Eric Font

Mercury anomaly, Deccan volcanism, and the end-Cretaceous mass extinction

The contribution of the Deccan Traps (west-central India) volcanism in the Cretaceous-Paleogene (KPg) crisis is still a matter of debate. Recent U-Pb dating of zircons interbedded within the Deccan lava flows indicate that the main eruptive phase (>1.1 × 106 km3 of basalts) initiated ∼250 k.y. before and ended ∼500 k.y. after the KPg boundary. However, the global geochemical effects of Deccan volcanism in the marine sedimentary record are still poorly resolved. Here we investigate the mercury (Hg) content of the Bidart (France) section, where an interval of low magnetic susceptibility (MS) located just below the KPg boundary was hypothesized to result from paleoenvironmental perturbations linked to the paroxysmal Deccan phase 2. Results show Hg concentrations >2 orders of magnitude higher from ∼80 cm below to ∼50 cm above the KPg boundary (maximum 46.6 ppb) and coincident with the low MS interval. Increase in Hg contents shows no correlation with clay or total organic carbon contents, suggesting that the Hg anomalies resulted from higher input of atmospheric Hg species into the marine realm, rather than organic matter scavenging and/or increased runoff. The Hg anomalies correlate with high shell fragmentation and dissolution effects in planktic foraminifera, suggesting correlative changes in marine biodiversity. This discovery represents an unprecedented piece of evidence of the nature and importance of the Deccan-related environmental changes at the onset of the KPg mass extinction.

The dawn of CAMP volcanism and its bearing on the end-Triassic carbon cycle disruption

The cause-and-effect relationship between the c. 201 Ma eruption of the Central Atlantic magmatic province (CAMP) and the end-Triassic abrupt climate change and mass extinction is at present based on controversial temporal correlations. Upper Triassic sedimentary strata underlying CAMP basalts in Morocco illustrate a clear mineralogical and geochemical fingerprint of early CAMP basaltic eruptions, namely unusually high contents of MgO (10–32 wt%) and of mafic clay minerals (11–84%). In the same rocks a coincident negative carbon-isotope excursion (CIE) is present, equivalent to the so-called ‘initial negative CIE’ recorded worldwide shortly before the Triassic–Jurassic boundary. The new data show that the onset of CAMP activity preceded the end-Triassic carbon cycle disruption and that the initial negative CIE is unequivocally synchronous with CAMP volcanism. The results of this study strongly support the hypothesis that the culmination of pollution of atmosphere and seawater by CAMP-derived volcanic gases was the proximate cause of the end-Triassic mass extinction. Supplementary material: The stratigraphic position of analysed samples, and the C-isotope, bulk-rock mineralogy, element analysis, Mg–Al–Si ternary diagram and trace-element analysis data are available at www.geolsoc.org.uk/SUP18707.

Episodic Remagnetizations related to tectonic events and their consequences for the South America Polar Wander Path

Abstract The South American record of remagnetizations is linked to specific events of its tectonic history stretching back to Precambrian times. At the Ediacaran–Cambrian time interval (570–500 Ma), the final stages of the western Gondwana assemblage led to remagnetization of Neoproterozoic carbonates within the São Francisco–Congo Craton and at the border of the Amazon Craton, along the Araguaia–Paraguay–Pampean Belt. From the late Permian to early Triassic, the San Rafaelic orogeny and the emplacement of the Choiyoi magmatic province was responsible for widespread remagnetizations in Argentina and Uruguay. Cretaceous remagnetization has also been documented in Brazil and interpreted to result from magmatism and fault reactivations linked to the opening of the South Atlantic Ocean. We present a review of these widespread remagnetization events principally based on palaeomagnetic data and, when available, on rock magnetic and radiogenic isotope age data. This study gives an overview of the geographical distribution of the remagnetization events in South America, and provides important clues to better understand the geodynamic evolution of the South American plate at these times. In addition, magnetic mineralogy data for the different case studies presented here constrain the physical–chemical mechanisms that led to partial or total resetting of magnetic remanences in sedimentary rocks.

Magnetic fingerprint of southern Portuguese speleothems and implications for paleomagnetism and environmental magnetism

Environmental magnetism of speleothems is still in its early stage of development. Here we report on our investigation of the environmental and paleomagnetic information that has been recorded in speleothems, and what are the factors that control its preservation and reliability. To address these issues, we used a multidisciplinary approach, including rock magnetism, petrography, scanning electron microscopy, stable carbon and oxygen isotope compositions, and major and trace element concentrations. We applied this to a set of samples from different stages of speleothem evolution: present-day dripwater (glass plates), a weathered stalactite, a fresh stalagmite, cave sediments, and terra rossa soils. These samples come from the Penico and Excentricas caves, located in two distinct aquifers of the Algarve region, South Portugal. Our results show that the main magnetic carriers of the speleothems under study are primary (detrital) and consist of maghemite (and magnetite?). Similarities in coercivity and temperature dependence of the studied set of samples suggest that iron oxides are inherited from the terra rossa soils that cap the cave and were transported to the speleothems by dripwater. Hence, they represent a regional environmental signature. Interestingly, a stable and probably detrital remanent magnetization could be isolated in the fresh stalagmite, whereas the weathered stalactite yielded chaotic magnetic directions and very low remanent intensities. We propose that these low intensities can be the result from (i) different remanence acquisition mechanisms between stalagmite and stalactite and/or (ii) iron dissolution by fungal activity. We also suggest that magnetic properties and color and the content in detrital elements in the fresh speleothem inform about environmental processes acting on the interface of rock (soil)-atmosphere, while oxygen isotope composition and alkaline-earth element concentrations inform about calcite-water interaction processes. These results provide a better understanding of how environmental information is recorded in speleothems and what the factors are that control the reliability of the paleomagnetic and paleo-environmental signal.

Paleoenvironmental signature of the Deccan Phase-2 eruptions

The environmental impact of the Deccan trap volcanism is poorly understood as yet. The paucity of geological markers that can unambiguously be attributed to the Deccan volcanism and the temporal coincidence of the volcanism with an asteroid impact make evaluation of volcanic contribution to the end Cretaceous mass extinction difficult. Here we briefly review environmental proxy records of two reference Cretaceous-Tertiary boundary (KTB) sections, Bidart (France) and Gubbio (Italy). In both sections, a change in colour of sediments located just below the KTB is systematically associated with very low values of (low-field) magnetic susceptibility (MS). Rock magnetic characteristics suggest that the decrease in MS values results from the loss (dissolution) of ferrimagnetic mineral in this intervals. In addition to the characteristic change in magnetic assemblage, akaganeite (chlorine-bearing iron oxyhydroxide) is commonly observed under the scanning electron microscope in the low MS intervals at Bidart and Gubbio, but has never been detected in the remaining sedimentary successions. We suggest that the association of granular akaganeite and iron oxides dissolution features can be explained by an ocean acidification and aerosol deposition event linked to the Deccan Phase-2 volcanism.

End-Cretaceous akaganéite as a mineral marker of Deccan volcanism in the sedimentary record

An enigmatic chloride-rich iron (oxyhydr)oxide has been recently identified together with mercury anomalies in End-Cretaceous marine sediments coeval with the Deccan Traps eruptions. The mineral was observed in Bidart (France) and Gubbio (Italy), suggesting a widespread phenomenon. However, the exact nature and origin of this Cl-bearing mineral remained speculative. Here, we characterized the accurate composition and nanostructure of this chloride-rich phase by using micro-Raman spectroscopy, Transmission (TEM) and Scanning (SEM) Electron Microscopy on Focused Ion Beam foils. We also provide new evidence of its occurrence in Zumaia, a reference KPg section from Spain. Results confirm akaganéite (β-FeOOH) as the main phase, with chloride content of 3–5 atomic weight %. Akaganéite particles are constituted by the aggregation of nanorods of akaganéite. Internal structures contain empty spaces, suggesting formation in a low-density (atmospheric) environment. This new mineralogical evidence supports the hypothesis that the observed akaganéite was formed in the Deccan volcanic plume and was transported to the Atlantic and Tethysian realms through the stratosphere. Therefore, akaganéite provides a potential new sedimentary marker to identify the imprint of the Deccan eruptions in the stratigraphic record and is evidence of volcanic halogen degassing and its potential role for the Cretaceous-Tertiary mass extinction.

The effect of speleothem surface slope on the remanent magnetic inclination

Speleothems are of interest for high-resolution reconstruction of the Earths magnetic field. However, little is known about the influence of speleothem morphologies on their Natural Remanent Magnetization (NRM) record. Here we report on a high-resolution paleomagnetic study of a dome-shaped speleothem of Middle Holocene age from southern Portugal, with special attention to the anisotropy of magnetic susceptibility (AMS) and anisotropy of anhysteretic remanent magnetization (AARM). To assess the potential influence of the slope of the speleothem surface on the recorded remanent magnetization, we compare magnetic directions and AMS and AARM fabrics from sub-horizontal to gradually sub-vertical calcite growth layers collected in a transversal cross-section of the speleothem. A linear correlation is observed between magnetic inclinations, calcite laminae slope and AARM k1 inclination. The AMS fabric is mostly controlled by calcite crystals, with direction of the minimum axes (k3) perpendicular to laminae growth. Magnetic inclinations recorded in inclined and vertical calcite growth layers are underestimated when compared to a global paleosecular variation (PSV) model. After extrapolating magnetic inclinations to the horizontal, the corrected data better fit the PSV model, but are still lower than the predicted magnetic inclinations, suggesting that inclination shallowing affects the entire speleothem. We suggest that speleothem morphology exerts a critical role on the magnetic inclination recording, which is controlled by the Earths magnetic field but also influenced by particle rolling along the sloping surfaces. These observations open new avenues for reconstructing high-resolution paleomagnetic secular variations records from speleothems and provide new insights into their NRM acquisition mechanisms.

A Reply to the Comment on “Assessing Discrepancies Between Previous Plate Kinematic Models of Mesozoic Iberia and Their Constraints” by Barnett-Moore Et Al.: A response document

We welcome the comments of van Hinsbergen et al. [2017] on the recent efforts of Barnett-Moore et al. [2016]. Specifically, van Hinsbergen et al. [2017] raise concerns about two of the major conclusions made by Barnett-Moore et al. [2016]. Firstly, Barnett-Moore et al. [2016] choose to negate the Cretaceous Iberian paleomagnetic database as a viable plate kinematic constraint on the plate motions of Mesozoic Iberia. This conclusion, criticized by van Hinsbergen et al. [2017], was based on citing the previous efforts of Neres et al. [2012; 2013], which exposed several shortcomings, elaborated on below, within this dataset. Secondly, van Hinsbergen et al. [2017] criticize Barnett-Moore et al. [2016] for dismissing mantle tomographic interpretations in support of a preserved Cretaceous Pyrenean ‘subducted slab’ beneath northern Africa. Below, we have addressed each of these major criticisms from van Hinsbergen et al. [2017] in a two-section layout, similar to their comment above.