Fayuan Chen

Transformation characteristics of refractory pollutants in plugboard wastewater by an optimal electrocoagulation and electro-Fenton process

The treatment of the plugboard wastewater was performed by an optimal electrocoagulation and electro-Fenton. The organic components with suspended fractions accounting for 30% COD were preferably removed via electrocoagulation at initial 5 min. In contrast, the removal efficiency was increased to 76% with the addition of H(2)O(2). The electrogenerated Fe(2+) reacts with H(2)O(2) and leads to the generation of (·)OH, which is responsible for the higher COD removal. However, overdosage H(2)O(2) will consume (·)OH generated in the electro-Fenton process and lead to the low COD removal. The COD removal efficiency decreased with the increased pH. The concentration of Fe(2+) ions was dependent on the solution pH, H(2)O(2) dosage and current density. The changes of organic characteristics in coagulation and oxidation process were differenced and evaluated using gel permeation chromatography, fluorescence excitation-emission scans and Fourier transform infrared spectroscopy. The fraction of the wastewater with aromatic structure and large molecular weight was decomposed into aliphatic structure and small molecular weight fraction in the electro-Fenton process.

Efficient treatment of an electroplating wastewater containing heavy metal ions, cyanide, and organics by H2O2 oxidation followed by the anodic Fenton process

A real electroplating wastewater, containing heavy metals, cyanide, and organic contaminants, was treated by electrocoagulation (EC), H2O2 oxidation, H2O2 pre-oxidation followed by EC, and the anodic Fenton process and the efficacy of the processes was compared. Concentration of cyanide, Cu, Ni, Zn, and Cr was largely decreased by EC within 5 min. When the reaction time was extended, removal of residual cyanide, Cu, and Ni was limited. In H2O2 oxidation, the concentration of cyanide decreased from initial 75 to 12 mg L(-1) in 30 min. The effluents from the H2O2 oxidation were further treated by EC or anodic Fenton. In EC, the concentration of total cyanide, Ni, and Cu decreased to below 0.3, 0.5, and 1.5 mg L(-1), respectively. Removal efficiency of chemical oxygen demand by EC was less than 20.0%. By contrast, there was 73.5% reduction by the anodic Fenton process with 5 mM H2O2 at 30 min; this can be attributed to the oxidation induced by hydroxyl radicals generated by the reaction of H2O2 with the electrogenerated Fe(2+). Meanwhile, residual cyanide, Cu, and Ni can also be efficiently removed. Transformation of organic components in various processes was analyzed using UV-visible and fluorescence excitation-emission spectra.

Landscape Classifications for Landscape Metrics-based Assessment of Urban Heat Island: A Comparative Study

In recent years, some studies have been carried out on the landscape analysis of urban thermal patterns. With the prevalence of thermal landscape, a key problem has come forth, which is how to classify thermal landscape into thermal patches. Current researches used different methods of thermal landscape classification such as standard deviation method (SD) and R method. To find out the differences, a comparative study was carried out in Xiamen using a 20-year winter time-serial Landsat images. After the retrieval of land surface temperature (LST), the thermal landscape was classified using the two methods separately. Then landscape metrics, 6 at class level and 14 at landscape level, were calculated and analyzed using Fragstats 3.3. We found that: (1) at the class level, all the metrics with SD method were evened and did not show an obvious trend along with the process of urbanization, while the R method could. (2) While at the landscape level, 6 of the 14 metrics remains the similar trends, 5 were different at local turn points of the curve, 3 of them differed completely in the shape of curves. (3) When examined with visual interpretation, SD method tended to exaggerate urban heat island effects than the R method.