G. M. Panova

Hydrolysis of Bis[5,5-dimethyl-3-(4-oxa-1-azoniacyclohexylidene)-1-cyclohexenyl] Sulfide Diperchlorate

Hydrolysis of bis[5,5-dimethyl-3-(4-oxa-1-azoniacyclohexylidene)-1-cyclohexenyl] sulfide diperchlorate, as well as of bis(5,5-dimethyl-3-thioxo-1-cyclohexenyl) sulfide, in the system MeCN-Et3N yields a mixture of bis(5,5-dimethyl-3-oxo-1-cyclohexenyl) sulfide and isomeric 5,5-dimethyl-3-oxo-1-cyclohexenyl 3,3-dimethyl-5-oxo-1-cyclohexenyl sulfide. The structure of the products and their ratio were established by 1H and 13C NMR and IR spectroscopy.

Intramolecular Thiiranocyclobutane-Open Chain Isomerization of 3,3'-Dithioxo Sulfide Derivatives: A Quantum-Chemical Study

The thermodynamic stability and structural and electronic characteristics of thiabicyclic structures, expected products of photochemical isomerization of bis(3-thioxo-1-phenylpropenyl), bis(3-thioxo-1-propenyl), and bis(5,5-dimethyl-3-thioxocyclohex-1-enyl) sulfides, were evaluated by quantum-chemical calculations. The energy in the thiabicyclic structures is accumulated owing to formation of metastable highly strained fused systems. The heats of dark isomerization of thiabicyclic structures into acyclic ones range from 50 to 250 kJ mol-1. The activation energy of thermal transformations into acyclic isomers are 90-310 kJ mol-1. Higher thermal effects and lower activation energies are obtained when the polarity of the medium is taken into account. The calculation results show that this class of compounds is promising for solar energy conversion.

Steric Structure of Bis(5,5-dimethyl-3-thioxo-1-cyclohexenyl) Sulfide

Two-dimensional NMR spectroscopy, dipole moment measurements, and quantum-chemical calculations (basis 6-31G*) were used to show that in the gas phase and in solutions bis(5,5-dimethyl-3-thioxo-1-cyclohexenyl) sulfide prefers a nonplanar cis-trans conformation.