Florentin Maurrasse

Coeval 40Ar/39Ar Ages of 65.0 Million Years Ago from Chicxulub Crater Melt Rock and Cretaceous-Tertiary Boundary Tektites

40Ar/39Ar dating of drill core samples of a glassy melt rock recovered from beneath a massive impact breccia contained within the 180-kilometer subsurface Chicxulub crater in Yucat�n, Mexico, has yielded well-behaved incremental heating spectra with a mean plateau age of 64.98 � 0.05 million years ago (Ma). The glassy melt rock of andesitic composition was obtained from core 9 (1390 to 1393 meters) in the Chicxulub 1 well. The age of the melt rock is virtually indistinguishable from 40Ar/39Ar ages obtained on tektite glass from Beloc, Haiti, and Arroyo el Mimbral, northeastern Mexico, of 65.01 � 0.08 Ma (mean plateau age for Beloc) and 65.07 � 0.10 Ma (mean total fusion age for both sites). The 40Ar/39Ar ages, in conjunction with geochemical and petrological similarities, strengthen the recent suggestion that the Chicxulub structure is the source for the Haitian and Mexican tektites and is a viable candidate for the Cretaceous-Tertiary boundary impact site.

Pleistocene sea levels from raised coral reefs of haiti.

The elevations and ages of a sequence of three uplifted Pleistocene coral reefs on the Northwest Peninsula of Haiti have been determined. With the assignment of a sea level of +6 meters (relative to the present day) at 130,000 years before present and constant uplift of the reefs, the data indicate that sea level stood –10 and –13 meters at 108,000 and 81,000 years before present, respectively. These results are in substantial agreement with those reported for Barbados and New Guinea and support the hypothesis of constant uplift for each area. Sea level data from raised reefs indicate that the interglacial marine oxygen isotope oscillations during oxygen isotope stage 5 are a result of 30 percent ice volume effects and 70 percent temperature effects.

Kinetics of chromium (VI) reduction by a type strain Shewanella alga under different growth conditions.

We conducted kinetic batch experiments to determine the reduction of Chromium(VI) by a type strain of Shewanella alga (BrY-MT) ATCC 55627. Chromium(VI) was reduced to Chromium(III) by BrY-MT grown in three different substrates: BHIB (brain heart infusion broth), TSB (tryptic soy broth), and M9 (minimum broth). Four different Cr(VI) concentrations 4.836, 10.00, 37.125, and 260.00 mg l-1 were reduced at different rates by BrY-MT in both aerobic and anaerobic conditions. BrY-MT grown in BHIB reduced the maximum amount of Cr(VI) followed by TSB and M9. Carbondioxide produced from bacterial respiration varied with and without Cr(VI) under both aerobic and anaerobic conditions. The Cr(VI) reduction data under anaerobic condition was fitted by a monod model to determine the bacterial kinetic parameters. The kinetic parameters determined by fitting the anaerobic experimental data were used to run a forward simulation for experiments conducted under aerobic conditions. The monod model was modified to account for an inhibition parameter for the Cr(VI) experiment at 260 mg l-1. All the parameters varied within a narrow range, and were distinct for different substrates. Our studies show that, successful in situ bioremediation of Cr(VI) is depended on the type of substrates (electron donors) and the concentration of Cr(VI) in geologic medium.

Impacts, tsunamis, and the haitian cretaceous-tertiary boundary layer.

The marker bed at the Cretaceous-Tertiary boundary of the Beloc Formation (southern Haiti) contains abundant coarse-grained microtektites and minor amounts of shocked quartz grains in the basal part. The upper part is composed of medium-grained marl with amalgamated microtektite lenses and finer-grained marl lenses disseminated throughout. Field and petrographic observations, and the distribution of planktonic foraminifera suggest that the bed formed from a complex sequence of events. A bolide impact nearby produced microtektites that sett1led to form a nearly pure layer at the base. Vaporized materials with anomalously high extraterrestrial components settled last, along with carbonate sediments. The entire bed became sparsely consolidated. Subsequently, another major disruptive event, perhaps a giant tsunami, partly reworked the initial deposit. Cohesive fragments of the original marker bed mixed with exotic materials were redeposited as lenticular bodies. This process also may have caused further mixing of Cretaceous and Tertiary microfossils, as observed at Beloc and elsewhere.

Geochemistry of basalts from the Dumisseau Formation, southern Haiti: implications for the origin of the Caribbean Sea crust

Abstract Basalt and diabase from the Cretaceous Dumisseau Formation, southern Haiti have Mg-numbers of 43–63, TiO 2 contents of 1.6–3.9% and La abundances of 3.6–15.3 ppm. La/Ta ratios average 10, and indicate that the basalts are oceanic in character, distinct from the arc associations forming the northern part of Haiti. Oldest lavas have low TiO 2 (1.6%) and are LREE-depleted, similar to N-MORBs, whereas overlying lavas have higher TiO 2 (2–3.9%) and are LREE-enriched, similar to E-MORBs or hotspot basalts. 87 Sr 86 Sr ratios vary from 0.70280 to 0.70316, 143 Nd 144 Nd from 0.512929 to 0.513121, and 206 Pb 204 Pb from 19.00 to 19.27. LREE-depleted lavas have high 143 Nd 144 Nd (0.51309–0.51310) typical of MORBs, whereas 143 Nd 144 Nd in the LREE-enriched lavas varies widely (0.512929–0.513121). Chemical features of the Dumisseau basalts are equivalent to those of Caribbean seafloor basalts recovered on DSDP Leg 15, and support the contention that the Dumisseau is an uplifted section of Caribbean Sea crust. Oldest lavas are analogous to MORB-like basalts cored at Leg 15 Sites 146, 150, 152 and 153, and the overlying lavas are analogous to incompatible-element-enriched basalts cored at Site 151 on the Beata Ridge. Isotopic compositions of the Dumisseau basalts overlap with those of the eastern Pacific Galapagos and Easter Island hotspots. However, the presence of N-MORB basalts in the lower part of the Dumisseau and at the majority of Leg 15 Sites indicates that the anomalously thick Caribbean crust probably did not originate as a hotspot-related basaltic plateau, but may have been generated by on-ridge or near-ridge hotspot magmatism.

Lower Aptian ammonite biostratigraphy in the Maestrat Basin (Eastern Iberian Chain, Eastern Spain). A Tethyan transgressive record enhanced by synrift subsidence

The present paper analyses the stratigraphic distribution of ammonites collected in the Lower Aptian sediments of the Maestrat Basin (E Spain). The faunal successions obtained from the systematic sampling of ten selected sections located in several sub basins led us to identify four biostratigraphic units (from base to top: Deshayesites oglanlensis, Deshayesites forbesi, Deshayesites deshayesi and Dufrenoyia furcata Zones) that are directly correlatable with the current Mediterranean standard zonation. This study further provides essential biochronologic information to accurately date the different lithostratigraphic units included in the interval studied. Thus, the upper part of the Xert Formation can be tentatively attributed to the lowermost Aptian (D. oglanlensis Zone). The Forcall Formation, which has yielded most of the ammonites, practically extends within most of the Lower Aptian. Its lower and middle parts (Cap de Vinyet and Barra de Morella Members) correspond to the upper part of the D. oglanlensis Zone and the lower part of the D. forbesi Zone, respectively. The base of the Morella la Vella Member (upper part of the Forcall Formation) includes the local record of Oceanic Anoxic Event 1a (OAE 1a) and correlates with the Roloboceras hambrovi horizon (middle/upper part of the D. forbesi Zone). The boundary between the Forcall Formation and the Villarroya de los Pinares Formation is diachronous and varies depending on the sub-basins. The base of the Villarroya de los Pinares Formation can be dated as the middle-upper part of the D. furcata Zone in the Galve, Perello and Salzedella sub-basins.

Microbiological reduction of chromium(VI) in presence of pyrolusite-coated sand by Shewanella alga Simidu ATCC 55627 in laboratory column experiments

Hexavalent chromium (Cr(VI)) was reduced to non-toxic trivalent chromium (Cr(III)) by a dissimilatory metal reducing bacteria, Shewanella alga Simidu (BrY-MT) ATCC 55627. A series of dynamic column experiments were conducted to provide an understanding of Cr(VI) reduction by the facultative anaerobe BrY-MT in the presence of pyrolusite (beta-MnO(2)) coated sand and uncoated-quartz sand. All dynamic column experiments were conducted under growth conditions using Cr(VI) as the terminal electron acceptor and lactate as the electron donor and energy source. Reduction of Cr(VI) was rapid (within 8 h) in columns packed with uncoated quartz sand and BrY-MT, whereas Cr(VI) reduction by BrY-MT was delayed (57 h) in the presence of beta-MnO(2)-coated sand. The role of beta-MnO(2) in this study was to provide oxidation of trivalent chromium (Cr(III)). BrY-MT attachment was higher on beta-MnO(2)-coated sand than on uncoated quartz sand at 10, 60, and 85.5 h. Results have shown that this particular strain of Shewanella did not appreciably reduce Mn(IV) to Mn(II) species nor biosorbed Cr and Mn during its metabolic activities.

Lower Aptian ammonite and carbon isotope stratigraphy in the eastern Prebetic Domain (Betic Cordillera, southeastern Spain)

Major global palaeobiologic and palaeoenvironmental changes occurred during the Early Aptian. Precise dating and timing of the different events is crucial to determine possible cause-effect relationships between them. In this regard, the combination of biostratigraphic and chemostratigraphic data can provide a very useful tool for time control. So far attempts to correlate the Lower Aptian carbon isotope record and the ammonite zonation yielded contradictory conclusions. In this paper, we present the results of an integrated analysis of the ammonite stratigraphic distribution and highresolution carbon isotope profiles from Lower Aptian sections of the eastern Prebetic Domain (Betic Cordillera, southeastern Spain). We recognized, in ascending order, the Deshayesites oglanlensis, Deshayesites forbesi, Deshayesites deshayesi, and Dufrenoyia furcata Zones. This succession is the same as that recently identified in the eastern Iberian Chain, and it closely correlates with both standard Mediterranean and Boreal zonations. The carbon isotope record displays the trends globally recognized for the Early Aptian, with two long positive shifts separated by a pronounced negative excursion. Calibration of this isotopic record with the ammonite zonation shows that the age of OAE 1a, which corresponds to the negative excursion and subsequent positive shift, is constrained to the middle/upper part of the Deshayesites forbesi Zone.

Nanofósiles del límite Cretácico/Terciario cerca de Beloc (Haití): bioestratigrafía, composición de las asociaciones e implicaciones paleoclimáticas

Los materiales de la Formacion Beloc, en la Peninsula Meridional de Haiti, presentan un buen registro del limite Cretacico/Terciario, e incluyen un nivel esferulitico resultado del impacto de Chicxulub. El estudio cuantitativo, mediante nanofosiles, de cuatro secciones en estos materiales ha permitido el reconocimiento del intervalo correspondiente a las Subzonas de Micula murus/Nephrolithus frequens (CC25c/CC26a) y una potente Subzona de Micula prinsii (CC26b) para los materiales del Cretacico superior. En los materiales de la base del Paleoceno se ha identificado la Subzona de Cruciplacolithus primus (CP1a). Se han observado, dentro de la Subzona CC26b, dos intervalos en los que se registra un aumento en las proporciones relativas de Prediscosphaera stoveri y Ahmuellerella regularis que, junto al descenso paralelo observado en la abundancia del indicador de aguas calidas Watznaueria barnesae, se han interpretado como periodos de enfriamiento climatico. Dentro de los materiales terciarios se han identificado los acmes sucesivos de Thoracosphaera spp. y Neobiscutum, como eventos significativos. En los ultimos centimetros de los materiales del Maastrichtiense terminal, por debajo del nivel esferulitico, se ha observado un pequeno aumento en la proporcion de Thoracosphaera spp., que podria suponer un leve incremento en el estres del medio. Al contrario de lo que ocurre en otras secciones de paleolatitudes bajas, no hay registro en Beloc de ningun acme de Braarudosphaera y la presencia de este taxon es solo testimonial. Escasos especimenes de Biantholithus (incluyendo a B. sparsus), que presentan ademas un registro discontinuo, constituyen el unico taxon claramente terciario encontrado por encima del nivel esferulitico.

Characterization of the negative carbon isotope shift in segment C2, its global implications as a harbinger of OAE1a

Lower Cretaceous C-isotope records show intermittent negative/positive spikes, and consistent patterns of coeval chemostratigraphic curves thus document shifts that signal simultaneous responses of temporal changes in the global carbon reservoir. The standard pattern registered by the δ13Corg and δ13Ccarb in Lower Aptian sediments includes distinct isotope segments C1 to C8 (Menegatti et al., 1998). In the El Pui section, Organyà Basin, Spain, C-isotope segment C2 is the longest interval preceding segments C3–C6 associated with oceanic anoxic event 1a (OAE 1a), and reveals a distinct negative shift of ~1.8‰ to ~2.23‰ defining the C-isotope pattern within that interval. Total inorganic carbon (TIC), total organic carbon (TOC), δ13Corg, microfacies, n-alkanes show no difference before, during, or after the negative inflection. The biomarkers indicate that organic matter (OM) mainly originates from algal/microbial sources because short-chain length homologues (≤nC19) dominate. nC20 through nC25 indicate some contribution from aquatic vegetation, but little from higher plants (>nC25), as also suggested by the terrestrial/aquatic ratio of n-alkanes or (TAR) = [(nC27+nC29+nC31)/(nC15+nC17+nC19)] (averages 0.085). We suggest that conjoint pulses of contemporaneous LIPs (Ontong Java) and massive explosive volcanism in northeast Asia, the Songliao Basin (SB-V), best conform to plausible causes of the negative intra-C2 carbon isotopic excursion (CIE) at that time. Because of its apparent common occurrence the intra-C2 inflection could be a useful marker harbinger to the more pronounced CIE C3, the hallmark of OAE1a.