Fumin Wang
Tianjin University
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Featured researches published by Fumin Wang.
Catalysis Science & Technology | 2015
Hang Li; Fumin Wang; Wangfeng Cai; Jinli Zhang; Xubin Zhang
Phosphorus-doped copper catalysts supported on spherical activated carbon (SAC) were prepared using an incipient wetness impregnation technique. The catalysts were characterized by low-temperature N2 adsorption/desorption, X-ray diffraction (XRD), transmission electron microscopy (TEM), temperature-programmed reduction (TPR), X-ray photoelectron spectroscopy (XPS), inductively coupled plasma (ICP), N2O pulse titration method and thermogravimetric (TG) technologies. The results indicate that the phosphorus-doped Cu-based catalysts exhibit both high activity and good stability. The amount of phosphorus dopant has a significant effect on the catalytic activity of acetylene hydrochlorination and the optimal molar ratio of Cu/P is 2.5. The phosphorus doping facilitates the dispersion of copper species, enhances the interaction between metal and support, and restrains the growth of copper species during acetylene hydrochlorination. These results suggest that this high-activity, good-stability and low-cost catalyst has great potential in industrial applications.
RSC Advances | 2016
Yi Xie; Mingshuai Sun; Yu Shen; Hang Li; Guojun Lv; Zhe Cai; Chaoqun Yang; Gusai Awadalkrim Ahead Ali; Fumin Wang; Xubin Zhang
A series of reduced graphene oxide–mesoporous silica nanoflakes (rGO–MSN) with adjustable surface wettability were developed. Detailed SEM, TEM, XRD, BET, and TGA analyses demonstrated that morphologies, structures, porosities of the obtained composite materials were greatly influenced by rGO content. Moreover, micrographs and conductivity measurements were conducted to investigate the performance of rGO–MSN as emulsifier in stabilizing paraffin/water two-phase system. Furthermore, anchored with –SO3H, the modified hybrid nanoflakes SO3H–rGO–MSN-x% were employed as solid emulsifier and catalyst (Pickering interfacial catalyst) at solvent free oil–oil interface for acetal reaction and showed excellent dodecyl aldehyde conversion more than 90%.
RSC Advances | 2015
Lei Xu; Guojun Lv; Hang Li; Yu Shen; Wangfeng Cai; Fumin Wang; Xubin Zhang
Functional TS-1, partially hydrophobilized with organosilanes, was found to be more active and stable in a Pickering emulsion. In this work, TS-1 behaved simultaneously as a catalyst and solid emulsifier favoring the cyclohexanone ammoximation reaction in organic solvent-free conditions. The composition, structure, formed emulsion morphology, and surface morphology were characterized by Fourier-transform infrared (FT-IR) spectroscopy, conductometer, optical microscope with high speed CCD camera, Brunauer–Emmett–Teller (BET), X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). It indicated that hydrophobilization provided TS-1 a moderate wettability, allowing the formation of a stable Pickering emulsion, thus promoting the performance in catalyzing the cyclohexanone/H2O2/NH3·H2O reaction in the absence of organic solvents. What is more, due to alkyl groups grafted to TS-1, the zeolites were comparatively exclusive to the aqueous phase and they are more capable of enduring severe environment, i.e., 200 °C, under autogenic pressure.
Australian Journal of Chemistry | 2017
Yu Shen; Fumin Wang; Chaoqun Yang; Xubin Zhang
Hierarchical HZSM-5 were synthesised by controlled desilication in alkaline medium and characterised by field-emission scanning electron microscopy, X-ray diffraction, transmission electron microscopy, inductively coupled plasma–atomic emission spectrometry, N2 adsorption–desorption, and Fourier transform infrared spectroscopy. The catalytic performance of HZSM-5 towards the selective oxidation of 2,3,6-trimethylphenol by H2O2 was evaluated. Recyclability tests were also carried out. The results showed that 2,3,5-trimethyl-1,4-benzoquinone was produced in high yields (i.e. 90 %), corresponding to a 2,3,6-trimethylphenol percentage of 98 %. The N2 adsorption–desorption and XRD studies suggested that mesopores with an average size of 5 nm were produced and that the structural character of HZSM-5 was preserved after desilication. Transmission electron microscopy analysis of the spent catalyst indicated good stability of the hierarchical structure. The Fourier transform infrared spectroscopy studies revealed the development of acid sites. The combined results suggested that the nature of the solvent, intrinsic acidity, and shape selectivity of the hierarchical structure of the catalyst ensured high catalytic properties.
Materials Letters | 2006
Ruisong Guo; Qiang Wei; Haipeng Li; Fumin Wang
Chemical Engineering & Technology | 2013
Zhen-Chuan Fan; Xubin Zhang; Wangfeng Cai; Fumin Wang
Colloids and Surfaces A: Physicochemical and Engineering Aspects | 2014
Guojun Lv; Fumin Wang; Wangfeng Cai; Xubin Zhang
Experimental Thermal and Fluid Science | 2013
Jing Tang; Xubin Zhang; Wangfeng Cai; Fumin Wang
Journal of Materials Science | 2005
Qiang Wei; Ruisong Guo; Fumin Wang; Haipeng Li
Colloids and Surfaces A: Physicochemical and Engineering Aspects | 2014
Guojun Lv; Fumin Wang; Wangfeng Cai; Xubin Zhang