François Treussart

Experimental realization of Wheeler's delayed-choice Gedanken Experiment

Wave-particle duality is strikingly illustrated by Wheelers delayed-choice gedanken experiment, where the configuration of a two-path interferometer is chosen after a single-photon pulse has entered it: Either the interferometer is closed (that is, the two paths are recombined) and the interference is observed, or the interferometer remains open and the path followed by the photon is measured. We report an almost ideal realization of that gedanken experiment with single photons allowing unambiguous which-way measurements. The choice between open and closed configurations, made by a quantum random number generator, is relativistically separated from the entry of the photon into the interferometer.

Diamonds with a high density of nitrogen-vacancy centers for magnetometry applications

V. M. Acosta, E. Bauch, 2 M. P. Ledbetter, C. Santori, K.-M. C. Fu, P. E. Barclay, R. G. Beausoleil, H. Linget, J. F. Roch, F. Treussart, S. Chemerisov, W. Gawlik, and D. Budker 8, 9 1 Department of Physics, University of California, Berkeley, CA 94720-7300 2 Technische Universität Berlin, Hardenbergstraÿe 28, 10623 Berlin, Germany 3 Hewlett-Packard Laboratories, 1501 Page Mill Rd., Palo Alto, CA 94304 4 Ecole Normale Supérieure de Cachan, 61 Avenue du Président Wilson, 94235 Cachan CEDEX, France 5 Laboratoire de Photonique Quantique et Moléculaire (CNRS UMR 8537), Ecole Normale Supérieure de Cachan, 61 Avenue du Président Wilson, 94235 Cachan CEDEX, France 6 Argonne National Laboratory, Argonne, IL, 60439, U.S.A. 7 Center for Magneto-Optical Research, Institute of Physics, Jagiellonian University, Reymonta 4, 30-059 Kraków, Poland Nuclear Science Division, Lawrence Berkeley National Laboratory, Berkeley CA 94720, USA budker@berkeley.edu (Dated: July 31, 2009)

In situ diagnostics of the crystalline nature of single organic nanocrystals by nonlinear microscopy.

We elucidate the crystalline nature and the three-dimensional orientation of isolated organic nanocrystals embedded in a sol-gel matrix, using a polarized nonlinear microscopy technique that combines two-photon fluorescence and second harmonic generation. This technique allows the distinction between monocrystalline structures and nanoscale polycrystalline aggregates responsible for incoherent second harmonic signals.

Experimental open air quantum key distribution with a single photon source

We describe the implementation of a quantum key distribution (QKD) system using a single-photon source, operating at night in open air. The single- photon source at the heart of the functional and reliable set-up relies on the pulsed excitation of a single nitrogen-vacancy colour centre in a diamond nanocrystal. We tested the effect of attenuation on the polarized encoded photons for inferring the longer distance performance of our system. For strong attenuation, the use of pure single-photon states gives measurable advantage over systems relying on weak attenuated laser pulses. The results are in good agreement with theoretical models developed to assess QKD security.

Near-field optical microscopy with a nanodiamond-based single-photon tip.

We introduce a point-like scanning single-photon source that operates at room temperature and offers an exceptional photostability (no blinking, no bleaching). This is obtained by grafting in a controlled way a diamond nanocrystal (size around 20 nm) with single nitrogen-vacancy color-center occupancy at the apex of an optical probe. As an application, we image metallic nanostructures in the near-field, thereby achieving a near-field scanning single-photon microscopy working at room temperature on the long term. Our work may be of importance to various emerging fields of nanoscience where an accurate positioning of a quantum emitter is required such as for example quantum plasmonics.

Delayed-choice test of quantum complementarity with interfering single photons.

We report an experimental test of quantum complementarity with single-photon pulses sent into a Mach-Zehnder interferometer with an output beam splitter of adjustable reflection coefficient R. In addition, the experiment is realized in Wheelers delayed-choice regime. Each randomly set value of R allows us to observe interference with visibility V and to obtain incomplete which-path information characterized by the distinguishability parameter D. Measured values of V and D are found to fulfill the complementarity relation V2+D2 < or =1.

Diamond nanocrystals hosting single nitrogen-vacancy color centers sorted by photon-correlation near-field microscopy

Diamond nanocrystals containing highly photoluminescent color centers are attractive, nonclassical, and near-field light sources. For near-field applications, the size of the nanocrystal is crucial, since it defines the optical resolution. Nitrogen-vacancy (NV) color centers are efficiently created by proton irradiation and annealing of a nanodiamond powder. Using near-field microscopy and photon statistics measurements, we show that nanodiamonds with sizes down to 25 nm can hold a single NV color center with bright and stable photoluminescence.

Stimulated emission depletion microscopy resolves individual nitrogen vacancy centers in diamond nanocrystals.

Nitrogen-vacancy (NV) color centers in nanodiamonds are highly promising for bioimaging and sensing. However, resolving individual NV centers within nanodiamond particles and the controlled addressing and readout of their spin state has remained a major challenge. Spatially stochastic super-resolution techniques cannot provide this capability in principle, whereas coordinate-controlled super-resolution imaging methods, like stimulated emission depletion (STED) microscopy, have been predicted to fail in nanodiamonds. Here we show that, contrary to these predictions, STED can resolve single NV centers in 40-250 nm sized nanodiamonds with a resolution of ≈10 nm. Even multiple adjacent NVs located in single nanodiamonds can be imaged individually down to relative distances of ≈15 nm. Far-field optical super-resolution of NVs inside nanodiamonds is highly relevant for bioimaging applications of these fluorescent nanolabels. The targeted addressing and readout of individual NV(-) spins inside nanodiamonds by STED should also be of high significance for quantum sensing and information applications.

Room temperature triggered single-photon source in the near infrared

We report the realization of a solid-state triggered single-photon source with narrow emission in the near infrared at room temperature. It is based on the photoluminescence of a single nickel–nitrogen NE8 colour centre in a chemical vapour deposited diamond nanocrystal. Stable single-photon emission has been observed in the photoluminescence under both continuous-wave and pulsed excitations. The realization of this source represents a step forward in the application of diamond-based single-photon sources to quantum key distribution (QKD) under practical operating conditions.

Fluorescent Nanodiamonds Embedded in Biocompatible Translucent Shells

High pressure high temperature (HPHT) nanodiamonds (NDs) represent extremely promising materials for construction of fluorescent nanoprobes and nanosensors. However, some properties of bare NDs limit their direct use in these applications: they precipitate in biological solutions, only a limited set of bio-orthogonal conjugation techniques is available and the accessible material is greatly polydisperse in shape. In this work, we encapsulate bright 30-nm fluorescent nanodiamonds (FNDs) in 10-20-nm thick translucent (i.e., not altering FND fluorescence) silica shells, yielding monodisperse near-spherical particles of mean diameter 66 nm. High yield modification of the shells with PEG chains stabilizes the particles in ionic solutions, making them applicable in biological environments. We further modify the opposite ends of PEG chains with fluorescent dyes or vectoring peptide using click chemistry. High conversion of this bio-orthogonal coupling yielded circa 2000 dye or peptide molecules on a single FND. We demonstrate the superior properties of these particles by in vitro interaction with human prostate cancer cells: while bare nanodiamonds strongly aggregate in the buffer and adsorb onto the cell membrane, the shell encapsulated NDs do not adsorb nonspecifically and they penetrate inside the cells.