Emmanuel Rivière

Role of lee waves in the formation of solid polar stratospheric clouds: Case studies from February 1997

Recent theories of solid polar stratospheric clouds (PSCs) formation have shown that particles could remain liquid down to 3 K or 4 K below the ice frost point. Such temperatures are rarely reached in the Arctic stratosphere at synoptic scale, but nevertheless, solid PSCs are frequently observed. Mesoscale processes such as mountain-induced gravity waves could be responsible for their formation. In this paper, a microphysical-chemical Lagrangian model (MiPLaSMO) and a mountain wave model (NRL/MWFM) are used to interpret balloon-borne measurements made by an optical particle counter (OPC) and by the Absorption par Minoritaires Ozone et NOx (AMON) instrument above Kiruna on February 25 and 26, 1997, respectively. The model results show good agreement with the particle size distributions obtained by the OPC in a layer of large particles, and allow us to interpret this layer as an evaporating mesoscale type Ia PSC (nitric acid trihydrate) mixed with liquid particles. The detection of a layer of solid particles by AMON is also qualitatively reproduced by the model and is interpreted to be frozen sulfate acid aerosols (SAT). In this situation, the impact of mountain waves on chlorine activation is studied. It appears that mesoscale perturbations amplify significantly the amount of computed ClO, as compared to synoptic runs. Moreover, MiPLaSMO chemical results concerning HNO3 and HCl agree with measurements made by the Limb Profile Monitor of the Atmosphere (LPMA) instrument on February 26 at a very close location to AMON, and explain part of the differences between LPMA measurement and Reactive Processes Ruling the Ozone Budget in the Stratosphere (REPROBUS) model outputs.

Measurements and simulation of stratospheric NO3 at mid and high latitudes in the northern hemisphere

Simultaneous measurements of NO 3 , along with those of O 3 , NO 2 , and aerosol extinction coefficient, have been performed during the night by the AMON instrument since 1992 at high and midlatitudes and by the SALOMON instrument since 1998 at midlatitude. Observations are conducted using the stellar and lunar occultation methods, respectively. Vertical profiles of NO 3 are obtained after inversion of the optical depth spectra recorded from 650 to 670 nm, including the 662-nm absorption line. Five profiles at midlatitude and two profiles at high latitude are presented. Comparisons with a box model constrained with measured ozone and temperatures (and NO 2 at high latitude) have been performed, taking into account the uncertainties in the rate constants of the reactions leading to NO 3 equilibrium. The modeling results can reproduce part of the observations, taking into account possible errors in the rate constants, temperature, or NO 3 absorption cross sections. Some disagreements nevertheless remain between observations and modeling outputs. In the middle stratosphere they could result from gradients of temperature. Below 30 km, other phenomena could be invoked to explain the disagreements. At high latitude the presence of solid polar aerosols induces an artifact in the data reduction. At midlatitude, large increases observed in the NO 3 concentration profiles obtained between 1992 and 1994 are real. A speculative hypothesis involving volcanic aerosols is proposed.

Remote‐sensing measurements in the polar vortex: Comparison to in situ observations and implications for the simultaneous retrievals and analysis of the NO2 and OClO species

Nighttime remote-sensing balloon observations conducted by the SALOMON instrument in the arctic polar vortex in January 2006 reveal high amounts of stratospheric NO 2 in the lower stratosphere similarly to previously published profiles. NO 2 concentration enhancements are also present in the vertical profiles observed by the GOMOS instrument on board the Envisat satellite and obtained coincidently to the balloon measurements. Such quantities are not present in in situ observations obtained by the SPIRALE instrument in similar geophysical conditions. While OClO amounts are acceptably reproduced by Chemistry Transport Model (CTM) calculations, NO 2 simulated values are well below the observed quantities. The examination of the slant column densities of NO 2 obtained at float altitude highlights unexpected strong enhancements with respect to the elevation angle and displacement of the balloon. It is shown that these fluctuations result from NO 2 spatial inhomogeneities located above the balloon float altitude. Potential vorticity maps reveal the presence of midlatitude NO 2 -rich air in the upper stratosphere or lower mesosphere as a result of the perturbed dynamical situation of the vortex. The presence of spatial inhomogeneities crossed by the lines of sight leads to artificial high concentration values of NO 2 in the vertical profile retrieved from the slant column densities assuming spatial homogeneity. A direct implication is that the differences previously observed between measurements of NO 2 and OClO and model results are probably mostly due to the improper inversion of NO 2 in the presence of perturbed dynamical conditions or when mesospheric NO x production events occur. The dynamical situation will have to be systematically analyzed in future studies involving remote-sensing observations.

Nitric acid particles in cold thick ice clouds observed at global scale: Link with lightning, temperature, and upper tropospheric water vapor

Signatures of nitric acid particles (NAP) in cold thick ice clouds have been derived from satellite observations. Most NAP are detected in the tropics (9 to 20% of clouds with T < 202.5 K). Higher occurrences were found in the rare midlatitudes very cold clouds. NAP occurrence increases as cloud temperature decreases, and NAP are more numerous in January than July. Comparisons of NAP and lightning distributions show that lightning seems to be the main source of the NOx, which forms NAP in cold clouds over continents. Qualitative comparisons of NAP with upper tropospheric humidity distributions suggest that NAP may play a role in the dehydration of the upper troposphere when the tropopause is colder than 195 K.

Modeling the TTL at Continental Scale for a Wet Season: An Evaluation of the BRAMS Mesoscale Model Using TRO‐Pico Campaign, and Measurements From Airborne and Spaceborne Sensors

In order to better understand the water vapor (WV) intrusion into the tropical stratosphere, a mesoscale simulation of the tropical tropopause layer (TTL) using the BRAMS (Brazilian version of RAMS) model is evaluated for a wet season. This simulation with a horizontal grid-point resolution of 20 km × 20 km cannot resolve the stratospheric overshooting convection (SOC). Its ability to reproduce other key parameters playing a role in the stratospheric WV abundance is investigated using the balloon-borne TRO-Pico campaign measurements, the upper-air soundings over Brazil, and the satellite observations by Aura MLS (Microwave Limb Sounder), MHS (Microwave Humidity Sounder) and GOES-12. The BRAMS exhibits a good ability in simulating temperature, cold-point, WV variability around the tropopause. However, the simulation is typically observed to be warmer by ∼2.0°C and wetter by ∼0.4 ppmv at the hygropause, which can be partly affiliated with the grid-boundary nudging of the model by ECMWF operational analyses. The modeled cloud tops show a good correlation (maximum cross-correlation of ∼0.7) with GOES-12. Furthermore, the overshooting cells detected by MHS are observed at the locations, where 75% of the modeled cloud tops are higher than 11 km. Finally, the modeled inertia-gravity wave periodicity and wavelength are comparable with those deduced from the radio sounding measurements during TRO-Pico campaign. The good behavior of BRAMS confirms the SOC contribution in the WV abundance and variability is of lesser importance than the large-scale processes. This simulation can be used as a reference run for upscaling the impact of SOC at a continental scale for future studies.