G. Dunn

The strong influence of substrate conductivity on droplet evaporation

We report the results of physical experiments that demonstrate the strong influence of the thermal conductivity of the substrate on the evaporation of a pinned droplet. We show that this behaviour can be captured by a mathematical model including the variation of the saturation concentration with temperature, and hence coupling the problems for the vapour concentration in the atmosphere and the temperature in the liquid and the substrate. Furthermore, we show that including two ad hoc improvements to the model, namely a Newtons law of cooling on the unwetted surface of the substrate and the buoyancy of water vapour in the atmosphere, give excellent quantitative agreement for all of the combinations of liquid and substrate considered.

On the effect of the atmosphere on the evaporation of sessile droplets of water

An experimental and theoretical study of the effect of the atmosphere on the evaporation of pinned sessile droplets of water is described. The experimental work investigated the evaporation rates of sessile droplets in atmospheres of three different ambient gases (namely, helium, nitrogen, and carbon dioxide) at reduced pressure (from 40 to 1000 mbars) using four different substrates (namely, aluminum, titanium, Macor, and polytetrafluoroethylene) with a wide range of thermal conductivities. Reducing the atmospheric pressure increases the diffusion coefficient of water vapor in the atmosphere and hence increases the evaporation rate. Changing the ambient gas also alters the diffusion coefficient and hence also affects the evaporation rate. A mathematical model that takes into account the effect of the atmospheric pressure and the nature of the ambient gas on the diffusion of water vapor in the atmosphere and the thermal conductivity of the substrate is developed, and its predictions are found to be in enc...

Evaporation of a thin droplet on a thin substrate with a high thermal resistance

A mathematical model for the quasisteady evaporation of a thin liquid droplet on a thin substrate that incorporates the dependence of the saturation concentration of vapor at the free surface of the droplet on temperature is used to examine an atypical situation in which the substrate has a high thermal resistance relative to the droplet (i.e., it is highly insulating and/or is thick relative to the droplet). In this situation diffusion of heat through the substrate is the rate-limiting evaporative process and at leading order the local mass flux is spatially uniform, the total evaporation rate is proportional to the surface area of the droplet, and the droplet is uniformly cooled. In particular, the qualitative differences between the predictions of the present model in this situation and those of the widely used “basic” model in which the saturation concentration is independent of temperature are highlighted.

On the Effect of an Atmosphere of Nitrogen on the Evaporation of Sessile Droplets of Water

The effect of an atmosphere of nitrogen on the evaporation of pinned sessile droplets of water is investigated both experimentally and theoretically.

The effect of the thermal conductivity of the substrate on droplet evaporation

The evaporation of liquid droplets is of fundamental importance to industry, with a vast number of applications including ink-jet printing, spray cooling and DNA mapping, and has been the subject of considerable theoretical and experimental research in recent years. Significant recent papers include those by Deegan [1], Deegan et al. [2], Hu and Larson [3], Poulard et al. [4], Sultan et al. [5], and Shahidzadeh-Bonn et al. [6].