Fritz Bien

Classical dynamics of the N(4S) + O2 (X³ Σg−) → NO(X²II) + O(³P) reaction

Classical trajectory calculations have been performed to determine the reaction rate constants and NO final vibrational-rotational distributions of the N(4S) + O2 reaction at hyperthermal translational energies. The reaction occurs on two electronic potential energy surfaces, both of which must be considered for a realistic description of the N(4S) + O2 dynamics. The calculations, which are in good agreement with the available experimental data, show that the reaction has a very strong translational energy dependence and produces NO with extensive vibrational and rotational excitation. The present study provides the N(4S) + O2 reaction attributes necessary to predict NO formation and emission from translationally hot N(4S) in the thermosphere.

Measurement of molecular concentrations and line parameters using line-locked second harmonic spectroscopy with an AlGaAs diode laser

The technique of line-locked wavelength modulation with 2f detection is applied to the measurement of water vapor concentration and absorption line parameters by using an 820-nm AlGaAs communications diode laser. Measurements of the 2f signal as a function of the modulation amplitude yield accurate concentrations and line parameters over a pressure range of an order of magnitude and half-widths from 0.02 to 0.15 cm(-1). Usingtwo different spectral lines, we determined concentrations and line parameters with 1% precision, and the absolute accuracy of the line parameters is 3% or better. The results have been used to calculate calibration curves for a diode laser humidity monitor.

Laser Raman sensor for measurement of trace-hydrogen gas

A new optical hydrogen sensor based on spontaneous Raman scattering of laser light has been designed and constructed for rugged field use. It provides good sensitivity (better than 100 parts in 10(6)), rapid response (several seconds), and the inherent Raman characteristics of linearity and background gas independence of the signal. Efficient light collection and discrimination by using fast optics and a bandpass interference filter compensate for the inefficiency of the Raman-scattering process. A multipass optical cavity with a Herriott-type configuration provides intense illumination from an air-cooled cw gas laser. The observed performance is in good agreement with the theoretical signal and noise level predictions.

Innovative Minimally Intrusive Sensor Technology Development for Versatile Affordable Advanced Turbine Engine Combustors

The feasibility of an innovative minimally intrusive sensor for monitoring the hot gas stream at the turbine inlet in high performance aircraft gas turbine engines was demonstrated. The sensor uses passive fiber-optical probes and a remote readout device to collect and analyze the spatially resolved spectral signature of the hot gas in the combustor/turbine flowpaths. Advanced information processing techniques are used to extract the average temperature, temperature pattern factor, and chemical composition on a sub-second time scale. Temperatures and flame composition were measured in a variety of combustion systems including a high pressure, high temperature combustion cell. Algorithms for real-time temperature measurements were developed and demonstrated. This approach should provide a real-time temperature profile, temperature pattern factor, and chemical species sensing capability for multi-point monitoring of high temperature and high pressure flow at the combustor exit with application as an engine development diagnostic tool, and ultimately, as a real-time active control component for high performance gas turbines.Copyright

In-situ ammonia analyzer for process control and environmental monitoring

An ammonia monitor designed for in situ smoke stack or exhaust duct applications is discussed here. A probe composed of a diffusion cell with a protected multipass optical measurement cavity provides the optical interaction with the sample. Other components of the system include signal processing electronics and an embedded PC104 computer platform. This instrument is useful in a wide variety of ammonia monitoring and process control applications, particularly ammonia-based NOx control technologies, such as selective catalytic reduction (SCR) and selective non-catalytic reduction (SNCR). The in situ design eliminates sample handling problems, associated with extractive analysis of ammonia, such as sample line adsorption and heated sample trains and cells. The sensor technology exploited in this instrument is second harmonic spectroscopy using a near infrared diode laser. Data collected during field trials involving both SCR and SNCR applications demonstrate the feasibility and robust operation of this instrument in traditionally problematic operating environments. The instrument can measure other gases by changing the wavelength, either by changing the diode operational set point or by changing the diode. In addition, with straightforward modification the instrument can measure multiple species.

Automated remote monitoring of toxic gases with diode-laser-based sensor systems

Spectral Sciences has developed a family of automated remote gas sensors including a long-path absorption system, and a fiber- optic-based system utilizing multiple remote-sensing heads. Results are presented from initial field tests of the long-path sensor.

Comparison of NH3 point monitoring and diode-laser-based path-integrated measurements

Measurements made using two different types of ammonia monitors during a two-month field study in the summer of 1994 are discussed. The first instrument was a diode-laser based open path monitor designed for automated operation in an industrial environment. The second is a point monitor based on thermal decomposition of ammonia to NO and subsequent analysis by O3 - NO chemiluminescence. The two monitors provided consistent measurements of ammonia during weeks of continuous unattended operation.

In Situ Measurement of Hydrochloric Acid in Rocket Exhaust Clouds Using a Remotely Piloted Aircraft

Abstract An instrumentation system employing an RPV (remotely piloted vehicle) platform was developed for temporally and spatially resolved air pollution measurements, and was used to measure the evolution of gas-phase HC1 in exhaust clouds from a solid rocket motor firing and fuel pit burns. A thermistor and a sensitive (ppmv-level), rapid-response (<0.1 sec) infrared absorption sensor for HC1 were mounted in a flow channel in the RPV, permitting concentration and temperature measurements to be made in the cloud on a several-meter scale. The RPV system was flown in a series of field tests at Thiokol Corporation’s Elkton, MD division to evaluate the HC1 content of the exhaust products of a new Mg-based fuel formulation. Measurements were made in the clouds from Al-based and Mg-based solid fuel pit burns and a Mg-fueled motor firing over periods of several minutes. Elevated temperatures and HC1 concentrations were found to be temporally correlated with video images of the particulate cloud. Cl originating ...