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Emilio E. Bunel

DuPont

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Publication

Featured researches published by Emilio E. Bunel.

Polyhedron | 1995

Oxidative addition of RCOI to [AsPh4][Rh(CO)2I2]. Synthesis of [AsPh4][RCORh(CO)2I3] (R = Me, Et, n-Pr, i-Pr)

Laurie A. Howe; Emilio E. Bunel

Abstract Reaction of [AsPh4][Rh(CO)2I2] (1) with RCOI yields complexes [AsPh4]2 [RCORh(CO)I3]2 (2,R Me; 3 R  Et; 4 R  n-Pr; 5 R  i-Pr). The 13CO Scrambling process for complexes [AsPh4][RCORh(13CO)(S)I3] (R  Me,Et; S  CD3CN) along with the skeleton isomerization of [AsPh4]RCORh(CO)(S)I3] (R  n-Pr, i-Pr) was determined by 1H NMR spectroscopy. Rates of CO insertion into the RhC bond in [AsPh4][RRh(CO)3I3] (R  Me, n-Pr, i-Pr) were determined. Thermolysis of [AsPh4] [MeCORh(CO)(CD3CN)I3] (6) in CD3CN gives methyl iodide in contrast to [AsPh4] give only propene as the organic fragment.

Journal of the American Chemical Society | 1995

Structural and physical properties of delocalized mixed-valent [Cp*M(pentalene)M′Cp*]n+ and [Cp*M(indacene)M′Cp*]n+ (M, M′ = Fe, Co, Ni; n = 0, 1, 2) complexes

Juan M. Manriquez; Michael D. Ward; William M. Reiff; Joseph C. Calabrese; Nancy L. Jones; Patrick J. Carroll; Emilio E. Bunel; Joel S. Miller

Archive | 1997

Process for the hydrocyanation of monoolefins using bidentate phosphite ligands and zero-valent nickel

Emilio E. Bunel; Kenneth C. Mcnulty

Archive | 2001

Production of 6-aminocaproic acid

Emilio E. Bunel; Theodore A. Koch; Ronnie Ozer; Sourav Kumar Sengupta

Archive | 1999

Hydroformylation of olefins using supported bis(phosphorus) ligands

Emilio E. Bunel; Patrick Michael Burke; Joe Douglas Druliner; Leo Ernest Manzer; Kenneth Gene Moloy; Manxue Wang

Archive | 2001

Bidentate organic phosphite ligands and compositions

Emilio E. Bunel; Helen S. M. Lu; Kenneth Gene Moloy; Shawn H. Phillips; Kathryn Eileen Schwiebert; Wilson Tam; Nora S. Radu

Archive | 1994

Preparation of 3-pentenoic acid and a catalyst therefore

Emilio E. Bunel; Michael B. D'Amore; Chen-Chou Chiang; Erik Jefferson Schaumann; Leon S. Scott

Archive | 1999

Process for the production of 6-aminocapronitrile and/or hexamethylenediamine

Emilio E. Bunel; Theodore A. Koch; Ronnie Ozer; Shawn H. Phillips; Sourav Kumar Sengupta

Archive | 2000

Hydroformylation of conjugated dienes to alkenals using phosphonite ligands

Emilio E. Bunel

Archive | 2000

Hydroformylation using multidentate phosphite ligands

Emilio E. Bunel; Helen S. M. Lu; Kenneth Gene Moloy; Shawn H. Phillips; Kathryn Eileen Schwiebert; Wilson Tam; Nora S. Radu

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Kenneth Gene Moloy

DuPont

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Ronnie Ozer

DuPont

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Sourav Kumar Sengupta

DuPont

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Theodore A. Koch

DuPont

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Joel S. Miller

University of Utah

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Kathryn Eileen Schwiebert

DuPont

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Shawn H. Phillips

DuPont

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B. Oelckers

Valparaiso University

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Nora S. Radu

DuPont

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Wilson Tam

DuPont

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