F. L. Sutherland

Alkaline rocks and gemstones, Australia: A review and synthesis

In Australia, valuable gemstones that occur in alkaline rocks include diamonds in lamproites and kimberlites and sapphires, zircons and rubies in alkali basalts. One gem zircon prospect is in carbonatite. This review combines geological and gemmological literature to discuss the tectonic settings and origins of Australian gem‐bearing alkaline rocks. Marked contrasts exist between diamond and sapphire/zircon associations across the continent. More western cratonic areas exhibit episodic, sparse, deep alkaline activity from the diamond zone (2 Ga‐20 Ma), while in eastern fold belt areas prolific Mesozoic/Cainozoic basalt volcanism carried up considerable sapphire and zircon (since 170 Ma). Some South Australian Mesozoic kimberlitic diamond events (180–170 Ma) represent ultra‐deep material rising through the mantle transition zone. Eastern Australian diamonds are unusual and at present their origin is contentious; Palaeozoic subductions that form young, shallow‐origin diamonds for later basaltic transport un...

Subduction model for the origin of some diamonds in the Phanerozoic of eastern New South Wales

Eastern New South Wales has produced over 500 000 carats of diamonds, mostly from the Copeton‐Bingara area in the north. A local derivation is indicated by their distinct tribal character and lack of surface damage, while carbon isotopic values and composition of mineral inclusions are unlike those in diamonds from conventional diamond‐producing areas, for example Yakutia (Siberia), Kapvaal (South Africa), or Argyle (Western Australia). The eastern New South Wales tectonic setting is also unlike that for ‘conventional’ diamonds, involving a Phanerozoic sequence of accreted subduction terranes, with relatively thin hot crust. A subduction diamond model is developed to explain the origin and geology of eastern New South Wales diamonds. This model involves prolonged subduction of mature oceanic crust, resulting in the development of a low‐temperature metamorphic window into the diamond stability field within the downgoing slab at half the depth required by conventional models. The diamonds are preserved at d...

Gem‐bearing basaltic volcanism, Barrington, New South Wales: Cenozoic evolution, based on basalt K–Ar ages and zircon fission track and U–Pb isotope dating

Barrington shield volcano was active for 55 million years, based on basalt K–Ar and zircon fission track dating. Activity in the northeast, at 59 Ma, preceded more substantial activity between 55 and 51 Ma and more limited activity on western and southern flanks after 45 Ma. Eruptions brought up megacrystic gemstones (ruby, sapphire and zircon) throughout the volcanism, particularly during quieter eruptive periods. Zircon fission track dating (thermal reset ages) indicates gem‐bearing eruptions at 57, 43, 38, 28 and 4–5 Ma, while U–Pb isotope SHRIMP dating suggests two main periods of zircon crystallisation between 60 and 50 Ma and 46–45 Ma. Zircons show growth and sector twinning typical of magmatic crystallisation and include low‐U, moderate‐U and high‐U types. The 46 Ma high‐U zircons exhibit trace and rare‐earth element patterns that approach those of zircon inclusions in sapphires and may mark a sapphire formation time at Barrington. Two Barrington basaltic episodes include primary lavas with trace‐element signatures suggesting amphibole/apatite‐enriched lithospheric mantle sources. Other basalts less‐enriched in Th, Sr, P and light rare‐earth elements have trace‐element ratios that overlap those of HIMU‐related South Tasman basalts. Zircon and sapphire formation is attributed to crystallisation from minor felsic melts derived by incipient melting of amphibole‐enriched mantle during lesser thermal activity. Ruby from Barrington volcano is a metamorphic type, and a metamorphic/metasomatic origin associated with basement ultramafic bodies is favoured. Migratory plate/plume paths constructed through Barrington basaltic episodes intersect approximately 80% of dated Palaeogene basaltic activity (65–30 Ma) along the Tasman margin (27–37°S) supporting a migratory plume‐linked origin. Neogene Barrington activity dwindled to sporadic gem‐bearing eruptions, the last possibly marking a minor plume trace. The present subdued thermal profile in northeastern New South Wales mantle suggests future Barrington activity will be minimal.

Gem-corundum megacrysts from east Australian basalt fields : trace elements, oxygen isotopes and origins

Gem corundum, a minor but persistent megacryst in east Australian basalt fields, is mined from some placer concentrations. Laser ablation, inductively coupled plasma mass spectrometry analyses and O isotope determinations on a colour range of corundum from different fields, show that chromophore (Fe, Cr, Ti, V) and genetic indicator (Ga, Mg, δ18O) values can distinguish corundum sources (magmatic, metamorphic and metasomatic) before basalt incorporation. They also characterise corundum groups from different fields. This identified two metamorphic groups, one carrying ruby at Barrington Tops, and a magmatic group distinct from those from other gem fields (lower Fe, northeast Tasmania; higher Fe, Yarrowitch). Ruby-bearing groups show clear provincial characteristics and include lower temperature spinel-facies groups (Barrington, Yarrowitch) and higher temperature garnet-facies groups (Cudgegong–Macquarie River). High Mg/Fe and Ni values in the latter approach those for corundum in diamond, and are a possible diamond indicator. The corundum derived from diverse fold-belt and felsic sources in underlying lithosphere forms a dataset for comparing corundum from other basalt fields.

Passive-margin prolonged volcanism, East Australian Plate: outbursts, progressions, plate controls and suggested causes.

Prolonged intraplate volcanism along the 4000 km-long East Australian margin for ca 100 Ma raises many genetic questions. Studies of the age-progressive pulses embedded in general basaltic activity have spawned a host of models. Zircon U–Pb dating of inland Queensland central volcanoes gives a stronger database to consider the structure and origin of Australian age-progressive volcanic chains. This assists appraisal of this volcanism in relation to plate motion and plate margin tectonic models. Inland Queensland central volcanoes progressed south-southeast from 34 to 31 Ma (∼5.4 cm/yr) until a surge in activity led to irregular southerly progression 31 to 28 Ma. A new inland southeastern Queensland central volcano line (25 to 22 Ma), from Bunya Mountains to North Main Range, followed 3 Ma behind the adjacent coastal progression. The Australian and Tasman Sea age-progressive chains are compared against recent plate motion modelling (Indian Ocean hotspots). The chain lines differ from general vector traces owing to west-facing swells and cessations in activity. Tectonic processes on the eastern plate margin may regulate these irregularities. These include subduction, rapid roll-back and progressive detachment of the Loyalty slab (43 to 15 Ma). West-flowing Pacific-type asthenosphere, related to perturbed mantle convection, may explain the west-facing volcanic surges. Such westward Pacific flow for over 28 Ma is known at the Australian–Antarctic Discordance, southeast of the present Australian plume sites under Bass Strait–West Tasman Sea. Most basaltic activity along eastern Australia marks asthenospheric melt injections into Tasman rift zone mantle and not lithospheric plate speed. The young (post-10 Ma) fields (Queensland, Victoria–South Australia) reflect new plate couplings, which altered mantle convection and stress regimes. These areas receive asthenospheric inputs from deep thermal zones off northeast Queensland and under Bass Strait.

K‐Ar ages of Cainozoic volcanic suites, Bowen‐St Lawrence Hinterland, North Queensland (with some implications for petrologic models)

Abstract Thirty K‐Ar dates on Cainozoic volcanic rocks lying at the north end of the Bowen Basin suggest that several episodes of volcanism took place at major structural weaknesses. The oldest volcanism (ca 54 m.y.) was located outside the basin structure. The main volcanism (Nebo and East Clermont Provinces) extended from early Oligocene (34–35 m.y.) to mid‐Cainozoic time (21–22 m.y.?). Isolated Pliocene activity is tentatively suggested by dates on Mt St Martin (ca 3 m.y.). Dating of the Nebo central volcano (31–33 m.y.) supports the model of Wellman & McDougall, with volcanic activity related to migration of Australia northwards over a mantle magma source. Consideration of the Nebo dates with those of other central volcanoes in north Queensland, suggests that central felsic activity was surrounded by broad zones of peripheral eruptives, petrologically zoned from outer undersaturated basalts to inner saturated basalts. These zones (super provinces) delineate the size and profile of underlying magma sou...

Al-rich diopside in alluvial ruby and corundum-bearing xenoliths, Australian and SE Asian basalt fields

Abstract Alluvial rubies and sapphires are found in palaeodrainage deposits along the Cudgegong-Macquarie River system, central eastern New South Wales, Australia. A pink to red suite contains Cr (up to 0.6 wt.% Cr2O3) as the main chromophore, exceeding Fe (up to 0.5 wt.%Fe2O3). Corrosive etching suggests a prior xenocrystic Mesozoic-Cenozoic basaltic transport, while Cr2O3/Ga2O3 to Fe2O3/TiO2 ratios indicate an original metamorphic source. Syngenetic mineral inclusions include Al-rich diopside, meionite and anatase. The Al-rich diopside (‘fassaite’) contains extremely high Al2O3 (20−1 wt.%). A blue-green suite contains Fe (up to 0.8 wt.% Fe2O3) as a dominant chromophore, while a rare nepheline-anorthoclase composite inclusion supports a magmatic phonolitic origin. The Cudgegong- Macquarie ruby formation is compared with a garnet granulite origin proposed for Thailand rubies and a xenolith of corundum-bearing garnet granulite from Ruby Hill, Bingara, Australia. Clinopyroxenecorundum thermometry suggests the Cudgegong-Macquarie rubies formed at T >1000−1300ºC, a high equilibration T for proposed lithospheric granulites. These rubies form a distinctive suite compared to other rubies from Australian and SE Asian basalt fields, but have some similarities with eastern Thailand rubies.

Gold- and diamond-bearing White Hills Gravel, St Arnaud district, Victoria: age and provenance based on U – Pb dating of zircon and rutile

Investigation of coarse (>2 mm) heavy-mineral concentrates from the White Hills Gravel near St Arnaud in western Victoria provides new evidence for the age and provenance of this widespread palaeoplacer formation. A prominent zircon – sapphire – spinel assemblage is characteristic of Cenozoic basaltic-derived gemfields in eastern Australia, while a single diamond shows similar features to others found in alluvial deposits in northeastern Victoria and New South Wales. Dating of two suites of zircons by fission track and U – Pb (SHRIMP) methods gave overlapping ages between 67.4 ± 5.2 and 74.5 ± 6.3 Ma, indicating a maximum age of Late Cretaceous for the formation. Another suite of minerals includes tourmaline (schorl – dravite), andalusite, rutile and anatase, which are probably locally derived from contact metamorphic aureoles in Cambro-Ordovician basement metapelites intruded by Early Devonian granites. U – Pb dating of rutile grains by laser ablation ICPMS gave an age of 393 ± 10 Ma, confirming an Early Devonian age for the regional granites and associated contact metamorphism. Other phases present include pseudorutile, metamorphic corundum of various types, maghemite and hematite, which have more equivocal source rocks. A model to explain the diverse sources of these minerals invokes recycling and mixing of the far-travelled basalt-derived suite with the less mature, locally derived metamorphic suite. Some minerals have probably been recycled from Mesozoic gravels through Early Cenozoic (Paleocene – Eocene) drainage systems during various episodes of weathering, ferruginisation and erosion. Comparison between heavy-mineral assemblages in occurrences of the White Hills Gravel may allow distinction between depositional models advocating either separate drainage networks or coalescing sheets. Such assemblages may also provide evidence for the present-day divide in the Western Uplands being the youngest expression of an old (Late Mesozoic – Early Cenozoic) stable divide separating north- and south-flowing streams or a much younger feature (ca 10 Ma) which disrupted mainly south-flowing drainage.

Spinel to garnet lherzolite transition in relation to high temperature palaeogeotherms, eastern Australia∗

Eastern Australian xenolith suites and lithospheric transition zones are re‐evaluated using new mineral analyses and thermo‐barometry. Some suites, including that defining the southeastern Australian geotherm, are not fully equilibrated. New pressure‐temperature estimates, based on experimental calibrations that allow for Cr and Ti in pyroxenes, differ from earlier results by up to 0.6 GPa and 250°C. The preferred Brey and Kohler 1990 thermo‐barometer indicates a shallower cooler garnet lherzolite transition under Mesozoic New South Wales (50 km depth at 980° C) than for Tertiary Tasmania (60 km depth at 1090°C). Deviations between palaeogeotherms may reflect: (i) higher temperature gradients for Tasmania and New South Wales (by 100°C/0.1 GPa) related to abnormally hot mantle; (ii) higher temperature gradients linked to more voluminous magmatism, largely Cenozoic in age; and (iii) complex temperature perturbations linked to different levels of magmatic intrusion. These deviations blur reconstructions of l...

Zircon megacryst ages and chemistry, from a placer, Dunedin volcanic area, eastern Otago, New Zealand

Abstract Zircon megacrysts from a sapphire‐bearing placer near Glenore, South Otago, New Zealand, gave U‐Pb ages linked to the Miocene Waipiata Volcanics. Yellow and brown (zoned) zircons gave ages almost within error of a mean age of 19.1 ± 0.2 Ma. Laser‐ablation inductively coupled plasma mass spectrometry analysis suggests these two zircons crystallised from separate magmas. The Ti‐in‐zircon thermometer gave different formation temperatures, between 550–685°C for yellow zircon and 700–730°C for brown zircon. The zircons have typical felsic chemistry, with positive Ce anomalies, while negligible Eu depletion indicates little plagioclase fractionation in their source magmas. Incompatible element values are enriched in the brown zircon. Such zircon megacrysts are rare in New Zealand, but they resemble east Australian zircons from basalt fields and may come from metasomatised mantle melts or fractionated alkali basalt magmas.