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Radiochimica Acta | 2008

Electrorefining of U-Pu-Zr-alloy fuel onto solid Aluminium cathodes in molten LiCl-KCl

Pavel Soucek; Laurent Cassayre; Rikard Malmbeck; Eric Mendes; R. Jardin; Jean-Paul Glatz

An electrorefining process in molten chloride salts using solid aluminium cathodes is being developed at ITU to recover actinides (An) from the spent nuclear fuel. The maximum possible loading of aluminium electrodes with actinides was investigated during the electrorefining of U-Pu-Zr alloy in a LiCl-KCl eutectic at 450 °C. Two different electrolytic techniques were applied during the experiment and almost 6000 C has been passed, corresponding to 3.7 g of deposited actinides. A very high capacity of aluminium to retain actinides has been proven as the average Al: An mass ratio was 1:1.58 for galvanostatic and 1:2.25 for potentiostatic mode. The obtained deposits were characterized by XRD and SEM-EDX analysis and alloys composed of (U,Pu)Al3 were detected. The influence of zirconium co-oxidation during the process was also investigated and the presence of dissolved Zr ions in the melt yielded a significant deterioration of the quality of the deposit.


Journal of Nuclear Materials | 2008

On the formation of U–Al alloys in the molten LiCl–KCl eutectic

Laurent Cassayre; Concepción Caravaca; R. Jardin; Rikard Malmbeck; Patrick Masset; Eric Mendes; Jérôme Serp; Pavel Soucek; Jean-Paul Glatz


Journal of Nuclear Materials | 2009

Study of thermodynamic properties of Np–Al alloys in molten LiCl–KCl eutectic

Pavel Soucek; Rikard Malmbeck; Eric Mendes; C. Nourry; David Sedmidubský; Jean-Paul Glatz


Journal of Nuclear Materials | 2012

On the electrochemical formation of Pu–Al alloys in molten LiCl–KCl

Eric Mendes; Rikard Malmbeck; C. Nourry; Pavel Soucek; Jean-Paul Glatz


Journal of Radioanalytical and Nuclear Chemistry | 2010

Exhaustive electrolysis for recovery of actinides from molten LiCl–KCl using solid aluminium cathodes

Pavel Soucek; Rikard Malmbeck; Eric Mendes; C. Nourry; Jean-Paul Glatz


Journal of Nuclear Materials | 2008

On the formation of UAl alloys in the molten LiClKCl eutectic

Laurent Cassayre; C. Caravaca; R. Jardin; Rikard Malmbeck; Patrick Masset; Eric Mendes; Jérôme Serp; Pavel Soucek; Jean-Paul Glatz


Archive | 2008

Recovery of Actinides from Actinide-Aluminium Alloys: Chlorination Route

Eric Mendes; Laurent Cassayre; Rikard Malmbeck; Pavel Soucek; R. Jardin; Jean-Paul Glatz


2015-Sustainable Industrial Processing Summit & Exhibition | 2015

Development of the Pyrochemical DOS Process for the Recovery of Actinides and its Application for Reprocessing of Transmutation Fuel Targets

Eric Mendes; Thomas Ducasse; Jérôme Serp; Manuel Miguirditchian; Murielle Bertrand


Journal of Nuclear Materials | 2009

Study of thermodynamic properties of NpAl alloys in molten LiClKCl eutectic

Pavel Soucek; Rikard Malmbeck; Eric Mendes; C. Nourry; David Sedmidubsky; Jean-Paul Glatz


Archive | 2007

Electrorefining of U-Pu-Zr alloy on solid Al electrodes in LiCl-KCl eutectic melt initially containing Zr ions

Pavel Soucek; Laurent Cassayre; Rikard Malmbeck; Eric Mendes; Jean-Paul Glatz

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