Franck Montmessin

Density and temperatures of the upper Martian atmosphere measured by stellar occultations with Mars Express SPICAM

[1] We present one Martian year of observations of the density and temperature in the upper atmosphere of Mars (between 60 and 130 km) obtained by the Mars Express ultraviolet spectrometer Spectroscopy for Investigation of Characteristics of the Atmosphere of Mars (SPICAM). Six hundred sixteen profiles were retrieved using stellar occultations technique at various latitude and longitude. The atmospheric densities exhibit large seasonal fluctuations due to variations in the dust content of the lower atmosphere which controls the temperature and, thus, the atmospheric scale height, below 50 km. In particular, the year observed by SPICAM was affected by an unexpected dust loading around Ls = 130° which induced a sudden increase of density above 60 km. The diurnal cycle could not be analyzed in detail because most data were obtained at nighttime, except for a few occultations observed around noon during northern winter. There, the averaged midday profile is found to slightly differ from the corresponding midnight profile, with the observed differences being consistent with propagating thermal tides and variations in local solar heating. About 6% of the observed mesopause temperatures exhibits temperature below the CO 2 frost point, especially during northern summer in the tropics. Comparison with atmospheric general circulation model predictions shows that the existing models overestimate the temperature around the mesopause (above 80 to 100 km) by up to 30 K, probably because of an underestimation of the atomic oxygen concentration which controls the CO 2 infrared cooling.

MAVEN observations of the response of Mars to an interplanetary coronal mass ejection

Coupling between the lower and upper atmosphere, combined with loss of gas from the upper atmosphere to space, likely contributed to the thin, cold, dry atmosphere of modern Mars. To help understand ongoing ion loss to space, the Mars Atmosphere and Volatile Evolution (MAVEN) spacecraft made comprehensive measurements of the Mars upper atmosphere, ionosphere, and interactions with the Sun and solar wind during an interplanetary coronal mass ejection impact in March 2015. Responses include changes in the bow shock and magnetosheath, formation of widespread diffuse aurora, and enhancement of pick-up ions. Observations and models both show an enhancement in escape rate of ions to space during the event. Ion loss during solar events early in Mars history may have been a major contributor to the long-term evolution of the Mars atmosphere.

Heterogeneous chemistry in the atmosphere of Mars

Hydrogen radicals are produced in the martian atmosphere by the photolysis of water vapour and subsequently initiate catalytic cycles that recycle carbon dioxide from its photolysis product carbon monoxide. These processes provide a qualitative explanation for the stability of the atmosphere of Mars, which contains 95 per cent carbon dioxide. Balancing carbon dioxide production and loss based on our current understanding of the gas-phase chemistry in the martian atmosphere has, however, proven to be difficult. Interactions between gaseous chemical species and ice cloud particles have been shown to be key factors in the loss of polar ozone observed in the Earth’s stratosphere, and may significantly perturb the chemistry of the Earth’s upper troposphere. Water-ice clouds are also commonly observed in the atmosphere of Mars and it has been suggested previously that heterogeneous chemistry could have an important impact on the composition of the martian atmosphere. Here we use a state-of-the-art general circulation model together with new observations of the martian ozone layer to show that model simulations that include chemical reactions occurring on ice clouds lead to much improved quantitative agreement with observed martian ozone levels in comparison with model simulations based on gas-phase chemistry alone. Ozone is readily destroyed by hydrogen radicals and is therefore a sensitive tracer of the chemistry that regulates the atmosphere of Mars. Our results suggest that heterogeneous chemistry on ice clouds plays an important role in controlling the stability and composition of the martian atmosphere.

Evidence of Water Vapor in Excess of Saturation in the Atmosphere of Mars

Spacecraft observations reveal more water vapor in the atmosphere of Mars than would be expected if vapor pressure controlled the water vapor profile. The vertical distribution of water vapor is key to the study of Mars’ hydrological cycle. To date, it has been explored mainly through global climate models because of a lack of direct measurements. However, these models assume the absence of supersaturation in the atmosphere of Mars. Here, we report observations made using the SPICAM (Spectroscopy for the Investigation of the Characteristics of the Atmosphere of Mars) instrument onboard Mars Express that provide evidence of the frequent presence of water vapor in excess of saturation, by an amount far surpassing that encountered in Earth’s atmosphere. This result contradicts the widespread assumption that atmospheric water on Mars cannot exist in a supersaturated state, directly affecting our long-term representation of water transport, accumulation, escape, and chemistry on a global scale.

Variations of sulphur dioxide at the cloud top of Venus's dynamic atmosphere

A pulse of sulphur dioxide in Venus’s upper atmosphere was observed by the Pioneer Venus spacecraft in the 1970s and 1980s and attributed to volcanism. Recent sulphur dioxide measurements from Venus Express indicate decadal-scale fluctuations in sulphur dioxide above Venus’s cloud tops in an atmosphere that is more dynamic than expected. Sulphur dioxide is a million times more abundant in the atmosphere of Venus than that of Earth, possibly as a result of volcanism on Venus within the past billion years1,2. A tenfold decrease in sulphur dioxide column density above Venus’s clouds measured by the Pioneer Venus spacecraft during the 1970s and 1980s has been interpreted as decline following an episode of volcanogenic upwelling from the lower atmosphere3,4. Here we report that the sulphur dioxide column density above Venus’s clouds decreased by an order of magnitude between 2007 and 2012 using ultraviolet spectrometer data from the SPICAV instrument onboard the Venus Express spacecraft. This decline is similar to observations during the 1980s. We also report strong latitudinal and temporal variability in sulphur dioxide column density that is consistent with supply fluctuations from the lower atmosphere. We suggest that episodic sulphur dioxide injections to the cloud tops may be caused either by periods of increased buoyancy of volcanic plumes, or, in the absence of active volcanism, by long-period oscillations of the general atmospheric circulation. The 30-year observational record from Pioneer Venus and Venus Express confirms that episodic injections of sulphur dioxide above the clouds recur on decadal timescales, suggesting a more variable atmosphere than expected.

Global climate modeling of the Martian water cycle with improved microphysics and radiatively active water ice clouds

Water ice clouds play a key role in the radiative transfer of the Martian atmosphere, impacting its thermal structure, its circulation, and, in turn, the water cycle. Recent studies including the radiative effects of clouds in global climate models (GCMs) have found that the corresponding feedbacks amplify the model defaults. In particular, it prevents models with simple microphysics from reproducing even the basic characteristics of the water cycle. Within that context, we propose a new implementation of the water cycle in GCMs, including a detailed cloud microphysics taking into account nucleation on dust particles, ice particle growth, and scavenging of dust particles due to the condensation of ice. We implement these new methods in the Laboratoire de Meteorologie Dynamique GCM and find satisfying agreement with the Thermal Emission Spectrometer observations of both water vapor and cloud opacities, with a significant improvement when compared to GCMs taking into account radiative effects of water ice clouds without this implementation. However, a lack of water vapor in the tropics after Ls = 180° is persistent in simulations compared to observations, as a consequence of aphelion cloud radiative effects strengthening the Hadley cell. Our improvements also allow us to explore questions raised by recent observations of the Martian atmosphere. Supersaturation above the hygropause is predicted in line with Spectroscopy for Investigation of Characteristics of the Atmosphere of Mars observations. The model also suggests for the first time that the scavenging of dust by water ice clouds alone fails to fully account for the detached dust layers observed by the Mars Climate Sounder.

Composition of the Venus mesosphere measured by Solar Occultation at Infrared on board Venus Express

Solar Occultation at Infrared (SOIR), which is a part of the Spectroscopy for Investigation of Characteristics of the Atmosphere of Venus (SPICAV) instrument on board Venus Express, combines an echelle-grating spectrometer with an acoustooptical tunable filter. It performs solar occultation measurements in the IR region at a high spectral resolution better than all previously flown planetary spectrometers. The wavelength range probed allows for a detailed chemical inventory of the Venus atmosphere above the cloud layer, with an emphasis on the vertical distribution of the gases. A general description of the retrieval technique is given and is illustrated by some results obtained for CO2 and for a series of minor constituents, such as H2O, HDO, CO, HCl, and HF. Detection limits for previously undetected species will also be discussed.

Early MAVEN Deep Dip campaign reveals thermosphere and ionosphere variability

The Mars Atmosphere and Volatile Evolution (MAVEN) mission, during the second of its Deep Dip campaigns, made comprehensive measurements of martian thermosphere and ionosphere composition, structure, and variability at altitudes down to ~130 kilometers in the subsolar region. This altitude range contains the diffusively separated upper atmosphere just above the well-mixed atmosphere, the layer of peak extreme ultraviolet heating and primary reservoir for atmospheric escape. In situ measurements of the upper atmosphere reveal previously unmeasured populations of neutral and charged particles, the homopause altitude at approximately 130 kilometers, and an unexpected level of variability both on an orbit-to-orbit basis and within individual orbits. These observations help constrain volatile escape processes controlled by thermosphere and ionosphere structure and variability.

Vertical distribution of ozone on Mars as measured by SPICAM/Mars Express using stellar occultations

[i] The ultraviolet spectrometer of the SPICAM instrument on board the European Mars Express mission has performed stellar occultations to probe the atmosphere. Vertical profiles of ozone are retrieved from inversion of transmission spectra in the altitude range 20-30 to 70 km. They are analyzed here as functions of latitude and season of the observations. These occultations have been monitored on the night side, from northern spring equinox (L s = 8°) to northern winter solstice (L s = 270°). The profiles show the presence of two ozone layers: (1) one located near the surface, the top of which is visible below 30 km altitude, and (2) one layer located in the altitude range 30 to 60 km, a feature that is highly variable with latitude and season. This layer is first seen after L s = 11°, and the ozone abundance at the peak tends to increase until L s ∼ 40°, when it stabilizes around 6-8 x 10 9 cm -3 . After southern winter solstice (L s ∼ 100°), the peak abundance starts decreasing again, and this ozone layer is no longer detected after L s ∼ 130°. A recent model (Lefevre et al., 2004) predicted the presence of these ozone layers, the altitude one being only present at night. Though the agreement between model and observations is quite good, this nocturnal altitude layer is present in SPICAM data over a less extended period than predicted. Though a possible role of heterogeneous chemistry is not excluded, this difference is probably linked to the seasonal evolution of the vertical distribution of water vapor.

SPICAM IR acousto‐optic spectrometer experiment on Mars Express

SPICAV IR, a part of SPICAV/SOIR suite on Venus Express, is a compact single pixel spectrometer for the spectral range of 0.65–1.7 mm based on acousto-optical tunable filter (AOTF) technology. SPICAV IR is derived from SPICAM IR operating on Mars Express, the first AOTF spectrometer in the deep space, and adapted for Venus atmosphere measurements. The spectrometer sequentially measures spectra of reflected solar radiation from Venus on the dayside and the emitted Venus radiation in spectral ‘‘windows’’ on the nightside, and works also in solar occultation mode. The spectral range is 0.65– 1.1 mm with spectral resolution of 7.8 cm � 1 , and 1–1.7 mm with spectral resolution of 5.2 cm � 1 .A description of this near-IR instrument, its calibration, in-flight performances, and the modes of operations on Venus’ orbit are presented. A brief overview of the science measurements is given: water vapor measurements in the mesosphere on the day-side and near surface on the nightside, mapping of the O2(a 1 Dg) emission at 1.27 mm, aerosol studies via polarization and scattering solar radiation at the day-side, and measurements of aerosol properties at the tops of the clouds in solar occultations.