Frances E. Jenner

The global pattern of trace-element distributions in ocean floor basalts

The magmatic layers of the oceanic crust are created at constructive plate margins by partial melting of the mantle as it wells up. The chemistry of ocean floor basalts, the most accessible product of this magmatism, is studied for the insights it yields into the compositional heterogeneity of the mantle and its thermal structure. However, before eruption, parental magma compositions are modified at crustal pressures by a process that has usually been assumed to be fractional crystallization. Here we show that the global distributions of trace elements in ocean floor basalts describe a systematic pattern that cannot be explained by simple fractional crystallization alone, but is due to cycling of magma through the global ensemble of magma chambers. Variability in both major and incompatible trace-element contents about the average global pattern is due to fluctuations in the magma fluxes into and out of the chambers, and their depth, as well as to differences in the composition of the parental magmas.

Mantle flow, volatiles, slab-surface temperatures and melting dynamics in the north Tonga arc―Lau back-arc basin

The Fonualei Spreading Center affords an excellent opportunity to evaluate geochemical changes with increasing depth to the slab in the Lau back-arc basin. We present H2O and CO2concentrations and Sr, Nd, Pb, Hf and U-Th-Ra isotope data for selected glasses as well as new Hf isotope data from boninites and seamounts to the north of the Tonga arc. The Pb and Hf isotope data are used to show that mantle flow is oriented to the southwest and that the tear in the northern end of the slab may not extend east as far as the boninite locality. Along the Fonualei Spreading Center, key geochemical parameters change smoothly with increasing distance from the arc front and increasing slab surface temperatures. The latter may range from 720 to 866°C, based on decreasing H2O/Ce ratios. Consistent with experimental data, the geochemical trends are interpreted to reflect changes in the amount and composition of wet pelite melts or super-critical fluids and aqueous fluids derived from the slab. With one exception, all of the lavas preserve both238U excesses and 226Ra excesses. We suggest that lavas from the Fonualei Spreading Center and Valu Fa Ridge are dominated by fluid-fluxed melting whereas those from the East and Central Lau Spreading Centers, where slab surface temperatures exceed ∼850–900°C, are largely derived through decompression. A similar observation is found for the Manus and East Scotia back-arc basins and may reflect the expiry of a key phase such as lawsonite in the subducted basaltic crust.

Eoarchean within-plate basalts from southwest Greenland

The majority of >3 Ga metabasalts have chemical features, such as high field strength element (HFSE) depletions, that are characteristic of modern island-arc basalts. These compositions have been interpreted as evidence for subduction of oceanic crust early in Earth’s history. Alternatively, the apparent absence of Archean mafic rocks with mid-oceanic ridge basalt (MORB) and ocean island basalt (OIB) compositions and the ubiquitous occurrence of metabasalts with HFSE anomalies suggest that these chemical features may instead be a widespread characteristic of the Archean mantle related to early chemical differentiation and unrelated to modern-style recycling of crust. Here we present major- and trace-element data for a suite of metabasalts from Innersuartuut Island, southwest Greenland, which have a minimum age constraint of 3.75 Ga and are likely as old as ≥3.85 Ga. Samples from Innersuartuut show no evidence for crustal contamination or subduction-related magmatism, and have a petrogenesis comparable to modern OIB. The new data demonstrate that a compositional range for volcanic rocks comparable to that seen in the Phanerozoic existed in the Eoarchean. Therefore, rather than a global anomaly, subduction-related processes are the likely origin for the compositions of the most commonly preserved Archean mafic rocks with island-arc basalt characteristics.

The competing effects of sulfide saturation versus degassing on the behavior of the chalcophile elements during the differentiation of hydrous melts

There is a lack of consensus regarding the roles of sulfide saturation versus volatile degassing on the partitioning of Cu and Ag during differentiation and eruption of convergent margin magmas. Because of their oxidized character, volatile-rich magmas from the Eastern Manus Back-arc Basin (EMBB) only reach sulfide saturation following magnetite-driven reduction of the melt: the so-called “magnetite crisis.” If sulfide saturation typically precedes volatile saturation, the magnetite crisis will limit the proportion of Cu and Ag that can partition from the melt into an exsolving volatile-rich phase, which may contribute to the sporadic occurrence of magmatic-hydrothermal ore deposits at convergent margins. However, it is unclear whether the magnetite crisis is a common or rare event during differentiation of volatile-rich magmas. We report major and trace element data for submarine volcanic glasses from the Tonga arc-proximal Valu Fa Ridge (VFR; SW Pacific). Cu-Se-Ag systematics of samples erupting at the southern VFR suggest magnetite fractionation-triggered sulfide saturation. The similarity in chalcophile element systematics of the southern VFR and EMBB samples is unlikely to be coincidental, and may indicate that the magnetite crisis is a common event during differentiation of hydrous melts. However, unlike many convergent margin magmas, it is unlikely that the evolving VFR and EMBB were saturated in a S-bearing volatile phase prior to magnetite fractionation. Hence, the metal-depleting magnetite crisis may be restricted to back-arc basin magmas that do not degas volatiles prior to magnetite fractionation and potentially convergent margin magmas fractionating at high pressures in the continental crust.

Eoarchaean crustal growth in West Greenland (Itsaq Gneiss Complex) and in northeastern China (Anshan area): review and synthesis

Abstract Eoarchaean crust in West Greenland (the Itsaq Gneiss Complex, 3870–3600 Ma) is >80% by volume orthogneisses derived from plutonic tonalite–trondhjemite–granodiorite (TTG) suites, <10% amphibolites derived from basalts and gabbros, <10% crustally derived granite, <1% metasedimentary rocks and ≪1% tectonic slices of upper mantle peridotite. Amphibolites at >3850, c. 3810 and c. 3710 Ma have some compositional similarities to modern island arc basalts (IAB), suggesting their origin by hydrous fluxing of a suprasubduction-zone upper mantle wedge. Most of the Eoarchaean tonalites match in composition high-silica, low-magnesian adakites, whose petrogenesis is dominated by partial melting of garnetiferous mafic rocks at high pressure. However, associated with the tonalites are volumetrically minor more magnesian quartz diorites, whose genesis probably involved melting of depleted mantle to which some slab-derived component had been added. This assemblage is evocative of suites of magmas produced at Phanerozoic convergent plate boundaries in the case where subducted crust is young and hot. Thus, Eoarchaean ‘subduction’ first gave rise to short-lived episodes of mantle wedge melting by hydrous fluxing, yielding IAB-like basalts±boninites. In the hotter Eoarchaean Earth, flux-dominated destructive plate boundary magma generation quickly switched to slab melting of (‘subducted’) oceanic crust. This latter process produced the voluminous tonalites that were intruded into the slightly older sequences consisting of tectonically imbricated assemblages of IAB-like pillow lavas+sedimentary rocks, gabbros and upper mantle peridotite slivers. Zircon dating shows that Eoarchaean TTG production in the Itsaq Gneiss Complex was episodic (3870, 3850–3840, 3820–3810, 3795, 3760–3740, 3710–3695 and 3660 Ma). In each case, emplacement of small volumes of magma was probably followed by 10–40 Ma quiescence, which allowed the associated thermal pulse to dissipate. This explains why Greenland Eoarchaean crustal growth did not have granulite-facies metamorphism directly associated with it. Instead, 3660–3600 Ma granulite-facies metamorphism(s) in the Itsaq Gneiss Complex were consequential to collisional orogeny and underplating, upon termination of crustal growth. Similar Eoarchaean crustal history is recorded in the Anshan area of China, where a few well-preserved rocks as old as 3800 Ma have been found including high-MgO quartz diorites. For 3800 Ma rocks, this is a rare, if not unique, situation outside of the Itsaq Gneiss Complex. The presence of volumetrically minor 3800 Ma mantle-derived high-MgO quartz diorites in both the Itsaq Gneiss Complex and the Anshan area indicates either that Eoarchaean ‘subduction’ zones were overlain by a narrow mantle wedge or that the shallow subduction trapped slivers of upper mantle between the conserved and consumed plates.

Geodynamic implications for zonal and meridional isotopic patterns across the northern Lau and North Fiji Basins

We present new Sr-Nd-Pb-Hf-He isotopic data for sixty-five volcanic samples from the northern Lau and North Fiji Basin. This includes forty-seven lavas obtained from forty dredge sites spanning an east-west transect across the Lau and North Fiji basins, ten ocean island basalt (OIB)-type lavas collected from seven Fijian islands, and eight OIB lavas sampled on Rotuma. For the first time we are able to map clear north-south and east-west geochemical gradients in 87 Sr/ 86 Sr across the northern Lau and North Fiji Basins: lavas with the most geochemically enriched radiogenic isotopic signatures are located in the northeast Lau Basin, while signatures of geochemical enrichment are diminished to the south and west away from the Samoan hotspot. Based on these geochemical patterns and plate reconstructions of the region, these observations are best explained by the addition of Samoa, Rurutu, and Rarotonga hotspot material over the past 4 Ma. We suggest that underplated Samoan material has been advected into the Lau Basin over the past ∼4 Ma. As the slab migrated west (and toward the Samoan plume) via rollback over time, younger and hotter (and therefore less viscous) underplated Samoan plume material was entrained. Thus, entrainment efficiency of underplated plume material was enhanced, and Samoan plume signatures in the Lau Basin became stronger as the trench approached the Samoan hotspot. The addition of subducted volcanoes to the Cook-Austral Volcanic Lineament material, first from the Rarotonga hotspot, then followed by the Rurutu hotspot, contributes to the extreme geochemical signatures observed in the northeast Lau Basin.

What can we learn from the trace element composition of silicate minerals in the Bushveld Complex

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