Fosong Wang

Ethylene polymerization by 2-iminopyridylnickel halide complexes: synthesis, characterization and catalytic influence of the benzhydryl group

A series of 2-(2-benzhydrylbenzenamino)pyridine ligands (L1–L13) was synthesized and used as bidentate N^N ligands with nickel halides to afford the corresponding nickel dihalide complexes L(2)Ni(2)Cl(4) C1–C13 and L(2)NiBr(2) D1–D13. All ligands and complexes were characterized by IR and NMR spectroscopy, and by elemental analysis. The molecular structures of the representative complexes C1·2CH(3)OH, C5·2H(2)O, D4, D7 and D9 were confirmed by single-crystal X-ray diffraction studies. Upon activation with either methylaluminoxane (MAO) or ethylaluminium sesquichloride (Et(3)Al(2)Cl(3), EASC), these nickel pre-catalysts exhibited high activities (up to the range of 10(7) g mol(-1) (Ni) h(-1)) towards ethylene polymerization, producing branched polyethylenes with narrow polydispersity.

Synthesis, characterization and ethylene oligomerization behaviour of 8-(1-aryliminoethylidene)quinaldinylnickel dihalides

A series of 8-(1-aryliminoethylidene)quinaldines and the nickel halides thereof were synthesized and characterized, and the molecular structures of two representative nickel complexes were confirmed by single-crystal X-ray diffraction studies. Upon treatment with diethylaluminium chloride (Et2AlCl), the nickel pro-catalysts exhibited high activity for ethylene oligomerization (1.24–1.83 × 106 g mol−1(Ni) h−1) with good thermal stability at 60 °C under 10 atm of ethylene. The influence of the reaction parameters on the catalytic behaviour was investigated for these nickel-based systems, including variation of Al/Ni molar ratio and reaction temperature. Furthermore, the effect of the ancillary ligand Ph3P was also probed.