Francis Luck

Fischer–Tropsch Reaction on a Thermally Conductive and Reusable Silicon Carbide Support

The Fischer-Tropsch (FT) process, in which synthesis gas (syngas) derived from coal, natural gas, and biomass is converted into synthetic liquid fuels and chemicals, is a strongly exothermic reaction, and thus, a large amount of heat is generated during the reaction that could severely modify the overall selectivity of the process. In this Review, we report the advantages that can be offered by different thermally conductive supports, that is, carbon nanomaterials and silicon carbide, pure or doped with different promoters, for the development of more active and selective FT catalysts. This Review follows a discussion regarding the clear trend in the advantages and drawbacks of these systems in terms of energy efficiency and catalytic performance for this most-demanded catalytic process. It is demonstrated that the use of a support with an appropriate pore size and thermal conductivity is an effective strategy to tune and improve the activity of the catalyst and to improve product selectivity in the FT process. The active phase and the recovery of the support, which also represents a main concern in terms of the large amount of FT catalyst used and the cost of the active cobalt phase, is also discussed within the framework of this Review. It is expected that a thermally conductive support such as β-SiC will not only improve the development of the FT process, but that it will also be part of a new support for different catalytic processes for which high catalytic performance and selectivity are strongly needed.

Efficient Synthesis of Dimethyl Ether over HZSM‐5 Supported on Medium‐Surface‐Area β‐SiC Foam

In this study, we aimed to produce a highly selective and stable catalyst for the production of dimethyl ether by methanol dehydration. The activities were compared of different active phases of the employed system, zeolite HZSM-5 or gamma-alumina, supported on silicon carbide as foam, and it was found that the supported zeolite catalysts are more active than and as selective as the alumina-based catalysts. The as-prepared zeolite/SiC composites reveal good stability in long-term tests in the presence or absence of steam. The high stability is attributed to the presence of highly dispersed micrometer-sized zeolite particles, which make the active sites more accessible to the reactants and promote the quick transfer of the desired product, dimethyl ether, out of the catalyst bed, minimizing deactivation of the catalyst.

Distillate-range products from non-oil-based sources by catalytic cascade reactions.

An original two-step process efficiently catalyzed by functionalized mesoporous materials is proposed as a potential route for converting light olefins into long-chain hydrocarbons in the distillate range. In the first step, ethylene can be selectively transformed into C₄ -C₁₀ olefins with an even number of carbon atoms, over nickel-exchanged AlMCM-41, at 150 °C. When the nickel-catalyzed oligomerization was assisted by a second acid-catalyzed step over H-MCM-41, olefins with chains longer than 10 carbon atoms were mainly produced with a productivity of 180 g g⁻¹  h⁻¹.

Non-classical Nucleation Model for Cold Production of Heavy Oil

We examine the gas bubble nucleation phenomenon encountered in extra heavy oil during cold production. The nucleation model described in this work is based on so-called non-classical nucleation. Using this method, we show mesoporous cavities could be at the origin of the nanobubble trapping mechanism. The results obtained show this physical approach tends to demonstrate the pre-existence of gas bubbles in these crevices (surface roughness).The physics of capillarity used here is based on traditional Laplaces law and an original disjoining pressure expression. We test for several wettabilities in our mathematical model. The first configuration envisaged is for oil-wet rocks, although the cavity is assumed to be gas-wet. Water wettability is considered a second time, taking into account a precursor water film between the rock and the entrapped bubbles. The mix of these two configurations could represent nucleation in a global mixed-wet porous media. However, we show in the first part of this article that water presence does not affect the initial bubble radius. Nevertheless, a bubble growth model developed in the second configuration shows that bubble confinement could play an important role on gas bubble nucleation and the early first steps of its development.