Enrico Zavagno

Intrinsic vulnerability of the Isonzo/Soča high plain aquifer (NE Italy – W Slovenia)

ABSTRACT The paper presents the map of intrinsic groundwater vulnerability of the Isonzo/Soča High Plain, which is located between the Collio Hills and the Classical Karst Region and holds an aquifer shared between Italy and Slovenia. The map, produced at a scale of 1:25,000 and printed in A0 format, was obtained by means of the SINTACS method and shows the intrinsic vulnerability of the aquifer in terms of seven vulnerability classes, from extremely high to low. It is accompanied by four supplementary sketches that illustrate the geological framework, the bedrock top surface, the groundwater flow paths, the Hazard Index map and three diagrams that summarize the percentages of vulnerability classes and of Hazard Index classes of the study area.

The Karst Hydrostructure of the Mount Canin (Julian Alps, Italy and Slovenia)

The Mt. Canin massif, from a hydrogeological and geomorphological point of view, is a unique structure, being an independent part of the Italian Julian Alps (north east Italy) bounded on all sides by impressive karst springs. Extensive outcropping limestones go from the top (2587 m a.s.l.) to the bottom of the valleys (about 500 m a.s.l.) creating an hydrostructure subdivided between two countries originating two transboundary watersheds: the Mediterranean one to the South and the Black Sea to the North. The aim of this paper is to define the dynamic and the characteristics of the groundwaters and to identify the superficial and deep watersheds in order to elaborate the aquifer vulnerability.

Rock Fall Characterization in Climbing Spots: The Case Study of the “ Napoleonica ” Tourist Route (Trieste, NE Italy)

In NE Italy, fast-moving landslides represent a significant threat both to the population and the built environment. In the eastern portion of the Italian Alps, rock falls are common and are often responsible for casualties or severe damage to infrastructure. This type of landslide is characterized by strong relief energy and is triggered by earthquakes or copious rainfall, which often exceeds 2000 mm/yr. To assess rock fall hazard using software analysis, field surveys are crucial to accurately recognize the source areas of falling rock phenomena, to quantify the volumes of unstable blocks and identify the possible block trajectories. The current work takes in detailed geological and geomorphological mapping, through the identification of dislodged blocks, fractures and fallen blocks on a much-frequented limestone cliff in the Trieste Karst used as a climbing spot. Moreover, a popular tourist path (the Napoleonica) lies at the foot of the climbing cliffs. In-depth traditional activities, such as field surveys and aerial photo analysis were undertaken, including morphometric and geomechanical characterization of the whole rock mass, in order to perform a first identification of the more hazardous sections of the Napoleonica. The field data were collected using UAV (Unmanned Aircraft Vehicle) images and videos and this innovative technique allow the reaching and study of difficult sites with excellent resolution and precision. The final output is a GIS-developed map, that will be the starting point for future 2D and 3D simulations, that will lead to the creation of a rock fall susceptibility evaluation of the whole area.

Mercury in the unconfined aquifer of the Isonzo/Soca River alluvial plain downstream from the Idrija mining area

This work aims at evaluating mercury (Hg) occurrence, spatial distribution and speciation in groundwater of the Isonzo/Soča River upper alluvial plain downstream from the Idrija Hg mine (Western Slovenia). Several wells and piezometers were sampled both in static and dynamic mode. Total (THg) and filtered (FHg) concentrations were generally higher in static (THg, 1.87-855 ng L-1; FHg, 0.20-13.61 ng L-1) than in dynamic mode (THg, 0.08-78.77 ng L-1; FHg, 0.28-6.65 ng L-1). The estimated background value accounts for 2-3 ng L-1. On the basis of hydrochemistry and isotopic composition, the main sources of groundwater were established. Hg concentrations in the Slovenian sector, supplied by local rainfall, are comparable to values measured close to the Isonzo River. Possible further Hg local sources have been suggested. Stability field analysis for the aqueous Hg species revealed that in the presence of chloride Hg solubility may be increased by the formation of chlorocomplexes. Mercury that rarely enters reduced surrounding conditions can be bound to sulphur to form polysulphide species depending on the pH of water. Since Hg-contaminated alluvial sediments of the Isonzo River may act as a secondary Hg source in groundwater, a borehole was dug down to the water table. Mercury content and speciation revealed that cinnabar (HgS) is the prevalent form followed by the matrix-bound Hg (Hgbound). Variations of the physico-chemical boundary conditions, as well as the raising/lowering of the water table, may be locally responsible for the slight variability of Hg concentrations in the aquifer.