Felix A. Pollock

A multi-site variational master equation approach to dissipative energy transfer

Unitary transformations can allow one to study open quantum systems in situations for which standard, weak-coupling type approximations are not valid. We develop here an extension of the variational (polaron) transformation approach to open system dynamics, which applies to arbitrarily large exciton transport networks with local environments. After deriving a time-local master equation in the transformed frame, we go on to compare the population dynamics predicted using our technique with other established master equations. The variational frame dynamics are found to agree with both weak coupling and full polaron master equations in their respective regions of validity. In parameter regimes considered difficult for these methods, the

Enhancing the Charging Power of Quantum Batteries

Can collective quantum effects make a difference in a meaningful thermodynamic operation? Focusing on energy storage and batteries, we demonstrate that quantum mechanics can lead to an enhancement in the amount of work deposited per unit time, i.e., the charging power, when N batteries are charged collectively. We first derive analytic upper bounds for the collective quantum advantage in charging power for two choices of constraints on the charging Hamiltonian. We then demonstrate that even in the absence of quantum entanglement this advantage can be extensive. For our main result, we provide an upper bound to the achievable quantum advantage when the interaction order is restricted; i.e., at most k batteries are interacting. This constitutes a fundamental limit on the advantage offered by quantum technologies over their classical counterparts.

Dissipation enhanced vibrational sensing in an olfactory molecular switch

Motivated by a proposed olfactory mechanism based on a vibrationally activated molecular switch, we study electron transport within a donor-acceptor pair that is coupled to a vibrational mode and embedded in a surrounding environment. We derive a polaron master equation with which we study the dynamics of both the electronic and vibrational degrees of freedom beyond previously employed semiclassical (Marcus-Jortner) rate analyses. We show (i) that in the absence of explicit dissipation of the vibrational mode, the semiclassical approach is generally unable to capture the dynamics predicted by our master equation due to both its assumption of one-way (exponential) electron transfer from donor to acceptor and its neglect of the spectral details of the environment; (ii) that by additionally allowing strong dissipation to act on the odorant vibrational mode, we can recover exponential electron transfer, though typically at a rate that differs from that given by the Marcus-Jortner expression; (iii) that the ability of the molecular switch to discriminate between the presence and absence of the odorant, and its sensitivity to the odorant vibrational frequency, is enhanced significantly in this strong dissipation regime, when compared to the case without mode dissipation; and (iv) that details of the environment absent from previous Marcus-Jortner analyses can also dramatically alter the sensitivity of the molecular switch, in particular, allowing its frequency resolution to be improved. Our results thus demonstrate the constructive role dissipation can play in facilitating sensitive and selective operation in molecular switch devices, as well as the inadequacy of semiclassical rate equations in analysing such behaviour over a wide range of parameters.

An Introduction to Operational Quantum Dynamics

In the summer of 2016, physicists gathered in Torun, Poland for the 48th annual Symposium on Mathematical Physics. This Symposium was special; it celebrated the 40th anniversary of the discovery of the Gorini-Kossakowski-Sudarshan-Lindblad master equation, which is widely used in quantum physics and quantum chemistry. This article forms part of a Special Volume of the journal Open Systems & Information Dynamics arising from that conference; and it aims to celebrate a related discovery -- also by Sudarshan -- that of Quantum Maps (which had their 55th anniversary in the same year). Nowadays, much like the master equation, quantum maps are ubiquitous in physics and chemistry. Their importance in quantum information and related fields cannot be overstated. In this manuscript, we motivate quantum maps from a tomographic perspective, and derive their well-known representations. We then dive into the murky world beyond these maps, where recent research has yielded their generalisation to non-Markovian quantum processes.

Coherent measurements in quantum metrology

It is well known that a quantum correlated probe can yield better precision in estimating an unknown parameter than classically possible. However, how such a quantum probe should be measured remains somewhat elusive. We examine the role of measurements in quantum metrology by considering two types of readout strategies: coherent, where all probes are measured simultaneously in an entangled basis; and adaptive, where probes are measured sequentially, with each measurement one way conditioned on the prior outcomes. Here we firstly show that for classically correlated probes the two readout strategies yield the same precision. Secondly, we construct an example of a noisy multipartite quantum system where coherent readout yields considerably better precision than adaptive readout. This highlights a fundamental difference between classical and quantum parameter estimation. From the practical point of view, our findings are relevant for the optimal design of precision-measurement quantum devices.

Non-Markovian quantum control as coherent stochastic trajectories

We develop a notion of stochastic quantum trajectories. First, we construct a basis set of trajectories,called elementary trajectories, and go on to show that any quantum dynamical process, including those that are non-Markovian, can be expressed as a linear combination of this set. We then show that the set of processes divide into two natural classes: those that can be expressed as convex mixture of elementary trajectories and those that cannot be. The former are shown to be entanglement breaking processes (in each step), while the latter are dubbed coherent processes. This division of processes is analogous to separable and entangled states. In the second half of the paper, we show, with an information theoretic game, that when a process is non-Markovian, coherent trajectories allow for decoupling from the environment while preserving arbitrary quantum information encoded into the system. We give explicit expressions for the temporal correlations(quantifying non-Markovianity) and show that, in general, there are more quantum correlations than classical ones. This shows that non-Markovian quantum processes are indeed fundamentally different from their classical counterparts. Furthermore, we demonstrate how coherent trajectories (with the aid of coherent control) can turn non-Markovianity into a resource. In the final section of the paper we explore this phenomenon in a geometric picture with a convenient set of basis trajectories.

How Does Interference Fall

We study how single- and double-slit interference patterns fall in the presence of gravity. First, we demonstrate that universality of free fall still holds in this case, i.e., interference patterns fall just like classical objects. Next, we explore lowest order relativistic effects in the Newtonian regime by employing a recent quantum formalism which treats mass as an operator. This leads to interactions between non-degenerate internal degrees of freedom (like spin in an external magnetic field) and external degrees of freedom (like position). Based on these effects, we present an unusual phenomenon, in which a falling double slit interference pattern periodically decoheres and recoheres. The oscillations in the visibility of this interference occur due to correlations built up between spin and position. Finally, we connect the interference visibility revivals with non-Markovian quantum dynamics.

Divisible quantum dynamics satisfies temporal Tsirelson's bound

We give strong evidence that divisibility of qubit quantum processes implies temporal Tsirelsons bound. We also give strong evidence that the classical bound of the temporal Bells inequality holds for dynamics that can be described by entanglement-breaking channels---a more general class of dynamics than that allowed by classical physics.

Quantum capacitance and charge sensing of a superconducting double dot

We study the energetics of a superconducting double dot, by measuring both the quantum capacitance of the device and the response of a nearby charge sensor. We observe different behaviour for odd and even charge states and describe this with a model based on the competition between the charging energy and the superconducting gap. We also find that, at finite temperatures, thermodynamic considerations have a significant effect on the charge stability diagram.

Tomographically reconstructed master equations for any open quantum dynamics

Memory effects in open quantum dynamics are often incorporated in the equation of motion through a superoperator known as the memory kernel, which encodes how past states affect future dynamics. However, the usual prescription for determining the memory kernel requires information about the underlying system-environment dynamics. Here, by deriving the transfer tensor method from first principles, we show how a memory kernel master equation, for any quantum process, can be entirely expressed in terms of a family of completely positive dynamical maps. These can be reconstructed through quantum process tomography on the system alone, either experimentally or numerically, and the resulting equation of motion is equivalent to a generalised Nakajima-Zwanzig equation. For experimental settings, we give a full prescription for the reconstruction procedure, rendering the memory kernel operational. When simulation of an open system is the goal, we show how our procedure yields a considerable advantage for numerically calculating dynamics, even when the system is arbitrarily periodically (or transiently) driven or initially correlated with its environment. Namely, we show that the long time dynamics can be efficiently obtained from a set of reconstructed maps over a much shorter time.