Francesco Livi

Carbazole-based copolymers via direct arylation polymerization (DArP) for Suzuki-convergent polymer solar cell performance

Although direct arylation polymerization (DArP) has recently emerged as an alternative to traditional cross-coupling methods like Suzuki polymerization, the evaluation of DArP polymers in practical applications like polymer solar cells (PSCs) is limited. Because even the presence of minute quantities of defects can dramatically influence the solar cell, performance of DArP polymers offers critical insight alongside other structural and optoelectronic comparisons. Even via traditional methods, carbazole-based donors are frequently prone to homocoupling defects, which has been shown to—along with β-defects—compromise performance. Through defect minimization with the bulky and affordable neodecanoic acid (NDA) mixture, we report the synthesis of DArP poly[(9-(heptadecan-9-yl)-9H-carbazole)-alt-(4,7-di(thiophen-2-yl)benzo[c][1,2,5]thiadiazole)] (PCDTBT) that outperforms Suzuki PCDTBT with similar molecular weights. Expanding beyond this model system, carbazole-based polymers featuring 2,5-diethylhexyl-3,6-di(thiophen-2-yl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione (DPP), 4,10-bis(diethylhexyl)-thieno[2′,3′:5,6]pyrido[3,4-g]thieno[3,2-c]isoquinoline-5,11-dione (TPTI), 5-octyl-1,3-di(thiophen-2-yl)-4H-thieno[3,4-c]pyrrole-4,6(5H)-dione (DT-TPD), and 2,5-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)pyridine (EDOT-Pyr) are generated. Polymers are characterized by 1H NMR, cyclic voltammetry, UV-Vis, GIXRD, SCLC hole mobilities, and are implemented into polymer solar cells fabricated in air under ambient humidity. We demonstrate that DArP polymers perform comparably to Suzuki in practical applications.

Thiophene in Conducting Polymers: Synthesis of Poly(thiophene)s and Other Conjugated Polymers Containing Thiophenes, for Application in Polymer Solar Cells

Conducting polymers based on thiophene are described. The polymers include poly(thiophene) with and without side-chains and other conjugated polymers in general, based on thiophene. The synthesis and characteristics of the polymers are described along with the application of these as light-absorbing materials in polymer solar cells.