Frode Leirvik

Droplet breakup in subsurface oil releases – Part 1: Experimental study of droplet breakup and effectiveness of dispersant injection

Size distribution of oil droplets formed in deep water oil and gas blowouts have strong impact on the fate of the oil in the environment. However, very limited data on droplet distributions from subsurface releases exist. The objective of this study has been to establish a laboratory facility to study droplet size versus release conditions (rates and nozzle diameters), oil properties and injection of dispersants (injection techniques and dispersant types). This paper presents this facility (6 m high, 3 m wide, containing 40 m(3) of sea water) and introductory data. Injection of dispersant lowers the interfacial tension between oil and water and cause a significant reduction in droplet size. Most of this data show a good fit to existing Weber scaling equations. Some interesting deviations due to dispersant treatment are further analyzed and used to develop modified algorithms for predicting droplet sizes in a second paper (Johansen et al., 2013).

Depletion and biodegradation of hydrocarbons in dispersions and emulsions of the Macondo 252 oil generated in an oil-on-seawater mesocosm flume basin.

Physically and chemically (Corexit 9500) generated Macondo 252 oil dispersions, or emulsions (no Corexit), were prepared in an oil-on-seawater mesocosm flume basin at 30-32 °C, and studies of oil compound depletion performed for up to 15 days. The use of Corexit 9500 resulted in smaller median droplet size than in a physically generated dispersion. Rapid evaporation of low boiling point oil compounds (C⩽15) appeared in all the experiments. Biodegradation appeared to be an important depletion process for compounds with higher boiling points in the dispersions, but was negligible in the surface emulsions. While n-alkane biodegradation was faster in chemically than in physically dispersed oil no such differences were determined for 3- and 4-ring PAH compounds. In the oil dispersions prepared by Corexit 9500, increased cell concentrations, reduction in bacterial diversity, and a temporary abundance of bacteria containing an alkB gene were associated with oil biodegradation.

Large-scale oil-in-ice experiment in the Barents Sea: Monitoring of oil in water and MetOcean interactions

A large-scale field experiment took place in the marginal ice zone in the Barents Sea in May 2009. Fresh oil (7000 L) was released uncontained between the ice floes to study oil weathering and spreading in ice and surface water. A detailed monitoring of oil-in-water and ice interactions was performed throughout the six-day experiment. In addition, meteorological and oceanographic data were recorded for monitoring of the wind speed and direction, air temperature, currents and ice floe movements. The monitoring showed low concentrations of dissolved hydrocarbons and the predicted acute toxicity indicated that the acute toxicity was low. The ice field drifted nearly 80 km during the experimental period, and although the oil drifted with the ice, it remained contained between the ice floes.

Pneumatic oil barriers: The promise of area bubble plumes

Reviews of bubble curtain oil herding studies in 1971 and in 1997 concluded that a bubble oil boom, or pneumatic oil barrier, is ineffective for retaining oil spills except in quiescent water, such as harbors. A bubble oil boom generates a sea-surface outwelling flow that traps or blocks oil. The primary bubble oil boom failure mode arises from oil droplet injection due to turbulence and instabilities at the oil slick front, where the outwelling flow balances the oil spreading. Bubble oil boom leakage occurs where these droplets are entrained into and pass through the bubble barrier. Increasing bubble flow creates stronger outwelling flows but increases turbulence and instabilities, leading to enhanced oil droplet entrainment. Natural seep observations, field trials, and laboratory studies demonstrate that a bubble plume with a wide bubble oil boom area, which is driven by an array of several parallel spargers (a bubble raft), can increase oil retention greatly while addressing key bubble oil boom failure modes compared with a line-source bubble curtain plume. Further improvements are identified by synergistic bubble oil boom application with a retaining skirt, dramatically improving the bubble oil boom performance. Specifically, the bubble oil boom keeps the oil distant from the skirt, minimizing or eliminating several conventional oil boom failure mechanisms. Also, entrained droplets, which easily traverse a single bubble curtain, are blocked effectively by a wide bubble plume curtain.

The use of wide-band transmittance imaging to size and classify suspended particulate matter in seawater

An in situ particle imaging system for measurement of high concentrations of suspended particles ranging from 30μm to several mm in diameter, is presented. The system obtains quasi-silhouettes of particles suspended within an open-path sample volume of up to 5cm in length. Benchmarking against spherical standards and the LISST-100 show good agreement, providing confidence in measurements from the system when extending beyond the size, concentration and particle classification capabilities of the LISST-100. Particle-specific transmittance is used to classify particle type, independent of size and shape. This is applied to mixtures of oil droplets, gas bubbles and oil-coated gas bubbles, to provide independent measures of oil and gas size distributions, concentrations, and oil-gas ratios during simulated subsea releases. The system is also applied to in situ measurements of high concentrations of large mineral flocs surrounding a submarine mine tailings placement within a Norwegian Fjord.

Spreading of waxy oils on calm water

The objective of this paper is to provide a simple extension of the much-used gravity spreading model for oil on calm water to account for the spreading behavior of waxy crude oils in cold waters - including the observed retardation and eventual termination of spreading at certain oil film thicknesses. This peculiar behavior is not predicted by traditional spreading models for oil on calm water (i.e. viscous-gravity spreading models), but may occur due to non-Newtonian oil properties caused by precipitation of wax at low temperatures. To clarify the spreading behavior of such oils, SINTEF has conducted a series of laboratory experiments with a range of waxy oil mixtures. The present paper contains analyses of data from these experiments, including favorable comparisons with calculations by a proposed improved surface spreading model.

Subsea dispersants injection (SSDI), effectiveness of different dispersant injection techniques – An experimental approach

The main objective with this study has been to study injection techniques for subsea dispersant injection (SSDI) to recommend techniques relevant for both laboratory studies and operational response equipment. The most significant factor was the injection point of the dispersant in relation to the release of the oil. The dispersant should be injected immediately before or after the oil is released. Then the dispersant will mix into the oil and reduce IFT before the oil enters the turbulent zone where initial droplet formation occurs. All injection techniques tested gave significant reductions in oil droplet sizes. However, due to the rapid oil droplet formation in turbulent jets and possible formation of surfactant aggregates in the oil, premixing of dispersants should not be used for experimental studies of subsea dispersant injection. This could underestimate dispersant effectiveness and produce results that might not be representative for up-scaled field conditions.