Fredrick Tamooh

The age of river‐transported carbon: A global perspective

The role played by river networks in regional and global carbon (C) budgets is receiving increasing attention. Despite the potential of radiocarbon measurements (Δ14C) to elucidate sources and cycling of different riverine C pools, there remain large regions for which no data are available and no comprehensive attempts to synthesize the available information and examine global patterns in the 14C content of different riverine C pools. Here we present new 14C data on particulate and dissolved organic C (POC and DOC) from six river basins in tropical and subtropical Africa and compiled >1400 literature Δ14C data and ancillary parameters from rivers globally. Our analysis reveals a consistent pattern whereby POC is progressively older in systems carrying higher sediment loads, coinciding with a lower organic carbon content. At the global scale, this pattern leads to a proposed global median Δ14C signature of −203‰, corresponding to an age of ~1800 years B.P. For DOC exported to the coastal zone, we predict a modern (decadal) age (Δ14C = +22 to +46‰), and paired data sets confirm that riverine DOC is generally more recent in origin than POC—in contrast to the situation in ocean environments. Weathering regimes complicate the interpretation of 14C ages of dissolved inorganic carbon, but the available data favor the hypothesis that in most cases, more recent organic C is preferentially mineralized.

Sediment and carbon fluxes along a longitudinal gradient in the lower Tana River (Kenya)

We estimated annual fluxes of suspended matter and different carbon (C) pools at three sites along the lower Tana River (Kenya), based on monthly sampling between January 2009 and December 2011. Concentrations of total suspended matter (TSM), particulate organic carbon (POC), dissolved organic carbon (DOC), and dissolved inorganic carbon (DIC) were monitored, as was the stable isotope composition of the carbon pools. Both TSM and POC concentrations showed strong seasonality, varying over several orders of magnitude, while DOC and DIC concentrations showed no seasonal variations. A strong shift in the origin of POC was observed, which was dominated by C3-derived C during dry conditions (low δ13CPOC between −28‰ and −25‰), but had significant C4 contributions during high-flow events (δ13CPOC up to −19.5‰). Between Garissa and the most downstream sampling point, a clear decrease in suspended matter and organic C fluxes was observed, being most pronounced during high-discharge conditions: on an annual basis, fluxes of TSM, POC, and DIC decreased by 34% to 65% for the 3 year study period. Our results suggest that floodplains along the lower Tana River could play an important role in regulating the transport of suspended matter and organic C. A comparison of current flux estimates with data collected prior to the construction of several hydropower dams reveals that the sediment loading is reduced during low discharge conditions.