Emilie Dressaire

Interfacial Polygonal Nanopatterning of Stable Microbubbles

Micrometer-sized bubbles are unstable and therefore difficult to make and store for substantial lengths of time. Short-term stabilization is achieved by the addition of amphiphilic molecules, which reduce the driving force for dissolution. When these molecules crystallize on the air/liquid interface, the lifetime of individual bubbles may extend over a few months. We demonstrated low gas-fraction dispersions with mean bubble radii of less than 1 micrometer and stability lasting more than a year. An insoluble, self-assembled surfactant layer covers the surface of the microbubbles, which can result in nanometer-scale hexagonal patterning that we explain with thermodynamic and molecular models. The elastic response of the interface arrests the shrinkage of the bubbles. Our study identifies a route to fabricate highly stable dispersions of microbubbles.

Damping of liquid sloshing by foams

When a container is set in motion, the free surface of the liquid starts to oscillate or slosh. Such effects can be observed when a glass of water is handled carelessly and the fluid sloshes or even spills over the rims of the container. However, beer does not slosh as readily as water, which suggests that foam could be used to damp sloshing. In this work, we study experimentally the effect on sloshing of a liquid foam placed on top of a liquid bath. We generate a monodisperse two-dimensional liquid foam in a rectangular container and track the motion of the foam. The influence of the foam on the sloshing dynamics is experimentally characterized: only a few layers of bubbles are sufficient to significantly damp the oscillations. We rationalize our experimental findings with a model that describes the foam contribution to the damping coefficient through viscous dissipation on the walls of the container. Then we extend our study to confined three-dimensional liquid foam and observe that the behavior of 2D and confined 3D systems are very similar. Thus we conclude that only the bubbles close to the walls have a significant impact on the dissipation of energy. The possibility to damp liquid sloshing using foam is promising in numerous industrial applications such as the transport of liquefied gas in tankers or for propellants in rocket engines.

Clogging by sieving in microchannels: Application to the detection of contaminants in colloidal suspensions

We report on a microfluidic method that allows measurement of a small concentration of large contaminants in suspensions of solid micrometer-scale particles. To perform the measurement, we flow the colloidal suspension through a series of constrictions, i.e., a microchannel of varying cross-section. We show and quantify the role of large contaminants in the formation of clogs at a constriction and the growth of the resulting filter cake. By measuring the time interval between two clogging events in an array of parallel microchannels, we are able to estimate the concentration of contaminants whose size is selected by the geometry of the microfluidic device. This technique for characterizing colloidal suspensions offers a versatile and rapid tool to explore the role of contaminants on the properties of the suspensions.

Drop impact on a flexible fiber

When droplets impact fibrous media, the liquid can be captured by the fibers or contact then break away. Previous studies have shown that the efficiency of drop capture by a rigid fiber depends on the impact velocity and a threshold velocity was defined below which the drop is captured. However, it is necessary to consider the coupling of elastic and capillary effects to achieve an improved understanding of the capture process for soft substrates. Here, we study experimentally the dynamics of a single drop impacting on a thin flexible fiber. Our results demonstrate that the threshold capture velocity depends on the flexibility of fibers in a non-monotonic way. We conclude that tuning the mechanical properties of fibers can optimize the efficiency of droplet capture.

Mushrooms use convectively created airflows to disperse their spores

Significance Mushroom spore dispersal is usually described as a two-phase process: active ejection of spores clear of the gill surface by surface tension catapults, followed by a passive phase in which the spores are carried by whatever winds are present beneath the mushroom cap. Here, we show that control extends into the second phase of dispersal: water vapor loss creates slow airflows that carry spores out from under the mushroom cap and potentially tens of centimeters into the air. In addition to clarifying why mushrooms have such high water needs, and providing a mechanism by which spore dispersal can occur even in a low-wind environment, our work shows that the physics of apparently passive dispersal may be under organismal control. Thousands of basidiomycete fungal species rely on mushroom spores to spread across landscapes. It has long been thought that spores depend on favorable winds for dispersal—that active control of spore dispersal by the parent fungus is limited to an impulse delivered to the spores to carry them clear of the gill surface. Here we show that evaporative cooling of the air surrounding the pileus creates convective airflows capable of carrying spores at speeds of centimeters per second. Convective cells can transport spores from gaps that may be only 1 cm high and lift spores 10 cm or more into the air. This work reveals how mushrooms tolerate and even benefit from crowding and explains their high water needs.

Inertia dominated thin-film flows over microdecorated surfaces

We analyze the inertia dominated flow of thin liquid films on microtextured substrates, which here are assemblies of micron-size posts arranged on regular lattices. We focus on situations for which the thin-film thickness and the roughness characteristic length scale are of the same order of magnitude, i.e., a few hundred microns. We assume that the liquid flows isotropically through the roughness at a flow rate that depends on the geometrical features of the porous layer; above the texture, the flow is characterized by a larger Reynolds number and modeled using a boundary layer approach. The influence of the microtexture on the thin-film flow above the microposts is captured by a reduction of the flow rate due to the leakage flow through the texture and a slip boundary condition, which depends on the flow direction as well as on the lattice properties. In this way, the velocity field in the free surface flow adopts the symmetry of the microtexture underneath. The results of this model are in good agreeme...

Experimental study on penny-shaped fluid-driven cracks in an elastic matrix

When a pressurized fluid is injected into an elastic matrix, the fluid generates a fracture that grows along a plane and forms a fluid-filled disc-like shape. We report a laboratory study of such a fluid-driven crack in a gelatin matrix, study the crack shape as a function of time and investigate the influence of different experimental parameters such as the injection flow rate, Young’s modulus of the matrix and fluid viscosity. We choose parameters so that effects of material toughness are small. We find that the crack radius R(t) increases with time t according to tα with α=0.48±0.04. The rescaled experimental data at long times for different parameters collapse based on scaling arguments, available in the literature, showing R(t)∝t4/9 from a balance of viscous stresses from flow along the crack and elastic stresses in the surrounding matrix. Also, we measure the time evolution of the crack shape, which has not been studied before. The rescaled crack shapes collapse at longer times and show good agreement with the scaling arguments. The gelatin system provides a useful laboratory model for further studies of fluid-driven cracks, which has important applications such as hydraulic fracturing.

Mechanical Tuning of the Evaporation Rate of Liquid on Crossed Fibers

We investigate experimentally the drying of a small volume of perfectly wetting liquid on two crossed fibers. We characterize the drying dynamics for the three liquid morphologies that are encountered in this geometry: drop, column, and a mixed morphology, in which a drop and a column coexist. For each morphology, we rationalize our findings with theoretical models that capture the drying kinetics. We find that the evaporation rate significantly depends upon the liquid morphology and that the drying of the liquid column is faster than the evaporation of the drop and the mixed morphology for a given liquid volume. Finally, we illustrate that shearing a network of fibers reduces the angle between them, changes the morphology toward the column state, and therefore, enhances the drying rate of a volatile liquid deposited on it.

Wetting morphologies on an array of fibers of different radii

We investigate the equilibrium morphology of a finite volume of liquid placed on two parallel rigid fibers of different radii. As observed for identical radii fibers, the liquid is either in a column morphology or adopts a drop shape depending on the inter-fiber distance. However the cross-sectional area and the critical inter-fiber distance at which the transition occurs are both modified by the polydispersity of the fibers. Using energy considerations, we analytically predict the critical inter-fiber distance corresponding to the transition between the column and the drop morphologies. This distance depends both on the radii of the fibers and on the contact angle of the liquid. We perform experiments using a perfectly wetting liquid on two parallel nylon fibers: the results are in good agreement with our analytical model. The morphology of the capillary bridges between fibers of different radii is relevant to the modeling of large arrays of polydisperse fibers.

Wetting morphologies on randomly oriented fibers

We characterize the different morphologies adopted by a drop of liquid placed on two randomly oriented fibers, which is a first step toward understanding the wetting of fibrous networks. The present work reviews previous modeling for parallel and touching crossed fibers and extends it to an arbitrary orientation of the fibers characterized by the tilting angle and the minimum spacing distance. Depending on the volume of liquid, the spacing distance between fibers and the angle between the fibers, we highlight that the liquid can adopt three different equilibrium morphologies: 1) a column morphology in which the liquid spreads between the fibers, 2) a mixed morphology where a drop grows at one end of the column or 3) a single drop located at the node. We capture the different morphologies observed using an analytical model that predicts the equilibrium configuration of the liquid based on the geometry of the fibers and the volume of liquid.Graphical abstract