Gangjian Wei

Geochemical and Nd isotopic variations in sediments of the South China Sea: a response to Cenozoic tectonism in SE Asia

Secular variations in geochemistry and Nd isotopic data have been documented in sediment samples at ODP Site 1148 in the South China Sea. Major and trace elements show significant changes at ca. 29.5 Ma and 26^23 Ma, whereas ONd values show a single change at ca. 26^23 Ma. Increases in Al/Ti, Al/K, Rb/Sr, and La/Lu ratios and a decrease in the Th/La ratio of the sediments beginning at 29.5 Ma are consistent with more intense chemical weathering in the source region. The abrupt change in Nd isotopes and geochemistry at ca. 26^23 Ma coincides with a major discontinuity in the sedimentology and physical properties of the sediments, implying a drastic change in sedimentary provenance and environment at the drill site. Comparison of the Nd isotopes of sediments from major rivers flowing into the South China Sea suggests that pre-27 Ma sediments were dominantly derived from a southwestern provenance (Indochina^Sunda Shelf and possibly northwestern Borneo), whereas post-23 Ma sediments were derived from a northern provenance (South China). This change in provenance from southwest to north was largely caused by ridge jumping during seafloor spreading of the South China Sea, associated with a southwestward expansion of the ocean basin crust and a global rise in sea level. Thus, the geochemical and Nd isotopic changes in the sediments at ODP Site 1148 are interpreted as a response to a major plate reorganization in SE Asia at ca. 25 Ma. B 2003 Elsevier Science B.V. All rights reserved.

Geochemical and Sm-Nd isotopic study of amphibolites in the Cathaysia Block, southeastern China: evidence for an extremely depleted mantle in the Paleoproterozoic

Abstract Geochemical and Sm–Nd isotopic results are reported for late Paleoproterozoic mafic amphibolites from SW Zhejiang and NW Fujian, parts of the Cathaysia Block of SE China. Two suites of contemporaneous amphibolites are distinct in their geochemical characteristics. Group 1 samples, from NW Fujian, have chemical compositions of transitional and alkali basalts, show LREE-enriched patterns and plot mainly in the field of within-plate basalt on a number of trace element discrimination diagrams. Group 2 rocks, from SW Zhejiang, have tholeiitic compositions and are characterized by flat to LREE-depleted patterns and fall into the MORB field. All the amphibolite samples have high eNd(T) values of +5.6 to +8.5 (T=1766±19 Ma). A positive correlation between eNd(T) and Nb/Th suggests possible mixing of a mantle-derived magma and a crustal component, with the least-contaminated samples having very high eNd(T) values (+8∼+8.5) and Nb/Th ratios of ∼13. The geochemical and isotopic characters and close temporal relationship of these two suites of amphibolites suggest that their magmatic precursors were likely formed in an environment similar to an ensialic rift developing into a proto-oceanic basin (e.g. the Gulf of Tadjoura). The exceptionally high eNd(T) values of up to +8.5 for some of the amphibolites suggest the presence of a time-integrated extremely depleted mantle source beneath Cathaysia during the Paleoproterozic.

Heavy metal pollution recorded in Porites corals from Daya Bay, northern South China Sea.

We examined metal-to-calcium ratios (Fe/Ca, Mn/Ca and Zn/Ca) in the growth bands of two Porites corals from Daya Bay, South China Sea, in order to trace long-term trends in local ambient pollution levels. Although Fe and Mn did not show any obvious increasing trends over 32 years in the period 1976-2007, peak values of Fe/Ca and Mn/Ca occurred in the mid-late 1980s, temporally-coeval with the local construction of a nuclear power station. Furthermore, both corals showed rapid increases in Zn concentrations over the past 14 years (1994-2007), most likely due to increases in domestic and industrial sewage discharge. The Daya Bay corals had higher concentrations of metals than other reported corals from both pristine and seriously polluted locations, suggesting that acute (Fe and Mn) and chronic (Zn) heavy metal contamination has occurred locally over the past approximately 32 years.

High‐resolution elemental records from the South China Sea and their paleoproductivity implications

[1] The biogenic-related elements Ca, Sr, Ba, P, Cd, scavenged Al, and Ti were analyzed by inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma atomic emission spectrometry (ICP-AES) for Core NS93-5 from the west slope of the South China Sea. Terrestrial input as estimated from the accumulation of Ti was higher during glacials than during interglacials. Carbonate accumulation rates are inversely related to those of terrestrial input, suggesting higher production of calcareous phytoplankton during interglacials. The accumulation patterns of authigenic Sr, Ba, P, and Cd match that of carbonate, further indicating higher calcareous phytoplankton production during interglacials. Scavenged Al and excess SiO2, which is related to biogenic opal, exhibit higher accumulation rates during glacials and correspond with changes in terrestrial input. This indicates that terrestrial input driven is important to siliceous phytoplankton production but not for calcareous phytoplankton production. As calcareous phytoplankton is the dominant component of the biogenic sediments in the South China Sea, particularly during interglacials, previous inference of higher productivity in the South China Sea during glacials based on only the biogenic opal proxy needs to be reconsidered.

Sea surface temperature records in the northern South China Sea from mid‐Holocene coral Sr/Ca ratios

[1] Three mid-Holocene sea surface temperature (SST) records spanning more than 30 years were reconstructed for the northern South China Sea using Sr/Ca ratios in Porites corals. The results indicate warmer than present climates between circa 6100 yr B.P. and circa 6500 yr B.P. with the mid-Holocene average minimum monthly winter SSTs, the average maximum monthly summer SSTs, and the average annual SSTs being about 0.5 degrees-1.4 degrees C, 0 degrees-2.0 degrees C, and 0.2 degrees-1.5 degrees C higher, respectively, than they were during 1970-1994. Summer SSTs decrease from circa 6500 yr B.P. to circa 6100 yr B.P. with a minimum centered at circa 6300 yr B.P. The higher average summer SSTs are consistent with a stronger summer monsoon during the mid-Holocene, and the decreasing trend indicates a secular decrease of summer monsoon strength, which reflects the change in summer insolation in the Northern Hemisphere. El Nino-Southern Oscillation (ENSO) cycles were apparent in both the mid-Holocene coral and modern instrumental records. However, the ENSO variability in the mid-Holocene SSTs was weaker than that in the modern record, and the SST record with the highest summer temperatures from circa 6460 yr B.P. to 6496 yr B.P. shows no robust ENSO cycle. This agrees with other studies that indicate that stronger summer monsoon circulation may have been associated with suppressed ENSO variability during the mid-Holocene.

Geochemical and Sr-Nd Isotopic Characteristics of Late Paleogene Ultrapotassic Magmatism in Southeastern Tibet

Geochemical and Sr-Nd isotopic data are reported for late Paleogene potassic lamprophyres from western Yunnan, southeastern margin of the Tibetan Plateau. These lamprophyres are mostly ultrapotassic in composition with K2O/Na2O = 2.1 to 5.2, except for a few samples with shoshonitic affinity showing slightly lower K2O/Na2O = 1.6 to 1.7. They are characterized by high initial 87Sr/86Sr ratios of 0.70624 to 0.70924; negative εNd(T) values of -1.7 to -4.6; enrichment in large-ion lithophile elements, light rare-earth elements, and Pb; and depletion in high-field-strength elements, resembling those of high K/Ti and low-Ti potassic magmas formed in subduction-related settings. These lamprophyres were generated by partial melting of a metasomatized, phlogopite-bearing spinel harzburgite lithospheric mantle source, followed by crystal fractionation and varying degrees of crustal assimilation. Relatively constant incompatible trace element ratios, such as Rb/ Sr (˜0.2), Rb/Ba (˜0.1), La/Sm (˜5), Th/K (˜0.0003), and Nb/La (˜0.2), and limited Sr and Nd isotopic compositions in the ultrapotassic rocks possibly reflect an evenly distributed metasomatized mantle source. With a general similarity in geochemistry, the potassic and ultrapotassic magmas from southeastern (40-30 Ma) and northern (<15 Ma) parts of the Tibetan Plateau display obvious differences in Th/U, Rb/Sr, and Sr-Nd isotopes. These differences in geochemistry and Sr-Nd isotopes suggest contrasting subcontinental lithosphere mantle bulk compositions beneath the southeastern and northern parts of the Tibetan Plateau, caused by metasomatism involving subducted sediments from distinct crustal provenances.

Paleoprecipitation record from coral Sr/Ca and δ18O during the mid Holocene in the northern South China Sea.

Coupled high-resolution Sr/Ca and δ18O records of a modern and a mid-Holocene coral from Sanya in the southern Hainan Island, northern South China Sea (SCS), were reported and the residual δ18O (Δδ18O) were calculated to indicate precipitation change in this region. Unlike other paleoclimate studies, this study focused on changes of precipitation time rather than precipitation amount. As negative Δδ18O peaks in coral generally correspond to peak precipitations or rainy seasons in the surrounding region, the time offsets between negative Δδ18O peaks and other seasonal indicators, such as sea surface temperature (SST), can well indicate the time of rainy seasons, and the precise time offsets can be estimated by the method of cross spectral analysis. The results of the modern coral indicate that the variation of the coral Δδ18O lags that of the instrumental measured precipitation by about 2 months, and about 3 months to the SST derived from coral Sr/Ca ratios. This agrees well with the modern observation that the salinity change in the southern coastal regions generally lags that of the precipitation in Hianan Island by about 2 months, and the precipitation change lags about 1 month behind the SST in this region. Thus, coral Δδ 18O records can be a reliable proxy for the change of rainy seasons in this region. The results of the mid-Holocene coral show about 2.5 months’ leading of the Δδ18O variation ahead of the SST. By compensating the approximate 3 months’ lag of the Δδ18O variation behind the SST in modern time, the occurrence of rainy seasons during the mid Holocene may have advanced about 5—6 months. In detail, it may start around December and end around April to May with maximum occurring around February. Therefore, rainy seasons mainly occur in winter through early spring during the mid Holocene, compared with that from May through October in modern times. Such precipitation patterns appear to agree with the mid-Holocene pollen records in this region. Variations of large-scale circulation may possibly result in such a different precipitation pattern. Further studies, in particular climate model studies collaborated with meteorologists, are required for a better understanding of the mechanism.

Records of Toba eruptions in the South China Sea ——Chemical characteristics of the glass shards from ODP 1143A

Three layers of volcanic tephra, sampled from ODP 1143 Site in the South China Sea, were observed at the mcd depth of 5.55 m, 42.66 m, and 48.25 m, and named, in this paper, layers of A, B, and C, respectively. All of these tephra layers have an average thickness of ca. 2 cm. They were constrained in age of ca. 0.070 Ma, ca. 0.80 Ma, and ca. 1.00 Ma, respectively, by the microbiostratigraphy data. These tephra layers were predominated by volcanic glass shards with a median grain size of 70–75 μm in diameter. Major chemical compositions analyzed by EMPA and comparison with the previous data from other scatter areas suggest that these three layers of tephra can correspond to the three layers of Toba tephra, YTT, OTT, and HDT, respectively, erupting during the Quaternary. The occurrence of these tephra layers in the South China Sea implies that the Toba eruptions often occurred in the summer monsoon seasons of the South China Sea during the Quaternary, and that the strength of eruptions was probably stronger than that previously estimated.

Acceleration of modern acidification in the South China Sea driven by anthropogenic CO2

Modern acidification by the uptake of anthropogenic CO2 can profoundly affect the physiology of marine organisms and the structure of ocean ecosystems. Centennial-scale global and regional influences of anthropogenic CO2 remain largely unknown due to limited instrumental pH records. Here we present coral boron isotope-inferred pH records for two periods from the South China Sea: AD 1048–1079 and AD 1838–2001. There are no significant pH differences between the first period at the Medieval Warm Period and AD 1830–1870. However, we find anomalous and unprecedented acidification during the 20th century, pacing the observed increase in atmospheric CO2. Moreover, pH value also varies in phase with inter-decadal changes in Asian Winter Monsoon intensity. As the level of atmospheric CO2 keeps rising, the coupling global warming via weakening the winter monsoon intensity could exacerbate acidification of the South China Sea and threaten this expansive shallow water marine ecosystem.

Decadal variations in trace metal concentrations on a coral reef: Evidence from a 159 year record of Mn, Cu, and V in a Porites coral from the northern South China Sea

Geochemical cycles of trace metals are important influences on the composition and function of the marine ecosystem. Although spatial distributions of most trace metals have now been determined in at least some parts of the oceans, temporal variations have barely been studied on account of data limitations. In this paper, we report on a 159 year record of trace metal concentrations from a Porites coral from the northern South China Sea (SCS), and discuss how oceanic and climatic processes control variations in Mn, Cu, and V concentrations in this region. Our results show that trace metal concentrations in the coral skeleton demonstrate decadal to interdecadal fluctuations, and that their variations are controlled by different mechanisms. The input of Mn to reef water is partly controlled by the Pacific Decadal Oscillation (PDO), which controls precipitation and river runoff. Surface water concentrations of the nutrient-like element Cu are controlled by summer upwelling to the east of Hainan Island. The concentrations of V show complex interrelationships, and are linked to riverine input prior to the 1990 and to upwelling after the 1990. Our results imply that in the northern SCS, ocean-atmosphere climate fluctuations, such as the PDO and the East Asian Summer Monsoon (EASM), are important factors that influence long-term variability of Mn, Cu, and V concentrations in seawater, by controlling precipitation-related river runoff and the strength of upwelling systems.