity of the Fourier Transform spectra of nanostructures that are designed for thin film light trapping applications, and optimize the full parameter space of the lithography process. Finally, we are able to reduce the exposure time by a factor of 5.5 without loss of photonic performance. We show that the performances of the fastest written structures are identical to the original ones within experimental error. As the target function can be varied according to different purposes, the method is also applicable to guided mode resonant grating and many other areas. These findings contribute to the advancement of EBL and point towards making the technology more attractive for commercial applications.

Performance Evaluation of a Gigabit Optical CDMA Network for Two Distinct Families of Two-Dimensional Codes and Different Transmission Rates

Abstract This paper investigates the performance of a given gigabit optical code division multiple access (O-CDMA) network for two distinct families of two-dimensional (2-D) codes. The purpose of this analysis is to provide additional information regarding code adequacy to a given system availability so that performance optimization can be more efficiently carried out. The analysis takes into account construction aspects of the codes as well as dispersive and nonlinear effects in the single-mode fiber (SMF), such as group velocity dispersion (GVD), polarization mode dispersion (PMD), self-phase modulation (SPM), and cross-phase modulation (XPM). The analysis focuses on four different transmission rates, i.e., 1.25, 2.5, 5, and 10 Gbit/s, and describes how signal degradations impact the performance of the network. The simulations are carried out for a back-to-back system and for a 50-km dispersion-compensated fiber-optic link.

Photonic Intermediate Structures for Perovskite/c-Silicon Four Terminal Tandem Solar Cells

Tandem perovskite/silicon devices are promising candidates for highly efficient and low-cost solar cells. Such tandem solar cells, however, require careful photon management for optimum performance, which can be achieved with intermediate photonic structures. Here, we identify the ideal requirements for such intermediate structures in perovskite/silicon tandem cells. Counter-intuitively, we find that the reflectance in the perovskite absorption window, i.e., below approx. 800 nm wavelength, does not have a strong impact on the tandem performance. Instead, the main function of the intermediate structure is to act as an optical impedance matching layer at the perovskite–silicon interface. This insight affords the design of simple and tolerant photonic structures that can obtain efficiencies surpassing 30%, assuming a passivated emitter, rear locally diffused (PERL) bottom cell and realistic perovskite top cell, by optical impedance matching alone.

Spatial resolution effect of light coupling structures

The coupling of light between free space and thin film semiconductors is an essential requirement of modern optoelectronic technology. For monochromatic and single mode devices, high performance grating couplers have been developed that are well understood. For broadband and multimode devices, however, more complex structures, here referred to as “coupling surfaces”, are required, which are often difficult to realise technologically. We identify general design rules based on the Fourier properties of the coupling surface and show how they can be used to determine the spatial resolution required for the coupler’s fabrication. To our knowledge, this question has not been previously addressed, but it is important for the understanding of diffractive nanostructures and their technological realisation. We exemplify our insights with solar cells and UV photodetectors, where high-performance nanostructures that can be realised cost-effectively are essential.

Characterization of planar microlenses made of high contrast gratings

We report on the focusing performance of reflective 2D high contrast grating lenses based on silicon. The combination of their subwavelength nature and their high refractive index contrast make it possible to create highly tolerant and planar microlenses. We used a rigorous mathematical code to design the lenses and verified their performance with finite element simulations. We also investigated the effects of grating thickness, angle and wavelength of incidence in these simulations. Experimentally, we show the evolution of the beam profile along the optical axis for a lens with a high (0.37) numerical aperture. We have explored a wide range of numerical apertures (0.1 – 0.93) and focal lengths (5 μm – 140 μm) and show that the lenses behave as expected across the full range. Our analyses demonstrate the large design flexibility with which these lenses can be made along with ease of fabrication and potential for a number of applications in micro-optics.

Focusing with planar microlenses made of two-dimensionally varying high contrast gratings

Abstract. We report on the focusing performance of reflective two-dimensionally varying high contrast grating lenses based on silicon. The combination of their subwavelength nature and their high refractive index contrast makes it possible to create highly tolerant and planar microlenses. We used a rigorous mathematical code to design the lenses and verified their performance with finite element simulations. We also investigated the effects of grating thickness, angle, and wavelength of incidence in these simulations. Experimentally, we show the evolution of the beam profile along the optical axis for a lens with a high (0.37) numerical aperture. We have explored a wide range of numerical apertures (0.1–0.93) and show that the lenses behave as expected across the full range. Our analyses demonstrate the large design flexibility with which these lenses can be made along with ease of fabrication and potential for a number of applications in micro-optics.