Georgiy M. Tsoi

Anomalous compressibility effects and superconductivity of EuFe2As2 under high pressures.

The crystal structure and electrical resistance of structurally layered EuFe(2)As(2) have been studied up to 70 GPa and down to a temperature of 10 K, using a synchrotron x-ray source and designer diamond anvils. The room temperature compression of the tetragonal phase of EuFe(2)As(2) (I4/mmm) results in an increase in the a-axis length and a rapid decrease in the c-axis length with increasing pressure. This anomalous compression reaches a maximum at 8 GPa and the tetragonal lattice behaves normally above 10 GPa, with a nearly constant c/a axial ratio. The rapid rise in the superconducting transition temperature (T(c)) to 41 K with increasing pressure is correlated with this anomalous compression, and a decrease in T(c) is observed above 10 GPa. We present P-V data or the equation of state for EuFe(2)As(2) both in the ambient tetragonal phase and in the high pressure collapsed tetragonal phase up to 70 GPa.

Phase transition and superconductivity of SrFe2As2 under high pressure

High pressure x-ray diffraction and electrical resistance measurements have been carried out on SrFe(2)As(2) to a pressure of 23 GPa and temperature of 10 K using a synchrotron source and designer diamond anvils. At ambient temperature, a phase transition from the tetragonal phase to a collapsed tetragonal (CT) phase is observed at 10 GPa under non-hydrostatic conditions. The experimental relation that T-CT transition pressure for 122 Fe-based superconductors is dependent on ambient pressure volume is affirmed. The superconducting transition temperature is observed at 32 K at 1.3 GPa and decreases rapidly with a further increase of pressure in the region where the T-CT transition occurs. Our results suggest that T(C) falls below 10 K in the pressure range of 10-18 GPa where the CT phase is expected to be stable.

Structural phase transitions in yttrium under ultrahigh pressures

X-ray diffraction studies were carried out on the rare earth metal yttrium up to 177 GPa in a diamond anvil cell at room temperature. Yttrium was compressed to 37% of its initial volume at the highest pressure. The rare earth crystal structure sequence hcp → Sm type → dhcp → mixed(dhcp + fcc) → distorted fcc (dfcc) is observed in yttrium below 50 GPa. The dfcc (hR24) phase has been observed to persist in the pressure range of 50-95 GPa. A structural transition from dfcc to a low symmetry phase has been observed in yttrium at 99 ± 4 GPa with a volume change of - 2.6%. This low symmetry phase has been identified as a monoclinic C2/m phase, which has also been observed in other rare earth elements under high pressures. The appearance of this low symmetry monoclinic phase in yttrium shows that its electronic structure under extreme conditions resembles that of heavy rare earth metals, with a significant increase in d-band character of the valence electrons and possibly some f-electron states near the Fermi level.

Simultaneous measurement of pressure evolution of crystal structure and superconductivity in FeSe0.92 using designer diamonds

Simultaneous high-pressure X-ray diffraction and electrical resistance measurements have been carried out on a PbO-type ?-FeSe0.92 compound to a pressure of 44?GPa and temperatures down to 4?K using designer diamond anvils at synchrotron source. At ambient temperature, a structural phase transition from a tetragonal (P4/nmm) phase to an orthorhombic (Pbnm) phase is observed at 11?GPa and the Pbnm phase persists up to 74?GPa. The superconducting transition temperature (TC) increases rapidly with pressure reaching a maximum of ?28?K at ?6?GPa and decreases at higher pressures, disappearing completely at 14.6?GPa. Simultaneous pressure-dependent X-ray diffraction and resistance measurements at low temperatures show superconductivity only in a low-pressure orthorhombic (Cmma) phase of the ?-FeSe0.92. Upon increasing pressure at 10?K near TC, crystalline phases change from a mixture of orthorhombic (Cmma) and hexagonal (P63/mmc) phases to a high-pressure orthorhombic (Pbnm) phase near 6.4?GPa where TC is maximum.

Structural phase transitions in EuFe2As2 superconductor at low temperatures and high pressures

The crystal structure of EuFe(2)As(2) has been studied up to a pressure of 35 GPa and down to a temperature of 8 K using temperature dependent x-ray diffraction in a diamond anvil cell at a synchrotron source. At 4.3 GPa, we have detected a structural phase transition from a high temperature tetragonal phase with I4/mmm space group to a low temperature orthorhombic phase with Fmmm space group around 120 K. With the application of pressure at a low temperature of 10 K, the orthorhombic phase is suppressed and a phase change to a collapsed tetragonal phase with I4/mmm space group is observed at 11 GPa. This collapsed tetragonal phase is similar to the one observed at ambient temperature and pressure above 8.5 GPa. We have shown that the collapsed tetragonal phase of EuFe(2)As(2) has the same pressure-volume (P-V) equation of state at ambient temperature and at 10 K, implying that the high pressure phase of EuFe(2)As(2) has a negligible thermal expansion coefficient.

Formation of collapsed tetragonal phase in EuCo2As2 under high pressure

The structural properties of EuCo₂As₂ have been studied up to 35 GPa, through the use of x-ray diffraction in a diamond anvil cell at a synchrotron source. At ambient conditions, EuCo₂As₂ ) (I4/mmm) has a tetragonal lattice structure with a bulk modulus of 48 ± 4 GPa. With the application of pressure, the a axis exhibits negative compressibility with a concurrent sharp decrease in c-axis length. The anomalous compressibility of the a axis continues until 4.7 GPa, at which point the structure undergoes a second-order phase transition to a collapsed tetragonal (CT) state with a bulk modulus of 111 ± 2 GPa. We found a strong correlation between the ambient pressure volume of 122 parents of superconductors and the corresponding tetragonal to collapsed tetragonal phase transition pressures.

Synthesis and Characterization of Sr-Doped Lanthanum Manganite Nanoparticles

Polycrystalline, nanometer-sized powders of La1-xSrxMnO3with x=0.25 and 0.45 were prepared by a citrate gel technique and annealed at 600, 700, and 800degC in air for a period of 3 or 10 h. This synthesis technique resulted in the characteristics of the nanoparticles being highly reproducible from different, but identically prepared starting solutions. The average particle sizes as determined from the width of the (024) X-ray diffraction peak were found to be in the 11-15 nm range for the x=0.45 Sr concentration materials and in the 12-17 nm range for x=0.25 materials. For both concentrations, the average particle size increases roughly linear with annealing temperature while the effect of increasing annealing time (3 h versus 10 h) appeared to increase with the particle size, but not in a uniform way. Likewise, the saturated magnetizations at 300 K (7-26 emu/g) and transition temperatures (275-350 K) were found to increase linearly with the average particle diameter for each Sr concentration of nanoparticles

Investigation of magnetic interactions in large arrays of magnetic nanowires

The magnetic interactions in large arrays of ordered magnetic nanowires with 12–48nm diameter and 55–95nm spacing were investigated using modified Henkel plots. The measurements for nanowire arrays ac demagnetized with the field applied parallel to the nanowire axis (the easy magnetization axis) indicate that the dominant interaction during the switching process is the magnetostatic coupling between the nanowires. Nevertheless, while the strength of the magnetostatic interactions increases with the magnetic moment associated with the nanowires, the increase is not linear with respect to the volume of the nanowires. Moreover, the dependence of the remanence curves on the field history suggests that even for magnetic nanowire systems with high geometric anisotropy, the magnetic pole structure of the nanowires can be complex. This conclusion is also supported by the field dependence of the initial magnetization curves.

High pressure studies using two-stage diamond micro-anvils grown by chemical vapor deposition

Ultra-high static pressures have been achieved in the laboratory using a two-stage micro-ball nanodiamond anvils as well as a two-stage micro-paired diamond anvils machined using a focused ion-beam system. The two-stage diamond anvils’ designs implemented thus far suffer from a limitation of one diamond anvil sliding past another anvil at extreme conditions. We describe a new method of fabricating two-stage diamond micro-anvils using a tungsten mask on a standard diamond anvil followed by microwave plasma chemical vapor deposition (CVD) homoepitaxial diamond growth. A prototype two-stage diamond anvil with 300 µm culet and with a CVD diamond second stage of 50 µm in diameter was fabricated. We have carried out preliminary high pressure X-ray diffraction studies on a sample of rare-earth metal lutetium sample with a copper pressure standard to 86 GPa. The micro-anvil grown by CVD remained intact during indentation of gasket as well as on decompression from the highest pressure of 86 GPa.

High-pressure phase transitions in rare earth metal thulium to 195?GPa

We have performed image plate x-ray diffraction studies on a heavy rare earth metal, thulium (Tm), in a diamond anvil cell to a pressure of 195 GPa and volume compression V/V₀ = 0.38 at room temperature. The rare earth crystal structure sequence, hcp →Sm-type→ dhcp →fcc → distorted fcc, is observed in Tm below 70 GPa with the exception of a pure fcc phase. The focus of our study is on the ultrahigh-pressure phase transition and Rietveld refinement of crystal structures in the pressure range between 70 and 195 GPa. The hexagonal hR-24 phase is seen to describe the distorted fcc phase between 70 and 124 GPa. Above 124 ± 4 GPa, a structural transformation from hR 24 phase to a monoclinic C 2/m phase is observed with a volume change of -1.5%. The equation of state data shows rapid stiffening above the phase transition at 124 GPa and is indicative of participation of f-electrons in bonding. We compare the behavior of Tm to other heavy rare-earths and heavy actinide metals under extreme conditions of pressure.