Fabio Arzilli

Role of syn-eruptive plagioclase disequilibrium crystallization in basaltic magma ascent dynamics

Timescales of magma ascent in conduit models are typically assumed to be much longer than crystallization and gas exsolution for basaltic eruptions. However, it is now recognized that basaltic magmas may rise fast enough for disequilibrium processes to play a key role on the ascent dynamics. The quantification of the characteristic times for crystallization and exsolution processes are fundamental to our understanding of such disequilibria and ascent dynamics. Here we use observations from Mount Etnas 2001 eruption and a magma ascent model to constrain timescales for crystallization and exsolution processes. Our results show that plagioclase reaches equilibrium in 1–2 h, whereas ascent times were <1 h. Using these new constraints on disequilibrium plagioclase crystallization we also reproduce observed crystal abundances for different basaltic eruptions. The strong relation between magma ascent rate and disequilibrium crystallization and exsolution plays a key role in controlling eruption dynamics in basaltic volcanism.

Gas-driven filter pressing in magmas: Insights into in-situ melt segregation from crystal mushes

Gas-driven filter pressing is the process of melt expulsion from a volatile-saturated crystal mush, induced by the buildup and subsequent release of gas pressure. Filter pressing is inferred to play a major role in magma fractionation at shallow depths (<10 km) by moving melt and gas relative to the solid, crystalline framework. However, the magmatic conditions at which this process operates remain poorly constrained. We present novel experimental data that illustrate how the crystal content of the mush affects the ability of gas-driven filter pressing to segregate melt. Hydrous haplogranite (2.1 wt% water in the melt) and dacite (4.2 wt% water in the melt) crystal mushes, with a wide range of crystallinities (34–80 vol% crystals), were investigated using in-situ, high-temperature (500–800 °C) synchrotron X-ray tomographic microscopy with high spatial (3 μm/pixel) and temporal resolution (∼8 s per three-dimensional data set). Our experimental results show that gas-driven filter pressing operates only below the maximum packing of bubbles and crystals (∼74 vol%). Above this threshold, the mush tends to fracture and gas escapes via fractures. Therefore, the efficiency of gas-driven filter pressing is promoted close to the percolation threshold and in situations where a mush inflates slowly relative to build-up of pressure and expulsion of melt. Such observations offer a likely explanation for the production of eruptible, crystal-poor magmas within Earth’s crust.

Viscosity measurements of crystallizing andesite from Tungurahua volcano (Ecuador)

Abstract Viscosity has been determined during isothermal crystallization of an andesite from Tungurahua volcano (Ecuador). Viscosity was continuously recorded using the concentric cylinder method and employing a Pt‐sheathed alumina spindle at 1 bar and from 1400°C to subliquidus temperatures to track rheological changes during crystallization. The disposable spindle was not extracted from the sample but rather left in the sample during quenching thus preserving an undisturbed textural configuration of the crystals. The inspection of products quenched during the crystallization process reveals evidence for heterogeneous crystal nucleation at the spindle and near the crucible wall, as well as crystal alignment in the flow field. At the end of the crystallization, defined when viscosity is constant, plagioclase is homogeneously distributed throughout the crucible (with the single exception of experiment performed at the lowest temperature). In this experiments, the crystallization kinetics appear to be strongly affected by the stirring conditions of the viscosity determinations. A TTT (Time‐Temperature‐Transformation) diagram illustrating the crystallization “nose” for this andesite under stirring conditions and at ambient pressure has been constructed. We further note that at a given crystal content and distribution, the high aspect ratio of the acicular plagioclase yields a shear‐thinning rheology at crystal contents as low as 13 vol %, and that the relative viscosity is higher than predicted from existing viscosity models. These viscosity experiments hold the potential for delivering insights into the relative influences of the cooling path, undercooling, and deformation on crystallization kinetics and resultant crystal morphologies, as well as their impact on magmatic viscosity.

CO2 flux from Javanese mud volcanism

Abstract Studying the quantity and origin of CO2 emitted by back‐arc mud volcanoes is critical to correctly model fluid‐dynamical, thermodynamical, and geochemical processes that drive their activity and to constrain their role in the global geochemical carbon cycle. We measured CO2 fluxes of the Bledug Kuwu mud volcano on the Kendeng Fold and thrust belt in the back arc of Central Java, Indonesia, using scanning remote sensing absorption spectroscopy. The data show that the expelled gas is rich in CO2 with a volume fraction of at least 16 vol %. A lower limit CO2 flux of 1.4 kg s−1 (117 t d−1) was determined, in line with the CO2 flux from the Javanese mud volcano LUSI. Extrapolating these results to mud volcanism from the whole of Java suggests an order of magnitude total CO2 flux of 3 kt d−1, comparable with the expected back‐arc efflux of magmatic CO2. After discussing geochemical, geological, and geophysical evidence we conclude that the source of CO2 observed at Bledug Kuwu is likely a mixture of thermogenic, biogenic, and magmatic CO2, with faulting controlling potential pathways for magmatic fluids. This study further demonstrates the merit of man‐portable active remote sensing instruments for probing natural gas releases, enabling bottom‐up quantification of CO2 fluxes.

Heterogeneous vesiculation of 2011 El Hierro xeno-pumice revealed by X-ray computed microtomography

During the first week of the 2011 El Hierro submarine eruption, abundant light-coloured pumiceous, high-silica volcanic bombs coated in dark basanite were found floating on the sea. The composition of the light-coloured frothy material (‘xeno-pumice’) is akin to that of sedimentary rocks from the region, but the textures resemble felsic magmatic pumice, leaving their exact mode of formation unclear. To help decipher their origin, we investigated representative El Hierro xeno-pumice samples using X-ray computed microtomography for their internal vesicle shapes, volumes, and bulk porosity, as well as for the spatial arrangement and size distributions of vesicles in three dimensions (3D). We find a wide range of vesicle morphologies, which are especially variable around small fragments of rock contained in the xeno-pumice samples. Notably, these rock fragments are almost exclusively of sedimentary origin, and we therefore interpret them as relicts an the original sedimentary ocean crust protolith(s). The irregular vesiculation textures observed probably resulted from pulsatory release of volatiles from multiple sources during xeno-pumice formation, most likely by successive release of pore water and mineral water during incremental heating and decompression of the sedimentary protoliths.

A novel protocol for resolving feldspar crystals in synchrotron X-ray microtomographic images of crystallized natural magmas and synthetic analogs

Abstract X-ray computed microtomography is a non-destructive imaging technique recognized in the geosciences as a powerful tool to investigate rock textures directly in three dimensions (3D) at the micrometer and sub-micrometer scale. The quantitative morphological and textural analysis of images requires segmentation and characterization of phases in the reconstructed volume based upon their gray levels (related to their relative X-ray attenuation) and/or morphological aspects. Often the differences in X-ray attenuation of some phases are so small that no contrast is observed in the reconstructed slices or, although the human eye can discern the differences between these phases, it is difficult, or sometimes impossible, to reliably segment and separately analyze these phases. Facing this challenge, we propose an experimental and computational procedure that allows the segmentation of phases with small density variations in geomaterials. By using an experimental protocol based on phase-contrast synchrotron X-ray microtomography combined with a customized 3D image processing procedure, we successfully segmented feldspar from the glassy matrix in both a natural volcanic sample and a synthetic analog. Our results demonstrate that crystallized natural volcanic rocks and synthetic analogs can be characterized by synchrotron X-ray phase-contrast microtomography and that phase-retrieval processing is an invaluable tool for the reconstruction of 3D multiphase textures.

Crystallisation in basaltic magmas revealed via in situ 4D synchrotron X-ray microtomography

Magma crystallisation is a fundamental process driving eruptions and controlling the style of volcanic activity. Crystal nucleation delay, heterogeneous and homogeneous nucleation and crystal growth are all time-dependent processes, however, there is a paucity of real-time experimental data on crystal nucleation and growth kinetics, particularly at the beginning of crystallisation when conditions are far from equilibrium. Here, we reveal the first in situ 3D time-dependent observations of crystal nucleation and growth kinetics in a natural magma, reproducing the crystallisation occurring in real-time during a lava flow, by combining a bespoke high-temperature environmental cell with fast synchrotron X-ray microtomography. We find that both crystal nucleation and growth occur in pulses, with the first crystallisation wave producing a relatively low volume fraction of crystals and hence negligible influence on magma viscosity. This result explains why some lava flows cover kilometres in a few hours from eruption inception, highlighting the hazard posed by fast-moving lava flows. We use our observations to quantify disequilibrium crystallisation in basaltic magmas using an empirical model. Our results demonstrate the potential of in situ 3D time-dependent experiments and have fundamental implications for the rheological evolution of basaltic lava flows, aiding flow modelling, eruption forecasting and hazard management.

Tephra From the 3 March 2015 Sustained Column Related to Explosive Lava Fountain Activity at Volcán Villarrica (Chile)

Villarrica Volcano in the Southern Andes of Chile has sustained persistent open conduit activity, associated with a dynamic lava lake since at least 1984-85. Increased seismic activity and degassing in August 2014 was followed by increased Strombolian activity starting in February 2015 and culminated with a 1.5 km-high lava fountain on 3 March 2015. This eruption produced tephra fallout, spatter agglutination, clastogenic lavas and mixed avalanche deposits. Field work carried out in 2017 and 2018 focused upon the tephra fallout deposits from the 3 March 2015 paroxysmal eruption. Tephra fall deposits produced by lava fountain and a rapid transition to sustained eruption column at Villarrica are here described for first time. Tephra dispersion was observed mostly southeast of the crater in a narrow, elongated, nearly-elliptic area. Minimum observed tephra loading was estimated to be 80-120 g/m2 at crosswind locations, while maximum load estimation was about 11,500 g/m2, at 7-9 km distance from the vent. At 6-8 km downwind, the tephra fall deposit consisted of a single black scoria layer, fall varied from a lapilli blanket at medial distances (9-19 km) to a few individual particles at distal sites (20-43 km). All samples are vitrophyric in texture, with a mineral assemblage of plagioclase (3-30 %), clinopyroxene (2-5 %), olivine (1-4 %) and scarce orthopyroxene (<1 %) phenocrysts. We estimate that 1.4 x 109 kg, equivalent to ~2.4 x 106 m3 of basaltic andesite tephra (52.8 to 54.7 SiO2 wt. %), were erupted within a period of about 16 minutes at a mass eruption rate of ~1.5 x 106 kg/s. The sustained eruption column height was estimated at ~10.8 km, with magnitude and intensity of 2.11 and 9.13 respectively. We propose that a rejuvenated, volatile-rich magmatic intrusion is the probable triggering factor for the paroxysm. The Villarrica eruption is classified as a short-lived, large-scale lava fountain, similar to intense historical lava fountains at Mt. Etna and Kilauea. As evident by devastating 20th century Villarrica eruptions which also developed similar lava fountain behavior, this eruption style should be considered as frequent and a potential source of volcanic hazard in the future.

Natural and laboratory compaction band in porous carbonates: a 3D characterization using synchrotron X-ray microtomography

Lucchi, Renata G. ... et. al.-- 87° Congresso della Societa Geologica Italiana e 90° Congresso della Societa Italiana di Mineralogia e Petrologia, The Future of the Italian Geosciences - The Italian Geosciences of the Future, 10-12 September 2014, Milan, Italy.-- 1 pageThe Montellina Spring (370 m a.s.l.) represents an example of groundwater resource in mountain region. It is a significant source of drinking water located in the right side of the Dora Baltea Valley (Northwestern Italy), SW of Quincinetto town. This spring shows a morphological location along a ridge, 400 m from the Renanchio Torrent in the lower sector of the slope. The spring was investigated using various methodologies as geological survey, supported by photo interpretation, structural reconstruction, NaCl and fluorescent tracer tests, discharge measurements. This multidisciplinary approach, necessary due to the complex geological setting, is required for the importance of the Montellina Spring. It is interesting in the hydrogeological context of Western Alps for its high discharge, relatively constant over time (average 150 l/s), and for its location outside a fluvial incision and suspended about 40 m above the Dora Baltea valley floor (Lasagna et al. 2013). According to the geological setting, the hydrogeological reconstruction of the area suggests that the large amount of groundwater in the basin is essentially favoured by a highly fractured bedrock, covered by wide and thick bodies of glacial and gravitational sediments. The emergence of the water along the slope, in the Montellina Spring, is essentially due to a change of permeability between the deep bedrock and the shallow bedrock and/or surficial sediments. The deep bedrock, showing closed fractures and/or fractures filled by glacial deposits, is slightly permeable. The shallow bedrock, strongly loosened as result of gravitational phenomena, and the local gravitational sediments are, on the contrary, highly permeable. The concentration of water at the spring is due to several reasons. a) The spring is immediately downward a detachment niche, dipping towards the spring, that essentially drains the water connected to the change of permeability in the bedrock. b) It is along an important fracture, that carries a part of the losses of the Renanchio Torrent. c) Finally, it is favored by the visible and buried morphology. Although it is located along a ridge, the spring occurs in a small depression between a moraine and a landslide body. It also can be favored by the likely concave trend of buried base of the landslide. At last, tracer tests of the Renanchio Torrent water with fluorescent tracer are performed, with a continuous monitoring in the Montellina Spring. The surveys permit to verify and quantify the spring and torrent hydrogeological relationship, suggesting that only a small fraction of stream losses feeds the spring.