Gema Álvarez-Pinazo

Accuracy in Rietveld quantitative phase analysis: a comparative study of strictly monochromatic Mo and Cu radiations

This work focuses on the comparison of Mo Kα1 and Cu Kα1 radiations for the Rietveld quantitative phase analysis of challenging crystalline mixtures including amorphous content determination. The quantifications have been carried out by using calibration curves with increasing amounts of a given phase. Mo Kα1 patterns were found to yield slightly more accurate analyses than those derived from Cu Kα1 radiation.

Rietveld quantitative phase analysis with molybdenum radiation

Building materials are very complex samples of worldwide importance; hence quantitative knowledge of their mineralogical composition is necessary to predict performances. Rietveld quantitative phase analysis (RQPA) allows a direct measurement of the crystalline phase contents of cements. We highlight in this paper the use of laboratory X-ray powder diffraction (LXRPD) employing high-energy radiation, molybdenum (Mo), for attaining the RQPA of cements. Firstly, we evaluate the accuracy of RQPA employing a commercial calcium sulfoaluminate clinker with gypsum. In addition to Mo Kα 1 and Mo Kα 1,2 radiations, Cu and synchrotron patterns are also analyzed for the sake of comparison. Secondly, the assessment of the accuracy of RQPA results obtained using different radiations (synchrotron, Mo, and Cu) and geometries (reflection and transmission) is performed by analyzing two well-known commercial samples. As expected, for LXRPD data, accuracy in the RQPA results improves as the irradiated volume increases. Finally, three very complex aged hydrated cements have been analyzed using Mo K α 1 -LXRPD and Synchrotron-XRPD. The main overall outcome of this work is the benefit for RQPA of using strictly monochromatic Mo Kα 1 radiation. Best laboratory results arise from Mo Kα 1 data as the effective tested volume is much increased but peak overlapping is not swelled.