Frank Mücklich

One- and two-dimensional photonic crystal microcavities in single crystal diamond

Diamond is an attractive material for photonic quantum technologies because its colour centres have a number of outstanding properties, including bright single photon emission and long spin coherence times. To take advantage of these properties it is favourable to directly fabricate optical microcavities in high-quality diamond samples. Such microcavities could be used to control the photons emitted by the colour centres or to couple widely separated spins. Here, we present a method for the fabrication of one- and two-dimensional photonic crystal microcavities with quality factors of up to 700 in single crystal diamond. Using a post-processing etching technique, we tune the cavity modes into resonance with the zero phonon line of an ensemble of silicon-vacancy colour centres, and we measure an intensity enhancement factor of 2.8. The controlled coupling of colour centres to photonic crystal microcavities could pave the way to larger-scale photonic quantum devices based on single crystal diamond.

Thermal stability of nano-RuAl produced by mechanical alloying

The thermal stability of as-milled nano-RuAl has been studied by isothermal annealing at high temperatures. All three kinds of structural evolutions in as-milled powders upon high temperature exposure, namely reordering, strain relaxation and grain growth, show signs of stagnation. The total quantity of impurities, mainly 15 at.% Fe has been analyzed as being dissolved substitutionally in RuAl and also segregated to grain boundaries. Upon grain growth, lattice diffusion and segregation of impurity atoms in grain boundaries have been verified by the lattice parameter variation. The incremental apparent activation energy for grain growth at different temperatures is related to the accumulation of impurities in grain boundaries. Reordering and strain relaxation processes that accompany grain growth could consume a certain part of the driving force for grain growth.

Laser Interference Metallurgy - using interference as a tool for micro/nano structuring

Abstract Interfering laser beams of a high-power pulsed laser provide the opportunity of applying a direct lateral interaction with the surface microstructure of metals in micro/nano-scale based on photo-thermal nature mechanisms. This “Laser interference metallurgy” allows the creation of periodic patterns of features with a well defined long-range order on metallic surfaces at the scale of typical microstructures (from the sub micrometer level up to micrometers). This technique is an approach to initiate metallurgical processes such as melting, recrystallization, recovery, and defect and phase formation in the lateral scale of the microstructure itself and with an additional long range order given by the interference periodicity. In this work, the laser interference theory is described and used to calculate multi-beam interference patterns. A method to calculate the numbers of laser beams as well as the geometrical arrangement of the beams to obtain a desired periodical pattern prior to experiments is presented. The formation of long-range-ordered intermetallic compounds as well as macroscopic and microscopic variations of mechanical properties on structured metallic thin films are presented as examples.

Deterministic Coupling of a Single Silicon-Vacancy Color Center to a Photonic Crystal Cavity in Diamond

Deterministic coupling of single solid-state emitters to nanocavities is the key for integrated quantum information devices. We here fabricate a photonic crystal cavity around a preselected single silicon-vacancy color center in diamond and demonstrate modification of the emitters internal population dynamics and radiative quantum efficiency. The controlled, room-temperature cavity coupling gives rise to a resonant Purcell enhancement of the zero-phonon transition by a factor of 19, coming along with a 2.5-fold reduction of the emitters lifetime.

Contact Killing of Bacteria on Copper Is Suppressed if Bacterial-Metal Contact Is Prevented and Is Induced on Iron by Copper Ions

ABSTRACT Bacteria are rapidly killed on copper surfaces, and copper ions released from the surface have been proposed to play a major role in the killing process. However, it has remained unclear whether contact of the bacteria with the copper surface is also an important factor. Using laser interference lithography, we engineered copper surfaces which were covered with a grid of an inert polymer which prevented contact of the bacteria with the surface. Using Enterococcus hirae as a model organism, we showed that the release of ionic copper from these modified surfaces was not significantly reduced. In contrast, killing of bacteria was strongly attenuated. When E. hirae cells were exposed to a solid iron surface, the loss of cell viability was the same as on glass. However, exposing cells to iron in the presence of 4 mM CuSO4 led to complete killing in 100 min. These experiments suggest that contact killing proceeds by a mechanism whereby the metal-bacterial contact damages the cell envelope, which, in turn, makes the cells susceptible to further damage by copper ions.

Transmittance enhancement and optical band gap widening of Cu2O thin films after air annealing

Cu2O thin films have been grown on glass substrates at room temperature by reactive magnetron sputtering. As-deposited films exhibit high electrical resistivity and low optical transmittance. To improve the film properties, post annealing treatments in air at various temperatures have been performed. Low temperature annealing (<300 °C) avoids the film oxidation into CuO and the films remain single-phased. In this temperature range, the annealing in air enhances the transmittance in the visible region due to the decrease of the defect scattering. Moreover, the optical band gap of Cu2O thin films is enlarged from 2.38 to 2.51 eV with increasing annealing temperature. The increase of optical band gap accompanying the reduction of Urbach energy indicates that the widening of optical band gap may result from the partial elimination of defect band tail after thermal annealing in air. Combining experimental results with recent reported calculations, the peak at about 1.7 eV in photoluminescence spectra is assign...

Description of the discharge process in spark plugs and its correlation with the electrode erosion patterns

The phases of the discharges in spark plugs were studied with a high-speed camera and an oscilloscope. The discharges were done using samples of nickel alloys and platinum as cathode in air at pressures ranging from 100 to 900 kPa. For low pressures (100 kPa), a glow discharge occurs after the breakdown. For higher pressures, an arc discharge follows the breakdown and changes into a glow discharge when the current decreases. The damage produced on the cathode surface was analyzed with scanning electron microscopy and white light interferometry and was correlated with the corresponding discharge. The craters on the surface are mainly produced by the breakdown and arc discharge. The glow discharge delivers energy to the cathode in a large area and produces a negligible material damage. The movement of the arc hot spot produces further craters that are commonly overlapped. Transitions from glow to arc modes produce new small craters, which in some cases can be arranged along polishing traces. This work is relevant for the development of new electrode materials for spark plugs and electrical contacts.

Physicochemical properties of copper important for its antibacterial activity and development of a unified model

Contact killing is a novel term describing the killing of bacteria when they come in contact with metallic copper or copper-containing alloys. In recent years, the mechanism of contact killing has received much attention and many mechanistic details are available. The authors here review some of these mechanistic aspects with a focus on the critical physicochemical properties of copper which make it antibacterial. Known mechanisms of contact killing are set in context to ionic, corrosive, and physical properties of copper. The analysis reveals that the oxidation behavior of copper, paired with the solubility properties of copper oxides, are the key factors which make metallic copper antibacterial. The concept advanced here explains the unique position of copper as an antibacterial metal. Based on our model, novel design criteria for metallic antibacterial materials may be derived.

Contact Mechanics of Laser-Textured Surfaces

We study numerically the contact mechanics of a flat and a curved solid. Each solid bears laser-induced, periodic grooves on its rubbing surface. Our surface topographies produce a similar load and resolution dependence of the true contact area as nominally flat, but randomly rough, self-affine surfaces. However, the contact area of laser-textured solids depends on their relative orientation. The estimated true contact areas correlate with kinetic friction measurements.

Dispersion analysis of carbon nanotubes, carbon onions, and nanodiamonds for their application as reinforcement phase in nickel metal matrix composites

Dispersions of multi-wall carbon nanotubes, onion-like carbon, and nanodiamonds in ethylene glycol are produced using a homogenizer and an ultrasonic bath, altering the treatment time. The dispersed particles are then used as reinforcement phase for nickel matrix composites. These nanoparticles are chosen to represent different carbon hybridization states (sp2 vs. sp3) or a different particle geometry (0D vs. 1D). This allows for a systematic investigation of the effect of named differences on the dispersibility in the solvent and in the composite, as well as the mechanical reinforcement effect. A comprehensive suite of complementary analytical methods are employed, including transmission electron microscopy, Raman spectroscopy, dynamic light scattering, sedimentation analysis, zeta-potential measurements, scanning electron microscopy, electron back scatter diffraction, and Vickers microhardness measurements. It can be concluded that the maximum achievable dispersion grade in the solvent is similar, not altering the structural integrity of the particles. However, nanodiamonds show the best dispersion stability, followed by onion-like carbon, and finally multi-walled carbon nanotubes. The distribution and agglomerate sizes of the particles within the composites are in good agreement with the dispersion analysis, which is finally correlated with a maximum grain refinement by a factor of 3 and a maximum mechanical reinforcement effect for nanodiamonds.