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Dive into the research topics where Fengjuan Zhu is active.

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Featured researches published by Fengjuan Zhu.


ACS Applied Materials & Interfaces | 2016

Soft-Templated Self-Assembly of Mesoporous Anatase TiO2/Carbon Composite Nanospheres for High-Performance Lithium Ion Batteries

Ruofei Wu; Shuiyun Shen; Guofeng Xia; Fengjuan Zhu; Christian M. Lastoskie; Junliang Zhang

Mesoporous anatase TiO2/carbon composite nanospheres (designated as meso-ATCCNs) were successfully synthesized via a facile soft-templated self-assembly followed by thermal treatment. Structural and morphological analyses reveal that the as-synthesized meso-ATCCNs are composed of primary TiO2 nanoparticles (∼5 nm), combined with in situ deposited carbon either on the surface or between the primary TiO2 nanoparticles. When cycled in an extended voltage window from 0.01 to 3.0 V, meso-ATCCNs exhibit excellent rate capabilities (413.7, 289.7, and 206.8 mAh g(-1) at 200, 1000, and 3000 mA g(-1), respectively) as well as stable cyclability (90% capacity retention over 500 cycles at 1000 mA g(-1)). Compared with both mesoporous TiO2 nanospheres and bulk TiO2, the superior electrochemical performance of the meso-ATCCNs electrode could be ascribed to a synergetic effect induced by hierarchical structure that includes uniform TiO2 nanoparticles, the presence of hydrothermal carbon derived from phenolic resols, a high surface area, and open mesoporosity.


RSC Advances | 2014

Soft-templated LiFePO4/mesoporous carbon nanosheets (LFP/meso-CNSs) nanocomposite as the cathode material of lithium ion batteries

Ruofei Wu; Guofeng Xia; Shuiyun Shen; Fengjuan Zhu; Fengjing Jiang; Junliang Zhang

A novel and facile in situ soft-templated method is proposed for synthesizing a LFP/mesoporous carbon nanosheets (LFP/meso-CNSs) nanocomposite, which involves solvent evaporation induced self-assembly of triblock copolymers, with resol and inorganic salts as co-precursors of CNSs and LFP, followed by a heat treatment. The LFP/meso-CNSs nanocomposite displays an excellent high-rate capability (122.1 mA h g−1 at 5 C and 102.1 mA h g−1 at 10 C) and stable cycling property as the cathode material of lithium ion batteries, benefitting from its high electronic conductivity, open mesoporosity, and the nano-size of its active material.


Scientific Reports | 2017

The respective effect of under-rib convection and pressure drop of flow fields on the performance of PEM fuel cells

Chao Wang; Qinglei Zhang; Shuiyun Shen; Xiaohui Yan; Fengjuan Zhu; Xiaojing Cheng; Junliang Zhang

The flow field configuration plays an important role on the performance of proton exchange membrane fuel cells (PEMFCs). For instance, channel/rib width and total channel cross-sectional area determine the under-rib convection and pressure drop respectively, both of which directly influence the water removal, in turn affecting the oxygen supply and cathodic oxygen reduction reaction. In this study, effects of under-rib convection and pressure drop on cell performance are investigated experimentally and numerically by adjusting the channel/rib width and channel cross-sectional area of flow fields. The results show that the performance differences with various flow field configurations mainly derive from the oxygen transport resistance which is determined by the water accumulation degree, and the cell performance would benefit from the narrower channels and smaller cross sections. It reveals that at low current densities when water starts to accumulate in GDL at under-rib regions, the under-rib convection plays a more important role in water removal than pressure drop does; in contrast, at high current densities when water starts to accumulate in channels, the pressure drop dominates the water removal to facilitate the oxygen transport to the catalyst layer.


Nano Research | 2018

Facile preparation of unique three-dimensional (3D) α-MnO2/MWCNTs macroporous hybrid as the high-performance cathode of rechargeable Li-O2 batteries

Shuiyun Shen; Aiming Wu; Guofeng Xia; Guanghua Wei; Xiaohui Yan; Yao Zhang; Fengjuan Zhu; Jiewei Yin; Junliang Zhang

Undoubtedly, there remains an urgent prerequisite to achieve significant advances in both the specific capacity and cyclability of Li-O2 batteries for their practical application. In this work, a series of unique three-dimensional (3D) α-MnO2/MWCNTs hybrids are successfully prepared using a facile lyophilization method and investigated as the cathode of Li-O2 batteries. Thereinto, cross-linked α-MnO2/MWCNTs nanocomposites are first synthesized via a modified chemical route. Results demonstrate that MnO2 nanorods in the nanocomposites have a length of 100–400 nm and a diameter ranging from 5 to 10 nm, and more attractively, the as-lyophilized 3D MnO2/MWCNTs hybrids is uniquely constructed with large amounts of interconnected macroporous channels. The Li-O2 battery with the 3D macroporous hybrid cathode that has a mass percentage of 50% of α-MnO2 delivers a high discharge specific capacity of 8,643 mAh·g−1 at 100 mA·g−1, and maintains over 90 cycles before the discharge voltage drops to 2.0 V under a controlled specific capacity of 1,000 mAh·g−1. It is observed that when being recharged, the product of toroidal Li2O2 particles disappears and electrode surfaces are well recovered, thus confirming a good reversibility. The excellent performance of Li-O2 battery with the 3D α-MnO2/MWCNTs macroporous hybrid cathode is ascribed to a synergistic combination between the unique macroporous architecture and highly efficient bi-functional α-MnO2/MWCNTs electrocatalyst.


Chemsuschem | 2018

Icosahedral Pt-Ni Nanocrystalline Electrocatalyst: Growth Mechanism and Oxygen Reduction Activity

Renxiu Tian; Shuiyun Shen; Fengjuan Zhu; Liuxuan Luo; Xiaohui Yan; Guanghua Wei; Junliang Zhang

Engineering the structure of Pt alloy offers an effective way to the design of high performance electrocatalysts. Herein, we synthesize a sandwich-structured, icosahedral Pt2.1 Ni catalyst through a hot injection method. Its growth involves three steps: 1) burst nucleation of Pt atoms to form a Pt-enriched core, 2) heterogeneous nucleation of Ni atoms onto the Pt core to form a Ni-enriched interlayer, and 3) kinetic controlled growth of a Pt-enriched shell. The Pt-enriched core protects the nanostructure from collapse and mitigates the strain change caused by lattice mismatch, and thus enhances the stability of the structure. The Ni-enriched interlayer induces the electronic modification of the outermost Pt shell, and in turn tunes the activity. The Pt-enriched shell provides more active sites through the exposure of (1 1 1) facets and retards the dissolution of Ni atoms. As a result, this sandwich-structure enables impressive electrocatalytic activity (0.91 mA cm-2 and 0.32 AmgPt-1 @ 0.9 V) and duability.


ACS Applied Materials & Interfaces | 2014

Enzyme-Labeled Pt@BSA Nanocomposite as a Facile Electrochemical Biosensing Interface for Sensitive Glucose Determination

Chenyi Hu; Da-Peng Yang; Fengjuan Zhu; Fengjing Jiang; Shuiyun Shen; Junliang Zhang


Renewable Energy | 2016

Experimental investigation on a MnCl2–CaCl2–NH3 thermal energy storage system

Liyan Jiang; Fengjuan Zhu; L.W. Wang; C.Z. Liu; R.Z. Wang


Applied Energy | 2016

Experimental investigation on a MnCl2CaCl2NH3 resorption system for heat and refrigeration cogeneration

Fengjuan Zhu; Liyan Jiang; L.W. Wang; R.Z. Wang


Electrochimica Acta | 2015

In-situ growth of LiFePO4 nanocrystals on interconnected carbon nanotubes/mesoporous carbon nanosheets for high-performance lithium ion batteries

Ruofei Wu; Guofeng Xia; Shuiyun Shen; Fengjuan Zhu; Fengjing Jiang; Junliang Zhang


ACS Catalysis | 2017

Composition-Graded PdxNi1–x Nanospheres with Pt Monolayer Shells as High-Performance Electrocatalysts for Oxygen Reduction Reaction

Liuxuan Luo; Fengjuan Zhu; Renxiu Tian; Lin Li; Shuiyun Shen; Xiaohui Yan; Junliang Zhang

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Junliang Zhang

Shanghai Jiao Tong University

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Shuiyun Shen

Shanghai Jiao Tong University

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Guofeng Xia

Shanghai Jiao Tong University

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Xiaohui Yan

Shanghai Jiao Tong University

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Ruofei Wu

Shanghai Jiao Tong University

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Chao Wang

Shanghai Jiao Tong University

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Fengjing Jiang

Shanghai Jiao Tong University

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L.W. Wang

Shanghai Jiao Tong University

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Liuxuan Luo

Shanghai Jiao Tong University

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Liyan Jiang

Shanghai Jiao Tong University

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