Frank Oldfield

The calculation of lead-210 dates assuming a constant rate of supply of unsupported 210Pb to the sediment

Summary The paper describes a method of calculating sediment age from 210Pb profiles where changes in accumulation rate have affected initial 210Pb concentration. Previously published age/depth profiles derived from 210Pb measurements have assumed a constant initial concentration of unsupported 210Pb per unit dry weight at each stage of accumulation, despite variations in accumulation rates. In sediments from three sites which have experienced rapid acceleration in accumulation in recent times, the assumption is not compatible with the measured unsupported 210Pb concentrations. the alternative assumption of a constant rate of supply of unsupported 210Pb to the sediments per unit time allows calculation of age throughout the profiles irrespective of evidence for rapidly accelerating accumulation. The methods of calculation used are outlined, illustrated and discussed in the light of evidence obtained from the sediments of Lough Erne and Lough Neagh, N. Ireland and lakes Ipea and Egari in the Highlands of Papua New Guinea. They provide a means of dating variations in accumulation rate resulting from human activity in the drainage basin.

210Pb dating by low background gamma counting

Lead-210 and radium-226 measurements by direct gamma assay can now provide a record of changing concentrations in lake sediments sufficiently reliable and precise to form a suitable basis for age/depth and dry-sedimentation-rate calculations. There are additional benefits in terms of non destructive sample preparation and simultaneous assay for other environmentally significant gamma-emitting radioisotopes (e.g. 137Cs and 241Am). Results from L. Fleet, S. W. Scotland illustrate the value of this approach especially in lakes with disturbed catchments where variable input of supported 210Pb has occurred.

High-resolution multi-proxy climate records from Chinese loess: evidence for rapid climatic changes over the last 75 kyr

The loess/paleosol sequence in loess layer L1 (Malan Loess) is investigated in three regions of the Western Chinese Loess Plateau. Nine pedogenic layers are found in L1 and three proxy climate indices, magnetic susceptibility (MS), grain size (GS) and CaCO3 content, are measured at intervals of 0.2 kyr in order to recover records of monsoon climate variations. Time series of MS, GS and CaCO3 content document the high resolution history of summer and winter monsoon climate variations over the last 75 kyr. The records show a high degree of similarity to the warm interstadials recorded in ice cores from Greenland and the Antarctic, and with Heinrich events in the North Atlantic, during the last glacial cycle. Bond cycles are also recorded by the Chinese loess records. Overall, our results indicate that numerous rapid changes in climate occurred in China during the last glacial cycle, but that the range of climate variations was smaller than recorded in Greenland.

Environmental magnetism — A personal perspective

Abstract Environmental magnetism is a versatile methodology applicable to a wide range of environmental studies and contexts. The complexity and unfamiliarity of many natural magnetic assemblages, coupled with the very versatility and sensitivity of the measurements can often limit interpretations at present, and there is an urgent need to improve the theoretical and quantitative basis for interpreting the results derived from these newly accessible techniques. There is also a need to make the results both more objective and more readily communicable to specialists in related fields. Examples are shown which illustrate the range of applications of magnetic measurements, and suggestions given as to the ways in which, in the future, environmental magnetists may be able to overcome current problems.

Environmental Applications of Magnetic Measurements

A wide range of examples of the application of magnetic measurements to environmental studies illustrate the advantages of magnetic techniques over conventional methods. Magnetic measurements, in both the field and the laboratory, are particularly useful for reconnaissance work because of their spee and flexibility, Quantification as well as simple diagnosis of the transformation and movement of magnetic minerals within and between the atmosphere, lithosphere, and hydrosphere is practical. Techniques of investigating intrinsic and mineral magnetic properties, in addition to paleomagnetic remanence, are described in subjects as diverse as meteorology, hydrology, sedimentology, geophysics, and ecology.

A multivariate mixing model for identifying sediment source from magnetic measurements

A sequential method for quantitative identification of sediment source components, based on magnetic measurements, has been developed and tested for sediments from the Rhode River, Maryland. Simulated mixing tests and multiple regression were employed to establish numerical relationships between source component proportions and the magnetic measurements of mixtures. On the basis of these multivariate mixing models, source components of three estuarine sediment cores were estimated by linear programming. The results strongly support the previous studies on this catchment which indicated a dramatic change in sediment source some 150 to 200 yr ago. Quantitative calculations are more useful and informative than purely qualitative descriptions.

Magnetic measurements and heavy metals in atmospheric particulates of anthropogenic origin

Abstract Recent investigations have established an apparent link between magnetic mineral and heavy metal concentrations in a variety of environmental contexts. Using a range of rapid, non-destructive magnetic measurements the magnetic components of power station fly ash and motor vehicle emissions have been characterised. The present investigation suggests that such an approach readily facilitates particle source differentiation and identification.

Delayed build-up of Arctic ice sheets during 400,000-year minima in insolation variability

Knowledge of the past variability of climate at high northern latitudes during astronomical analogues of the present interglacial may help to inform our understanding of future climate change. Unfortunately, long-term continuous records of ice-sheet variability in the Northern Hemisphere only are scarce because records of benthic 18O content represent an integrated signal of changes in ice volume in both polar regions. However, variations in Northern Hemisphere ice sheets influence the Siberian High (an atmospheric pressure system), so variations in the East Asian winter monsoon (EAWM)—as recorded in the aeolian dust deposits on the Chinese Loess Plateau—can serve as a useful proxy of Arctic climate variability before the ice-core record begins. Here we present an EAWM proxy record using grain-size variations in two parallel loess sections representative of sequences across the whole of the Chinese Loess Plateau over the past 900,000 years. The results show that during periods of low eccentricity and precessional variability at approximately 400,000-year intervals, the grain-size-inferred intensity of the EAWM remains weak for up to 20,000 years after the end of the interglacial episode of high summer monsoon activity and strong pedogenesis. In contrast, there is a rapid increase in the EAWM after the end of most other interglacials. We conclude that, for both the 400,000-year interglacials, the weak EAWM winds maintain a mild, non-glacial climate at high northern latitudes for much longer than expected from the conventional loess and marine oxygen isotope records. During these times, the less-severe summer insolation minima at 65° N (ref. 4) would have suppressed ice and snow accumulation, leading to a weak Siberian High and, consequently, weak EAWM winds.

Heavy metal and magnetic relationships for urban source sediments

A major problem in urban hydrology is the assessment of the relative contributions of different pollution sources within urban drainage systems. This paper examines the use of magnetic techniques for the identification of pollution sources and the possible relationships between heavy metal levels and several magnetic parameters. The characterisation of pollution sources by the use of magnetic methods is consistent with previously published results. Surface constructional materials and directly derived vehicular particulates have been analysed and compared with sediments sampled from within a highway catchment. The results of this analysis indicate that automobiles are the major source of metal pollution this is consistent with the results obtained for metal analysis of the sediment types. Strong linear relationships are observed between the metals (Cu, Fe, Pb and Zn) and ferrimagnetic concentration related parameters. The implications of these results regarding the use of magnetic techniques for the identification of pollution sources are discussed.

A high resolution late Holocene palaeo environmental record from the central Adriatic Sea

A multi-proxy study of a Holocene sediment core (RF 93-30) from the western flank of the central Adriatic, in 77 m of water, reveals a sequence of changes in terrestrial vegetation, terrigenous sediment input and benthic fauna, as well as evidence for variations in sea surface temperature spanning most of the last 7000 yr. The chronology of sedimentation is based on several lines of evidence, including AMS 14C dates of foraminifera extracted from the core, palaeomagnetic secular variation, pollen indicators and dated tephra. The temporal resolution increases towards the surface and, for some of the properties measured, is sub-decadal for the last few centuries. The main changes recorded in vegetation, sedimentation and benthic foraminiferal assemblages appear to be directly related to human activity in the sediment source area, which includes the Po valley and the eastern flanks of the central and northern Appenines. The most striking episodes of deforestation and expanding human impact begin around 3600 BP (Late Bronze Age) and 700 BP (Medieval) and each leads to an acceleration in mass sedimentation and an increase in the proportion of terrigenous material, reflecting the response of surface processes to widespread forest clearance and cultivation. Although human impact appears to be the proximal cause of these changes, climatic effects may also have been important. During these periods, signs of stress are detectable in the benthic foram morphotype assemblages. Between these two periods of increased terrigeneous sedimentation there is smaller peak in sedimentation rate around 2400BP which is not associated with evidence for deforestation, shifts in the balance between terrigenous and authigenic sedimentation, or changes in benthic foraminifera. The mineral magnetic record provides a sensitive indicator of changing sediment sources: during forested periods of reduced terrigenous input it is dominated by authigenic bacterial magnetite, whereas during periods of increased erosion, anti-ferromagetic minerals (haematite and/or goethite) become more important, as well as both paramagnetic minerals and super-paramagnetic magnetite. Analysis of the alkenone, U37k′, record provides an indication of possible changes in sea surface temperature during the period, but it is premature to place too much reliance on these inferred changes until the indirect effects of past changes in the depth of the halocline and in circulation have been more fully evaluated. The combination of methods used and the results obtained illustrate the potential value of such high resolution near-shore marine sedimentary sequences for recording wide-scale human impact, documenting the effects of this on marine sedimentation and fauna and, potentially, disentangling evidence for human activities from that for past changes in climate.