Emma Barchiesi
Solvay
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Publication
Featured researches published by Emma Barchiesi.
Journal of Fluorine Chemistry | 1999
Maurizio Pianca; Emma Barchiesi; Giuseppe Esposto; Stefano Radice
Abstract IR and NMR spectroscopies are the most important techniques used to identify and quantify end groups in fluoropolymers. We review here some literature studies about the characterisation of end groups in some fluoropolymers based on tetrafluoroethylene, vinylidene fluoride and vinyl fluoride, adding the contribution of our investigation on the matter.
Journal of Fluorine Chemistry | 1992
Stefano Radice; Maurizio Pianca; Emma Barchiesi; J. Abusleme
Abstract We have developed an IR method to study the content of monomer sequences in ETFE and ECTFE copolymers that may substitute for NMR spectroscopy in routine analysis. Indeed, the NMR analyses are carried out at 300 °C and 200 °C respectively, risking instrumental damage due to the high temperature. The search for a different technique based only on FT-IR spectroscopy can thereby be justified. We examined NMR and IR spectra of several ETFE and ECTFE polymers with different ethylene molar contents. Combining 19 F NMR and elemental analysis data it was possible to determine the structure of ETFE copolymers at the level of monomer triads. The triad monomer distribution can be obtained in the same way for ECTFE copolymers. In this case it was also possible to obtain 1 H NMR spectra that can be used to determine the concentration of [E]n sequences directly. In the case of ETFE copolymers this could only be calculated by difference. The IR spectra of both copolymers were carefully analyzed in the CH stretching region, because the CH oscillators are very sensitive to sequence distribution (both for frequency and intensity). The information so obtained considers total ethylene sequences [E]n for n>2. Some weak absorptions in the IR spectrum of the ETFE copolymer due to triad sequences [L.N. Pirozhnaya and L. I. Tarutina, Zh. Prikl. Spektros., 34 (1980) 862; L. I. Tarutina, Zh. Prikl. Spektros., 8 (1968) 653] have been correlated with the corresponding triad content determined through NMR spectroscopy. This work allowed us to discriminate in terms of homogeneity of monomer distribution between copolymers of similar molar composition and to test the reliability of available reactivity ratios.
Archive | 2008
Julio A. Abusleme; Riccardo Pieri; Emma Barchiesi
Journal of Polymer Science Part A | 2005
Antonio Russo; Claudio Tonelli; Emma Barchiesi
Journal of Fluorine Chemistry | 2005
Pier Antonio Guarda; Emma Barchiesi; Giovanni Fontana; Silvia Rita Petricci; M. Pianca; G. Marchionni
Journal of Fluorine Chemistry | 2008
Walter Navarrini; Francesco Venturini; Maurizio Sansotera; Maurizio Ursini; Pierangelo Metrangolo; Giuseppe Resnati; Marco Galimberti; Emma Barchiesi; Patrizia Dardani
Journal of Fluorine Chemistry | 2004
Stefano Radice; Paolo Toniolo; Emma Barchiesi; P.A. Guarda; Matteo Tommasini; C. Castiglioni
Journal of Fluorine Chemistry | 2003
Ivan Wlassics; Emma Barchiesi; M. Sala
Journal of Polymer Science Part A | 2002
Claudio Tonelli; Antonella Di Meo; Emma Barchiesi
Journal of Fluorine Chemistry | 2005
Marco Galimberti; Emma Barchiesi; Walter Navarrini