Gareth R.L. Chalmers

Characterization of gas shale pore systems by porosimetry, pycnometry, surface area, and field emission scanning electron microscopy/transmission electron microscopy image analyses: Examples from the Barnett, Woodford, Haynesville, Marcellus, and Doig units

The nanometer-scaled pore systems of gas shale reservoirs were investigated from the Barnett, Marcellus, Woodford, and Haynesville gas shales in the United States and the Doig Formation of northeastern British Columbia, Canada. The purpose of this article is to provide awareness of the nature and variability in pore structures within gas shales and not to provide a representative evaluation on the previously mentioned North American reservoirs. To understand the pore system of these rocks, the total porosity, pore-size distribution, surface area, organic geochemistry, mineralogy, and image analyses by electron microscopy were performed. Total porosity from helium pycnometry ranges between 2.5 and 6.6%. Total organic carbon content ranges between 0.7 and 6.8 wt. %, and vitrinite reflectance measured between 1.45 and 2.37%. The gas shales in the United States are clay and quartz rich, with the Doig Formation samples being quartz and carbonate rich and clay poor. Higher porosity samples have higher values because of a greater abundance of mesopores compared with lower porosity samples. With decreasing total porosity, micropore volumes relatively increase whereas the sum of mesopores and macropore volumes decrease. Focused ion beam milling, field emission scanning electron microscopy, and transmission electron microscopy provide high-resolution (∼5 nm) images of pore distribution and geometries. Image analysis provides a visual appreciation of pore systems in gas shale reservoirs but is not a statistically valid method to evaluate gas shale reservoirs. Macropores and mesopores are observed as either intergranular porosity or are confined to kerogen-rich aggregates and show no preferred orientation or align parallel with the laminae of the shale. Networks of mesopores are observed to connect with the larger macropores within the kerogen-rich aggregates.

Light volatile liquid and gas shale reservoir potential of the Cretaceous Shaftesbury Formation in northeastern British Columbia, Canada

The geologic controls on reservoir properties and potential hydrocarbon (volatile, low-molecular-weight liquid and gas) resources of the Cretaceous Shaftesbury Formation in northeastern British Columbia have been investigated. Maturity varies from the oil to dry gas window (Tmax = 429–486C), with increasing maturity and depth of burial toward the south. The Tmax, in degrees Celsius, is the oven temperature at the peak generation of S2 during pyrolysis. Total organic carbon (TOC) content ranges between 0.64 and 8.0 wt. %, with an average of 2.2 wt. %. The TOC content distribution mirrors the trends in maturity, with lower TOC content in areas of high maturity. Kerogen is characterized as either type II-III or type III. The quartz content ranges between 33 and 66%, with higher quartz content in areas with lower TOC content and greater maturities. Porosity ranges between 4.5 and 14.6%, with higher porosities observed within shallower wells, low quartz content, or maturities, or a combination of all three. The porosity is reduced in high-maturity samples by mechanical compaction and silica cementation. Total gas capacities range between 4.5 and 24.8 cm3/g, and gas-in-place (GIP) estimates are between 0.98 and 3.39 bcf/(section meter). The calculated hydrocarbon generation is less than 3.6 bcf/(section meter), with light liquid generation between 3.7 and 516.2 MMBO. Present-day depths and organic maturity have strong influences on the hydrocarbon capacity more so than TOC content. Deeper, higher maturity samples in the south have the largest total gas capacity and GIP estimates (0.98–3.39 bcf/[section meter]). Maturity is within the dry gas window in the southern one-third of the study area. Highest volumes of light liquid hydrocarbons are found within the less mature northern part of the study area.

Accommodation-based coal cycles and significant surface correlation of low-accommodation Lower Cretaceous coal seams, Lloydminster heavy oil field, Alberta, Canada: Implications for coal quality distribution

Sequence stratigraphy and coal cycles based on accommodation trends were investigated in the coal-bearing Lower Cretaceous Mannville Group in the Lloydminster heavy oil field, eastern Alberta. The study area is in a low accommodation setting on the cratonic margin of the Western Canada sedimentary basin. Geophysical log correlation of coal seams, shoreface facies, and the identification of incised valleys has produced a sequence-stratigraphic framework for petrographic data from 3 cored and 115 geophysical-logged wells. Maceral analysis, telovitrinite reflectance, and fluorescence measurements were taken from a total of 206 samples. Three terrestrial depositional environments were interpreted from the petrographic data: ombrotrophic mire coal, limnotelmatic mire coal, and carbonaceous shale horizons. Accommodation-based coal (wetting- and drying-upward) cycles represent trends in depositional environment shifts, and these cycles were used to investigate the development and preservation of the coal seams across the study area. The low-accommodation strata are characterized by a high-frequency occurrence of significant surfaces, coal seam splitting, paleosol, and incised-valley development. Three sequence boundary unconformities are identified in only 20 m (66 ft) of strata. Coal cycle correlations illustrate that each coal seam in this study area was not produced by a single peat-accumulation episode but as an amalgamation of a series of depositional events. Complex relations between the Cummings and Lloydminster coal seams are caused by the lateral fragmentation of strata resulting from the removal of sediment by subaerial erosion or periods of nondeposition. Syndepositional faulting of the underlying basement rock changed local accommodation space and increased the complexity of the coal cycle development. This study represents a low-accommodation example from a spectrum of stratigraphic studies that have been used to establish a terrestrial sequence-stratigraphic model. The frequency of changes in coal seam quality is an important control on methane distribution within coalbed methane reservoirs and resource calculations in coal mining. A depositional model based on the coal cycle correlations, as shown by this study, can provide coal quality prediction for coalbed methane exploration, reservoir completions, and coal mining.