Gaoru Chen
Harbin University of Science and Technology
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Publication
Featured researches published by Gaoru Chen.
Journal of Materials Chemistry C | 2016
Gaoru Chen; Xuan Wang; Jiaqi Lin; Wenlong Yang; Haidong Li; Yinian Wen; Landi Li; Zhichao Jiang; Qingquan Lei
A designed nano-KTN/Ag core/shell structure endows nano-KTN@Ag/PVDF composite films with excellent properties of remarkably enhanced dielectric permittivity, low loss tangent and flexibility. It has been found that the incorporation of KTN@Ag nanoparticles can increase the average crystallite size of the β phase in a polymer matrix, which elevates the polarization level of the polymer matrix and increases the dielectric permittivity of the nanocomposites. 25 vol% composites own a remarkably enhanced dielectric permittivity (er = 230) at 100 Hz, which is due to MWS polarization at the internal interface between nano-KTN@Ag and the PVDF matrix, the increased induced polarization of the nanoparticles and the “boundary layer capacitor effect”. The low loss tangent is achieved because of an enhanced polarization reverse speed by the Ag shells and a blockage of charge transfer by PVDF chains. The percolation threshold of the composite films (fc = 0.317) was predicted by the percolation theory, and the theoretical results were in good agreement with the experimental data.
Journal of Materials Chemistry C | 2017
Gaoru Chen; Wenlong Yang; Jiaqi Lin; Xuan Wang; Dongping Li; Yu Wang; Mengfan Liang; Weimin Ding; Haidong Li; Qingquan Lei
This paper indicates that rational design and precise control for the structure and shape of nanofillers are effective for achieving the desired permittivity and breakdown strength for high energy densities of polymer nanocomposites. Two types of KTa0.5Nb0.5O3 (KTN) nanoparticles with different shapes (NC-KTN and NR-KTN) were introduced into the PVDF matrix. The molecular dynamic simulation and the Brunauer–Emmett–Teller (BET) surface area proved that the nonbonding interaction energy is stronger in the NR-KTN/PVDF composite films due to the larger surface area of NR-KTN (30.96 m2 g−1). In addition, the interfacial polarization related to the shape of nanofillers further improved the dielectric permittivity of NR-KTN/PVDF composite films. Through the comparison between the experimental data and various theoretical models, we concluded that the geometric shape of fillers has a significant impact on the dielectric constant of composite films.
Journal of Polymer Research | 2014
Jiaqi Lin; Ying Liu; Wenlong Yang; Zhibin Xie; Panpan Zhang; Xiaokang Li; Hui Lin; Gaoru Chen; Qingquan Lei
Journal of Physical Chemistry C | 2016
Gaoru Chen; Xuan Wang; Jiaqi Lin; Wenlong Yang; Haidong Li; Yinian Wen
Applied Physics A | 2016
Jiaqi Lin; Gaoru Chen; Wenlong Yang; Zhichao Jiang; Haidong Li; Li Wang; Zhehua Yan; Xuan Wang; Qingquan Lei
Journal of Polymer Research | 2016
Jiaqi Lin; Gaoru Chen; Wenlong Yang; Huan Li; Qingquan Lei
Journal of Materials Science: Materials in Electronics | 2017
Wenlong Yang; Haidong Li; Jiaqi Lin; Gaoru Chen; Yu Wang; Li Wang; Haowei Lu; Liangyu Chen; Qingquan Lei
Journal of Applied Polymer Science | 2017
Haowei Lu; Jiaqi Lin; Wenlong Yang; Lizhu Liu; Yu Wang; Gaoru Chen; Wei Huang
Journal of Applied Polymer Science | 2017
Haowei Lu; Lizhu Liu; Jiaqi Lin; Wenlong Yang; Ling Weng; Xiaorui Zhang; Gaoru Chen; Wei Huang
Journal of Physical Chemistry C | 2017
Gaoru Chen; Xuan Wang; Jiaqi Lin; Wenlong Yang; Dongping Li; Weimin Ding; Haidong Li