Garrett Drayna

Buffer gas loaded magneto-optical traps for Yb, Tm, Er and Ho

Direct loading of lanthanide atoms into magneto-optical traps (MOTs) from a very slow cryogenic buffer gas beam source is achieved, without the need for laser slowing. The beam source has an average forward velocity of 60– and a velocity half-width of , which allows for direct MOT loading of Yb, Tm, Er and Ho. Residual helium background gas originating from the beam results in a maximum trap lifetime of about 80 ms (with Yb). The addition of a single-frequency slowing laser applied to the Yb in the buffer gas beam increases the number of trapped Yb atoms to with a loading rate of . Decay to metastable states is observed for all trapped species and decay rates are measured. Extension of this approach to the loading of molecules into a MOT is discussed.

Direct Time-Domain Observation of Conformational Relaxation in Gas-Phase Cold Collisions

Cooling molecules in the gas phase is important for precision spectroscopy, cold molecule physics, and physical chemistry. Measurements of conformational relaxation cross sections shed important light on potential energy surfaces and energy flow within a molecule. However, gas-phase conformational cooling has not been previously observed directly. In this work, we directly observe conformational dynamics of 1,2-propanediol in cold (6 K) collisions with atomic helium using microwave spectroscopy and buffer-gas cooling. Precise knowledge and control of the collisional environment in the buffer-gas allows us to measure the absolute collision cross-section for conformational relaxation. Several conformers of 1,2-propanediol are investigated and found to have relaxation cross-sections with He ranging from σ=4.7(3.0)×10(-18) cm(2) to σ>5×10(-16) cm(2). Our method is applicable to a broad class of molecules and could be used to provide information about the potential energy surfaces of previously uninvestigated molecules.