F. Almeraya-Calderón

Low Impact Velocity Wastage in FBCs - Experimental Results and Comparison Between Abrasion and Erosion Theories

The use of technologies related to combustion of coal in fluidized bed combustors (FBCs) present attractive advantages over conventional pulverized coal units. Some of the outstanding characteristics are: excellent heat transfer, low emission of contaminants, good combustion efficiencies and good fuel flexibility. However, FBC units can suffer materials deterioration due to particle interaction of solid particles with the heat transfer tubes immersed on the bed (Hou, 2004, Oka, 2004, Rademarkers et al., 1990). Among other issues, some of the most important factors believed to cause wear problems are: the motion of slowly but relatively coarse particles, particles loaded onto the surface by other particles, erosion by relatively fast-moving particles associated with bubbles, and abrasion by blocks of particles thrown into the surface by bubble collapse. Thus, erosion or abrasion processes can occur by a variety of causes. For the case of particle movement against in-bed surfaces, it has been suggested that there is no difference in the ability to cause degradation between solid particle erosion and low stress three body abrasion, and distinctions between the two forms of wear should not to be made (Levy, 1987).

Modeling of Volatiles Combustion and Alkali Deposition in a Fluidized Bed Coal Combustor

A simplified kinetic model, coupled with the bed hydrodynamics and a volatile evolution region within the bed, was formulated to predict the extent of gas-phase combustion in a laboratory-scale fluidized bed coal combustor (FBC). A close examination has also been made to highlight the relevance of the reducing/oxidizing environment (computed with the present theoretical model) in relation to FBC materials exposed to fireside corrosion at high temperature, under various operating conditions. The model results revealed that, for high-volatile coals with particle diameters (d c ) of 1-3 mm and sand particle size (d s ) of 0.674 mm, over one third of the original coal volatiles may burn in the freeboard region at bed temperature (T b ) ≤ 850 °C and excess air (XSA) ≤ 10 %. These values, together with the computed equilibrium conversion of alkali chlorides to sulfates, may suggest that sodium and potassium salts present in the vapor phase are likely to accelerate hot corrosion of heat exchange tubes above the bed when an FBC operates at T b ≤ 840 °C, XSA ≤ 20 %, d c 890 °C and XSA > 30 %, high oxidation rates may be present for the in-bed tubes. At these higher T b values and XSA < 10 %, a sulfidation mechanism presumably influences the extent of corrosion on the metallic components within the bed.

Concrete Carbonation in Mexico and Spain: DURACON Project, Four Year Evaluation

This work is part of the DURACON Ibero-American project, which seeks to characterize concrete durability under environmental conditions, based on reinforced concrete sample exposure in at least two different atmospheres (marine and urban), for each of the 11 countries in the project. Specimens were exposed to the environmental conditions of 13 Mexican sites (8 urban and 5 marine atmospheres). Concrete specimens were 15 x 15 x 30 cm, with 6 rebars each, and three concrete covers (15, 20 and 30 cm). Two concrete mixtures were used with water/cement ratios of 0.45 and 0.65, respectively. Six reinforced and six plain concrete specimens were placed on each exposure site. Environmental data was collected on each exposure site, including rainfall, relative humidity, time of wetness, temperature, wind velocity, and carbon dioxide/chloride concentrations. Corrosion rates and potentials, as well as concrete resistivity were measured in the reinforced samples. Carbonation depths were measured on the plain ones. The present work focused on the measurements of environmental parameters during the first two years of exposure to analyze the potentiality and the probability of carbonation-induced corrosion, and the evaluation of the corrosion initiation period for the reinforcing steel on the 13 Mexican exposure sites.