Geert Heideman

Transcoding of MPEG Bitstreams

This paper discusses the problem of transcoding as it may occur in, for instance, the following situation. Suppose a satellite transmits an MPEG-compressed video signal at say 9 Mbit/s. This signal must be relayed at a cable head end. However, since the cable capacity is only limited, the cable head end will want to relay this incoming signal at a lower bit-rate of, say, 5 Mbit/s. The problem is how to convert a compressed video signal of a given bit-rate into a compressed video signal of a lower bit-rate. The specific transcoding problem discussed in this paper is referred to as bit-rate conversion. Basically, a transcoder used for such a purpose will consist of a cascaded decoder and encoder. It is shown in the paper that the complexity of this combination can be significantly reduced. The paper also investigates the loss of picture quality that may be expected when a transcoder is in the transmission chain. The loss of quality as compared to that resulting in the case of transmission without a transcoder is studied by means of computations using simplified models of the transmission chains and by means of using computer simulations of the complete transmission chain. It will be shown that the presence of two quantizers, i.e. cascaded quantization, in the transmission chain is the main cause of extra losses, and it will be shown that the losses in terms of SNR will be some 0.5 ? 1.0 dB greater than in the case of a transmission chain without a transcoder.

Activators in Accelerated Sulfur Vulcanization

Abstract This review provides relevant background information about the vulcanization process, as well as the chemistry of thiuram- and sulfenamide-accelerated sulfur vulcanization with emphasis on the role of activators, to lay a base for further research. It commences with an introduction of sulfur vulcanization and a summary of the reaction mechanisms as described in literature, followed by the role of activators, particularly ZnO. The various possibilities to reduce ZnO levels in rubber compounding, that have been proposed in literature, are reviewed. A totally different approach to reduce ZnO is described in the paragraphs about the various possible roles of multifunctional additives (MFA) in rubber vulcanization. Another paragraph is dedicated to the role of amines in rubber vulcanization, in order to provide some insight in the underlying chemical mechanisms of MFA systems. Furthermore, an overview of Model Compound Vulcanization (MCV) with respect to different models and activator/accelerator syst...

Effect of zinc complexes as activator for sulfur vulcanization in various rubbers

Abstract Because of environmental concerns, the zinc content in rubber compounds has come under scrutiny; therefore it is necessary to explore possibilities to reduce this zinc content. In this article the application of several zinc complexes as activator for sulfur vulcanization are discussed, in order to find alternatives for the conventionally used ZnO and fatty acid activator system. The effects of different zinc complexes on the cure and physical properties of two widely different rubbers, viz. EPDM and s-SBR, are studied. It can be concluded that zinc-m-glycerolate is a good substitute for ZnO as activator for sulfur vulcanization, in EPDM as well as in s-SBR rubber, without detrimental effects on the cure and physical properties. Furthermore, the results indicate that, dependent on the intended applications, zinc-2-ethylhexanoate represents a substitute for the commonly used ZnO. Zinc stearate is considerably less active as activator in sulfur vulcanization.

Zinc loaded clay as activator in sulfur vulcanization: A new route for zinc oxide reduction in rubber compounds

Abstract Concern about the release of eco-toxic zinc species from rubbers into the environment leads to an increasing interest in potential substitutes. Although alternative metal oxides and zinc compounds as activators for sulfur vulcanization have been studied thoroughly, at present no viable alternative has been found to eliminate ZnO completely from rubber compounds, without significantly jeopardizing processing as well as performance characteristics. In this paper, the application of a new activator for sulfur vulcanization will be discussed. This activator is developed based on the assumption that an increase in the availability of Zn2+-ions could lead to a considerable reduction of ZnO in rubber compounds. Montmorillonite clay was used as carrier material and loaded with Zn2+-ions via an ion-exchange process. Application in a wide range of natural and synthetic rubbers has been explored. Results clearly demonstrate that this Zn-Clay can substitute conventional ZnO, retaining the curing and physical...

Multifunctional Additives as Zinc-Free Curatives for Sulfur Vulcanization

Abstract Concern about the release of eco-toxic zinc species from rubbers into the environment leads to an increasing interest in potential substitutes. This investigation reports on the applicatio...

Coherence Multiplex System Topologies

Coherence multiplexing is a potentially inexpensive form of optical code-division multiple access, which is particularly suitable for short-range applications with moderate bandwidth requirements, such as access networks, LANs, or interconnects. Various topologies are known for constructing an optical transmission system in which several channels are coherence-multiplexed in one optical fiber. In this paper, the parallel array, the intrinsic reference ladder (IRL), and the discontinuous series system topologies will be further considered and compared with respect to code orthogonality requirements, theoretical performance, and some practical implementation aspects. A modification to the IRL system is proposed, resulting in a significant improvement in the theoretical performance.