Francisco Javier Sierro

Chronology, causes and progression of the Messinian salinity crisis

The Messinian salinity crisis is widely regarded as one of the most dramatic episodes of oceanic change of the past 20 or so million years (refs 1–3). Earliest explanations were that extremely thick evaporites were deposited in a deep and desiccated Mediterranean basin that had been repeatedly isolated from the Atlantic Ocean,, but elucidation of the causes of the isolation — whether driven largely by glacio-eustatic or tectonic processes — have been hampered by the absence of an accurate time frame. Here we present an astronomically calibrated chronology for the Mediterranean Messinian age based on an integrated high-resolution stratigraphy and ‘tuning’ of sedimentary cycle patterns to variations in the Earths orbital parameters. We show that the onset of the Messinian salinity crisis is synchronous over the entire Mediterranean basin, dated at 5.96 ± 0.02 million years ago. Isolation from the Atlantic Ocean was established between 5.59 and 5.33 million years ago, causing a large fall in Mediterranean water level followed by erosion (5.59–5.50 million years ago) and deposition (5.50–5.33 million years ago) of non-marine sediments in a large ‘Lago Mare’ (Lake Sea) basin. Cyclic evaporite deposition is almost entirely related to circum-Mediterranean climate changes driven by changes in the Earths precession, and not to obliquity-induced glacio-eustatic sea-level changes. We argue in favour of a dominantly tectonic origin for the Messinian salinity crisis, although its exact timing may well have been controlled by the ∼400-kyr component of the Earths eccentricity cycle.

Dansgaard‐Oeschger and Heinrich event imprints in Alboran Sea paleotemperatures

Past sea surface temperature (SST) evolution in the Alboran Sea (western Mediterranean) during the last 50,000 years has been inferred from the study of C37 alkenones in International Marine Global Change Studies MD952043 core. This record has a time resolution of ∼200 years allowing the study of millennial-scale and even shorter climatic changes. The observed SST curve displays characteristic sequences of extremely rapid warming and cooling events along the glacial period. Comparison of this Alboran record with δ18O from Greenland ice (Greenland Ice Sheet Project 2 core) shows a strong parallelism between these SST oscillations and the Dansgaard-Oeschger events. Five prominent cooling episodes standing out in the SST profile are accompanied by an anomalous high abundance of Neogloboquadrina pachyderma sinistral which is confined to the duration of these cold intervals. These features and the isotopic record reflect drastic changes in the surface hydrography of the Alboran Sea in association with Heinrich events Hl–5.

Evidence for enhanced Mediterranean thermohaline circulation during rapid climatic coolings

Molecular biomarkers (C37 alkenones, n-nonacosane and n-hexacosanol) and TOC are used together with benthic δ18O and δ13C data to document the hydrographic response of the western Mediterranean Sea to rapid climatic variability. These proxies are recorded in core MD 95-2043 (Alboran Sea) affording the study of the Dansgaard–Oeschger (D–O) and Heinrich (HE) variability during the last glacial period. The results suggest that rapid changes in the western Mediterranean thermohaline circulation occurred in parallel to sea surface temperature oscillations. Enhanced deep water ventilation occurred during cold intervals (HE and D–O Stadials) probably driven by a strengthening of north-westerly wind over the north-western Mediterranean Sea. In contrast, decreased intensity of the thermohaline circulation is detected during warm intervals (D–O Interstadials) which led to low oxygenated deep water masses and better preservation of the organic matter in the sediment.

Correlation of Late Miocene to Early Pliocene sequences between the Mediterranean and North Atlantic

Ocean Drilling Program (ODP) Site 982 in the North Atlantic contains a complete latest Miocene to early Pliocene section that was tuned to the astronomical timescale by correlating the record of gamma ray attenuation (GRA) bulk density to summer insolation at 65°N and the benthic δ18O signal to orbital obliquity for the interval from 4.6 to 7.5 Ma. The astronomical tuning of the Site 982 record permits a direct bed-to-bed correlation to the cyclostratigraphy of Messinian sections in the Mediterranean [Krijgsman et al., 1999a, 2001]. The benthic δ18O signal at Site 982 records a latest Miocene glacial period that lasted from ∼6.26 to 5.50 Ma and consisted of 18 glacial-to-interglacial oscillations that were controlled by the 41-kyr cycle of obliquity. Although the intensification of glaciation at 6.26 Ma may have contributed to the restriction of the Mediterranean, it preceded the depositional onset of the lower evaporite unit at 5.96 Ma by some 300 kyr. The transition from Stage TG12 to TG11 at 5.5 Ma marks the end of the latest Miocene glacial period and precedes the Miocene/Pliocene boundary by 170 kyr. Although benthic δ18O values are relatively low and δ18O of bulk carbonate reaches a minimum at the Miocene/Pliocene boundary at 5.33 Ma, there is no single “event” that would indicate deglaciation and sea level rise as the cause of the reflooding of the Mediterranean. We conclude that glacioeustatic changes alone were not responsible for either the start or end of evaporite deposition during the Messinian, suggesting that tectonic or local climate changes in the Mediterranean region were the dominant cause(s).

Depositional history of estuarine infill during the last postglacial transgression (Gulf of Cadiz, Southern Spain)

Abstract The Late Pleistocene and Holocene evolution of the estuaries in the Gulf of Cadiz is interpreted for the first time using drill cores, logs, trenches, and 38 new radiocarbon data, and the results compared with the shelf. The Odiel, Tinto and Guadalete Rivers deposited conglomerates during a highstand that did not reach the present sea level dated at ca. 25–30 ka (Isotopic Stage (IS) 3), corresponding to a relatively humid period in the area. Rivers incised these coarse-grained deposits during the last main lowstand at ca. 18 ka, when sea level dropped to −120 m and the coastline lay 14 km seawards from the present. The erosional surface is a sequence boundary and the flooding surface of the postglacial eustatic rise, overlain by the valley fill deposits of the transgressive and highstand phases of the last fourth- and fifth-order depositional sequences recognised in the shelf. The first marine influence in the estuaries during the transgression occurs at −25/−30 m at ca. 10,000 years BP. According to fossil assemblages, the transgressed basins changed from brackish to more open marine as the sea rose until ca. 6500 years BP, when it reached the maximum flooding and the sandy estuarine barriers ceased to retrograde toward the muddy central basins. Then, the rate of eustatic rise decreased drastically, and the estuarine filling followed a two-fold pattern governed by the progressive change from vertical accretion to lateral (centripetal) progradation. At ca. 4000 years BP the fluvial input surpassed the already negligible rate of rise, causing partial emergence of tidal flats and spit barriers in the largely filled estuarine basins. Prevalence of coastal progradation upon vertical accretion at ca. 2400 years BP caused accelerated expansion of tidal flats and rapid growth of the sandy barriers. Further changes since the 16th century reflect widespread anthropic impacts.

Astrochronology for the Messinian Sorbas basin (SE Spain) and orbital (precessional forcing for evaporite cyclicity

The Sorbas basin of SE Spain contains one of the most complete sedimentary successions of the Mediterranean reflecting the increasing salinity during the Messinian salinity crisis. A detailed cyclostratigraphic study of these successions allows a correlation of the sedimentary cycle patterns to astronomical target curves. Here, we present an astrochronological framework for the Messinian of the central part of the Sorbas basin. This framework will form a solid basis for high-resolution correlations to the marginal carbonate facies and to the Central Mediterranean area. The early Messinian Abad Member contains 55 precession induced sedimentary cycles marked by homogeneous marl‐opalrich bed alternations in the ‘Lower Abad’ and by homogeneous marl‐sapropel alternations in the ‘Upper Abad’. Astronomical tuning results in an age of 5.96 Ma for the transition to the Yesares evaporites and thus for the onset of the ‘Messinian salinity crisis’. The marl‐sapropel cycles of the ‘Upper Abad’ are replaced by gypsum‐sapropel cycles (14) in the Yesares Member, indicating that the evaporite cyclicity is related to precession controlled oscillations in (circum) Mediterranean climate as well. As a consequence, gypsum beds correspond to precession maxima (insolation minima) and relatively dry climate, sapropelitic marls to precession minima (insolation maxima) and relatively wet climate. An alternative (glacio-eustatic) obliquity control for evaporite cyclicity can be excluded because the number of sedimentary cycles with a reversed polarity is too high. Sedimentation during the Abad, Yesares, and the overlying coastal sequences of the Sorbas Member, took place in a continuously marine environment, indicating that marine conditions in the Sorbas basin prevailed at least until 5.60‐5.54 Ma. According to our scenario, deposition of the Yesares and Sorbas Member took place synchronously with deposition of the ‘Lower Evaporites’ in the Central Mediterranean. Finally, the continental Zorreras Member consists of 8 sedimentary cycles of alternating reddish silts (dry climate) and yellowish sands (wet climate) which correlates very well with the ‘Upper Evaporites’ and Lago Mare facies of the Mediterranean. q 2001 Elsevier Science B.V. All rights reserved.

Impact of iceberg melting on Mediterranean thermohaline circulation during Heinrich events

Down-core samples of planktonic and benthic foraminifera were analyzed for oxygen and carbon isotopes in International Marine Past Global Changes Study (IMAGES) core MD99-2343 in order to study the interactions between climate change in the Northern Hemisphere and the western Mediterranean thermohaline circulation at times of Heinrich events (HE). Our results confirm the antiphase correlation between enhanced North Atlantic Deep Water formation and low ventilation in the Mediterranean. However, this study reveals that this antiphase relationship in deepwater formation between the North Atlantic and Mediterranean was interrupted during times of HE when the injection of large volumes of water from melting icebergs reached the entrance to the Mediterranean. These events, which lasted less than 1000 years, are represented by pronounced decreases in both planktonic d18O and benthic d13C signals. Lower salinities of Mediterranean surface water resulted in a slowdown of western Mediterranean deepwater overturn even though cold sea surface temperatures and drier climate should have resulted in enhanced deepwater formation.

The Abad composite (SE Spain): a Messinian reference section for the Mediterranean and the APTS

A high-resolution integrated stratigraphy is presented for the Abad marls of the Sorbas and Nijar basins in SE Spain (preevaporitic Messinian of the Western Mediterranean). Detailed cyclostratigraphic and biostratigraphic analyses of partially overlapping subsections were needed to overcome stratigraphic problems in particular encountered at the complex transition from the Lower to the Upper Abad. The resulting Abad composite section contains a continuous stratigraphic record from the Tortonian/Messinian boundary up to the transition to the Messinian evaporites of the Yesares Member. All together, 18 calcareous plankton events were recognized which were shown to be synchronous throughout the Mediterranean by means of detailed (bed-to-bed) cyclostratigraphic correlations. The magnetostratigraphy allowed the identification of the four magnetic reversals of chron C3An in the Upper Abad. Details in the sedimentary cycle patterns allowed the Abad composite to be astronomically calibrated. This calibration to the 658N summer insolation curve of solution La90(1,1) yielded astronomical ages for all sedimentary cycles, calcareous plankton bioevents, ash layers and paleomagnetic reversals. Up to now, the Abad composite is the only astronomically well-calibrated section that provided a reliable cyclostratigraphy, magnetostratigraphy and calcareous plankton biostratigraphy. As such it will serve as a reference section both for the pre-evaporite Messinian in the Mediterranean as well as for the Messinian interval in the Astronomical Polarity Time Scale. q 2001 Elsevier Science B.V. All rights reserved.

Late Pleistocene evolution of the ocean’s carbonate system

Abstract We demonstrate that the carbonate record from a single site (Ocean Drilling Program Site 1089) in the deep South Atlantic represents a qualitative, high-resolution record of the temporal evolution of the carbonate saturation state of the deep sea. The record is especially notable because it is free from many of the complications that limit other records (low sedimentation rates, blurring by chemical erosion, bioturbation, etc.). The pattern of carbonate variability is characteristic of Indo–Pacific cores with high-carbonate glacials and low-carbonate interglacials. Wt% carbonate lags changes in benthic δ 18 O by an average of ∼7.6 kyr, and carbonate variations are in-phase with the rate of change (first derivative) of benthic δ 18 O. Intense dissolution occurs at the transition from interglacial to glacial periods and increased preservation occurs during deglaciations. These observations represent two fundamentally different responses of the marine carbonate system. The lagged response of carbonate to δ 18 O reflects a steady-state mass balance process whereby the lysocline adjusts to maintain alkalinity balance between riverine input and marine burial. The Site 1089 carbonate signal is remarkably similar to inferred changes in the Sr/Ca of seawater for the past 250 kyr, which implies that both carbonate dissolution and seawater Sr/Ca may be controlled by sea level-induced changes in the location of carbonate deposition (shelf-basin fractionation) during glacial to interglacial cycles. The transient change in preservation during the transitions into and out of glacial stages reflects a response of the carbonate system to a redistribution of alkalinity and DIC in the ocean (i.e. carbonate compensation). Comparison of the Site 1089 carbonate and Vostok p CO 2 records suggests a role of deep-sea [CO 3 2− ] variations for governing at least some second-order features of the atmospheric p CO 2 signal. In order to quantify this role, however, measurement of indices of dissolution along a true depth transect will be required to estimate the magnitudes of changes in deep-sea [CO 3 2− ].

Holocene climate variability in the western Mediterranean region from a deepwater sediment record

[1] The detailed analysis of the International Marine Past Global Changes Study core MD99-2343 recovered from a sediment drift at 2391 m water depth north of the island of Minorca illustrates the effects of climate variability on thermohaline circulation in the western Mediterranean during the last 12 kyr. Geochemical ratios associated with terrigenous input resulted in the identification of four phases representing different climatic and deepwater overturning conditions in the Western Mediterranean Basin during the Holocene. Superimposed on the general trend, eight centennial- to millennial-scale abrupt events appear consistently in both grain size and geochemical records, which supports the occurrence of episodes of deepwater overturning reinforcement in the Western Mediterranean Basin. The observed periodicity for these abrupt events is in agreement with the previously defined Holocene cooling events of the North Atlantic region, thus supporting a strong AtlanticMediterranean climatic link at high-frequency time intervals during the last 12 kyr. The rapid response of the Mediterranean thermohaline circulation to climate change in the North Atlantic stresses the importance of atmospheric teleconnections in transferring climate variability from high latitudes to midlatitudes.