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Featured researches published by Geneva Laurita.


Journal of the American Chemical Society | 2016

Dynamic Stereochemical Activity of the Sn2+ Lone Pair in Perovskite CsSnBr3

Douglas H. Fabini; Geneva Laurita; Jonathon S. Bechtel; Constantinos C. Stoumpos; Hayden A. Evans; Athanassios G. Kontos; Y. S. Raptis; Polycarpos Falaras; Anton Van der Ven; Mercouri G. Kanatzidis; Ram Seshadri

Stable s(2) lone pair electrons on heavy main-group elements in their lower oxidation states drive a range of important phenomena, such as the emergence of polar ground states in some ferroic materials. Here we study the perovskite halide CsSnBr3 as an embodiment of the broader materials class. We show that lone pair stereochemical activity due to the Sn(2+) s(2) lone pair causes a crystallographically hidden, locally distorted state to appear upon warming, a phenomenon previously referred to as emphanisis. The synchrotron X-ray pair distribution function acquired between 300 and 420 K reveals emerging asymmetry in the nearest-neighbor Sn-Br correlations, consistent with dynamic Sn(2+) off-centering, despite there being no evidence of any deviation from the average cubic structure. Computation based on density functional theory supports the finding of a lattice instability associated with dynamic off-centering of Sn(2+) in its coordination environment. Photoluminescence measurements reveal an unusual blue-shift with increasing temperature, closely linked to the structural evolution. At low temperatures, the structures reflect the influence of octahedral rotation. A continuous transition from an orthorhombic structure (Pnma, no. 62) to a tetragonal structure (P4/mbm, no. 127) is found around 250 K, with a final, first-order transformation at 286 K to the cubic structure (Pm3̅m, no. 221).


Angewandte Chemie | 2016

Reentrant Structural and Optical Properties and Large Positive Thermal Expansion in Perovskite Formamidinium Lead Iodide

Douglas H. Fabini; Constantinos C. Stoumpos; Geneva Laurita; Andreas Kaltzoglou; Athanassios G. Kontos; Polycarpos Falaras; Mercouri G. Kanatzidis; Ram Seshadri

The structure of the hybrid perovskite HC(NH2 )2 PbI3 (formamidinium lead iodide) reflects competing interactions associated with molecular motion, hydrogen bonding tendencies, thermally activated soft octahedral rotations, and the propensity for the Pb2+ lone pair to express its stereochemistry. High-resolution synchrotron X-ray powder diffraction reveals a continuous transition from the cubic α-phase (Pm3‾ m, #221) to a tetragonal β-phase (P4/mbm, #127) at around 285 K, followed by a first-order transition to a tetragonal γ-phase (retaining P4/mbm, #127) at 140 K. An unusual reentrant pseudosymmetry in the β-to-γ phase transition is seen that is also reflected in the photoluminescence. Around room temperature, the coefficient of volumetric thermal expansion is among the largest for any extended crystalline solid.


Journal of the American Chemical Society | 2017

Universal Dynamics of Molecular Reorientation in Hybrid Lead Iodide Perovskites

Douglas H. Fabini; Ting Ann Siaw; Constantinos C. Stoumpos; Geneva Laurita; Daniel Olds; Katharine Page; Jerry G. Hu; Mercouri G. Kanatzidis; Songi Han; Ram Seshadri

The role of organic molecular cations in the high-performance perovskite photovoltaic absorbers, methylammonium lead iodide (MAPbI3) and formamidinium lead iodide (FAPbI3), has been an enigmatic subject of great interest. Beyond aiding in the ease of processing of thin films for photovoltaic devices, there have been suggestions that many of the remarkable properties of the halide perovskites can be attributed to the dipolar nature and the dynamic behavior of these cations. Here, we establish the dynamics of the molecular cations in FAPbI3 between 4 K and 340 K and the nature of their interaction with the surrounding inorganic cage using a combination of solid state nuclear magnetic resonance and dielectric spectroscopies, neutron scattering, calorimetry, and ab initio calculations. Detailed comparisons with the reported temperature dependence of the dynamics of MAPbI3 are then carried out which reveal the molecular ions in the two different compounds to exhibit very similar rotation rates (≈8 ps) at room temperature, despite differences in other temperature regimes. For FA, rotation about the N···N axis, which reorients the molecular dipole, is the dominant motion in all phases, with an activation barrier of ≈21 meV in the ambient phase, compared to ≈110 meV for the analogous dipole reorientation of MA. Geometrical frustration of the molecule-cage interaction in FAPbI3 produces a disordered γ-phase and subsequent glassy freezing at yet lower temperatures. Hydrogen bonds suggested by atom-atom distances from neutron total scattering experiments imply a substantial role for the molecules in directing structure and dictating properties. The temperature dependence of reorientation of the dipolar molecular cations systematically described here can clarify various hypotheses including those of large-polaron charge transport and fugitive electron spin polarization that have been invoked in the context of these unusual materials.


Journal of Applied Physics | 2016

Enhancement of thermoelectric properties in the Nb–Co–Sn half-Heusler/Heusler system through spontaneous inclusion of a coherent second phase

Malinda L. C. Buffon; Geneva Laurita; Nisha Verma; Leo Lamontagne; Leila Ghadbeigi; Demetrious L. Lloyd; Taylor D. Sparks; Tresa M. Pollock; Ram Seshadri

Half-Heusler XYZ compounds with an 18 valence electron count are promising thermoelectric materials, being thermally and chemically stable, deriving from relatively earth-abundant components, and possessing appropriate electrical transport properties. The typical drawback with this family of compounds is their high thermal conductivity. A strategy for reducing thermal conductivity is through the inclusion of secondary phases designed to minimize negative impact on other properties. Here, we achieve this through the addition of excess Co to half-Heusler NbCoSn, which introduces precipitates of a semi-coherent NbCo2Sn Heusler phase. A series of NbCo1+xSn materials are characterized here using X-ray and neutron diffraction studies and electron microscopy. Electrical and thermal transport measurements and electronic structure calculations are used to understand property evolution. We find that annealing has an important role to play in determining antisite ordering and properties. Antisite disorder in the as-...


Inorganic Chemistry | 2013

Structural investigation of the substituted pyrochlore AgSbO3 through total scattering techniques.

Geneva Laurita; Katharine Page; Arthur W. Sleight; M. A. Subramanian

Polycrystalline samples of the pyrochlore series Ag(1-x)M(n)(x)SbO(3+x[(n-1)/2]) (M = Na, K, and Tl) have been structurally analyzed through total scattering techniques. The upper limits of x obtained were 0.05 for Na, 0.16 for K, and 0.17 for Tl. The Ag(+) cation occupies a site with inversion symmetry on a 3-fold axis. When the smaller Na(+) cation substitutes for Ag(+), it is displaced by about 0.6 Å perpendicular to the 3-fold axis to achieve some shorter Na-O bond distances. When the larger Tl(+) cation substitutes for Ag(+), it is displaced by about 1.14 Å along the 3-fold axis and achieves an environment typical of a lone pair cation. Some of the Tl(3+) from the precursor remains unreduced, leading to a formula of Ag(0.772(1))Tl(+)(0.13(2))Tl(3+)(0.036(1))SbO(3.036(1)). The position of the K(+) dopant was effectively modeled assuming that K(+) occupied the same site as Ag(+). The expansion of the lattice caused by substitution of the larger K(+) and Tl(+) cations results in longer Ag-O bond lengths, which would reduce the overlap of the Ag 4d and O 2p orbitals that compose the valence band maximum. Substitution of the smaller Na(+) results in a decrease in the Ag-O bond distance, thus increasing the overlap of the Ag 4d and O 2p orbitals. This will have a direct influence on the band composition and observed properties of this material of interest.


Inorganic Chemistry | 2018

Crystal Structure Evolution and Notable Thermal Expansion in Hybrid Perovskites Formamidinium Tin Iodide and Formamidinium Lead Bromide

Emily C. Schueller; Geneva Laurita; Douglas H. Fabini; Constantinos C. Stoumpos; Mercouri G. Kanatzidis; Ram Seshadri

The temperature-dependent structure evolution of the hybrid halide perovskite compounds, formamidinium tin iodide (FASnI3, FA+ = CH[NH2]2+) and formamidinium lead bromide (FAPbBr3), has been monitored using high-resolution synchrotron X-ray powder diffraction between 300 and 100 K. The data are consistent with a transition from cubic Pm3m (No. 221) to tetragonal P4/mbm (No. 127) for both materials upon cooling; this occurs for FAPbBr3 between 275 and 250 K, and for FASnI3 between 250 and 225 K. Upon further cooling, between 150 and 125 K, both materials undergo a transition to an orthorhombic Pnma (No. 62) structure. The transitions are confirmed by calorimetry and dielectric measurements. In the tetragonal regime, the coefficients of volumetric thermal expansion of FASnI3 and FAPbBr3 are among the highest recorded for any extended inorganic crystalline solid, reaching 219 ppm K-1 for FASnI3 at 225 K. Atomic displacement parameters of all atoms for both materials suggest dynamic motion is occurring in the inorganic sublattice due to the flexibility of the inorganic network and dynamic lone pair stereochemical activity on the B-site. Unusual pseudocubic behavior is displayed in the tetragonal phase of the FAPbBr3, similar to that previously observed in FAPbI3.


Journal of Materials Chemistry C | 2017

Understanding the links between composition, polyhedral distortion, and luminescence properties in green-emitting β-Si6−zAlzOzN8−z:Eu2+ phosphors

Clayton Cozzan; Geneva Laurita; Michael W. Gaultois; Marcus Cohen; Alexander Mikhailovsky; Mahalingam Balasubramanian; Ram Seshadri

Inorganic phosphor materials play a crucial role in the creation of white light from blue and near-UV solid-state light-emitting diodes. Understanding the intricacies of the phosphor structure is key for setting the stage for improved, more efficient functionality. Average structure and coordination environment analysis of the robust and efficient green-emitting phosphor, β-SiAlON:Eu2+ (β-Si6−zAlzOzN8−zEu0.009), is combined here with a range of property measurements to elucidate the role of Al content (z) in luminescence properties, including the red shift of emission and the thermal quenching of luminescence as a function of increasing Al content z. Average structure techniques reveal changes in polyhedral distortion with increasing z for the 9-coordinate Eu site in β-SiAlON:Eu2+. X-ray absorption near edge structure (XANES) is used to confirm that the majority of the activator Eu is in the Eu2+ state, exhibiting the symmetry-allowed and efficient 4f75d0 → 4f65d1 transitions. Room temperature and temperature-dependent luminescence indicate a curious increase in thermal stability with increasing z over a small range due to an increasing barrier for thermal ionization, which is correlated to an increase in the quantum yield of the phosphor.


Inorganic Chemistry | 2017

Structural Evolution and Atom Clustering in β-SiAlON: β-Si6–zAlzOzN8–z

Clayton Cozzan; Kent Griffith; Geneva Laurita; Jerry G. Hu; Clare P. Grey; Ram Seshadri

SiAlON ceramics, solid solutions based on the Si3N4 structure, are important, lightweight structural materials with intrinsically high strength, high hardness, and high thermal and chemical stability. Described by the chemical formula β-Si6-zAlzOzN8-z, from a compositional viewpoint, these materials can be regarded as solid solutions between Si3N4 and Al3O3N. A key aspect of the structural evolution with increasing Al and O (z in the formula) is to understand how these elements are distributed on the β-Si3N4 framework. The average and local structural evolution of highly phase-pure samples of β-Si6-zAlzOzN8-z with z = 0.050, 0.075, and 0.125 are studied here, using a combination of X-ray diffraction, NMR studies, and density functional theory calculations. Synchrotron X-ray diffraction establishes sample purity and indicates subtle changes in the average structure with increasing Al content in these compounds. Solid-state magic-angle-spinning 27Al NMR experiments, coupled with detailed ab initio calculations of NMR spectra of Al in different AlOqN4-q tetrahedra (0 ≤ q ≤ 4), reveal a tendency of Al and O to cluster in these materials. Independently, the calculations suggest an energetic preference for Al-O bond formation, instead of a random distribution, in the β-SiAlON system.


Journal of Physics: Condensed Matter | 2017

Thermoelectric performance and the role of anti-site disorder in the 24-electron Heusler TiFe2Sn

Malinda L. C. Buffon; Geneva Laurita; Leo Lamontagne; Emily E. Levin; Shahryar Mooraj; Demetrious L. Lloyd; Natalie White; Tresa M. Pollock; Ram Seshadri

Heusler compounds XY 2 Z with 24 valence electrons per formula unit are potential thermoelectric materials, given their thermal and chemical stability and their relatively earth-abundant constituent elements. We present results on the 24-electron compound TiFe2Sn here. First principles calculations on this compound suggest semiconducting behavior. A relatively flat conduction band that could be associated with a high Seebeck coefficient upon electron doping is found. A series of compounds have been prepared and characterized using a combination of synchrotron x-ray and neutron diffraction studies to understand the effects of site order/disorder phenomena and n-type doping. Samples fabricated by a three step processing approach were subjected to high temperature Seebeck and electrical resistivity measurements. Ti:Fe anti-site disorder is present in the stoichiometric compound and these defects are reduced when starting Ti-rich compositions are employed. Additionally, we investigate control of the Seebeck coefficient through the introduction of carriers through the substitution of Sb on the Sn site in these intrinsically p-type materials.


Inorganic Chemistry | 2017

The Role of Structural and Compositional Heterogeneities in the Insulator-to-Metal Transition in Hole-Doped APd3O4 (A = Ca, Sr)

Leo Lamontagne; Geneva Laurita; Michael Knight; Huma Yusuf; Jerry Hu; Ram Seshadri; Katharine Page

The cubic semiconducting compounds APd3O4 (A = Ca, Sr) can be hole-doped by Na substitution on the A site and driven toward more conducting states. This process has been followed here by a number of experimental techniques to understand the evolution of electronic properties. While an insulator-to-metal transition is observed in Ca1-xNaxPd3O4 for x ≥ 0.15, bulk metallic behavior is not observed for Sr1-xNaxPd3O4 up to x = 0.20. Given the very similar crystal and (calculated) electronic structures of the two materials, the distinct behavior is a matter of interest. We present evidence of local disorder in the A = Sr materials through the analysis of the neutron pair distribution function, which is potentially at the heart of the distinct behavior. Solid-state 23Na nuclear magnetic resonance studies additionally suggest a percolative insulator-to-metal transition mechanism, wherein presumably small regions with a signal resembling metallic NaPd3O4 form almost immediately upon Na substitution, and this signal grows monotonically with substitution. Some signatures of increased local disorder and a propensity for Na clustering are seen in the A = Sr compounds.

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Ram Seshadri

University of California

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Clayton Cozzan

University of California

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Jerry G. Hu

University of California

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Katharine Page

Oak Ridge National Laboratory

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