Ger Shortle

Identifying contrasting influences and surface water signals for specific groundwater phosphorus vulnerability

Two groundwater dominated catchments with contrasting land use (Grassland and Arable) and soil chemistry were investigated for influences on P transfer below the rooting zone, via the aquifer and into the rivers. The objective was to improve the understanding of hydrochemical process for best management practise and determine the importance of P transfer via groundwater pathways. Despite the catchments having similar inorganic P reserves, the iron-rich soils of the Grassland catchment favoured P mobilisation into soluble form and transfer to groundwater. Sites in that catchment had elevated dissolved reactive P concentrations in groundwater (>0.035 mg l(-1)) and the river had flow-weighted mean TRP concentrations almost three times that of the aluminium-rich Arable catchment (0.067 mg l(-1) compared to 0.023 mg l(-1)). While the average annual TRP flux was low in both catchments (although three times higher in the Grassland catchment; 0.385 kg ha(-1) compared to 0.128 kg ha(-1)), 50% and 59% of TRP was lost via groundwater, respectively, during winter periods that were closed for fertiliser application. For policy reviews, slow-flow pathways and associated time-lags between fertiliser application, mobilisation of soil P reserves and delivery to the river should be carefully considered when reviewing mitigating strategies and efficacy of mitigating measures in groundwater fed catchments. For example, while the Grassland catchment indicated a soil-P chemistry susceptibility, the Arable catchment indicated a transient point source control; both resulted in sustained or transient periods of elevated low river-flow P concentrations, respectively.

Quantification of phosphorus transport from a karstic agricultural watershed to emerging spring water

The degree to which waters in a given watershed will be affected by nutrient export can be defined as that watersheds nutrient vulnerability. This study applied concepts of specific phosphorus (P) vulnerability to develop intrinsic groundwater vulnerability risk assessments in a 32 km(2) karst watershed (spring zone of contribution) in a relatively intensive agricultural landscape. To explain why emergent spring water was below an ecological impairment threshold, concepts of P attenuation potential were investigated along the nutrient transfer continuum based on soil P buffering, depth to bedrock, and retention within the aquifer. Surface karst features, such as enclosed depressions, were reclassified based on P attenuation potential in soil at the base. New techniques of high temporal resolution monitoring of P loads in the emergent spring made it possible to estimate P transfer pathways and retention within the aquifer and indicated small-medium fissure flows to be the dominant pathway, delivering 52-90% of P loads during storm events. Annual total P delivery to the main emerging spring was 92.7 and 138.4 kg total P (and 52.4 and 91.3 kg as total reactive P) for two monitored years, respectively. A revised groundwater vulnerability assessment was used to produce a specific P vulnerability map that used the soil and hydrogeological P buffering potential of the watershed as key assumptions in moderating P export to the emergent spring. Using this map and soil P data, the definition of critical source areas in karst landscapes was demonstrated.

Delivery and impact bypass in a karst aquifer with high phosphorus source and pathway potential

Conduit and other karstic flows to aquifers, connecting agricultural soils and farming activities, are considered to be the main hydrological mechanisms that transfer phosphorus from the land surface to the groundwater body of a karstified aquifer. In this study, soil source and pathway components of the phosphorus (P) transfer continuum were defined at a high spatial resolution; field-by-field soil P status and mapping of all surface karst features was undertaken in a > 30 km(2) spring contributing zone. Additionally, P delivery and water discharge was monitored in the emergent spring at a sub-hourly basis for over 12 months. Despite moderate to intensive agriculture, varying soil P status with a high proportion of elevated soil P concentrations and a high karstic connectivity potential, background P concentrations in the emergent groundwater were low and indicative of being insufficient to increase the surface water P status of receiving surface waters. However, episodic P transfers via the conduit system increased the P concentrations in the spring during storm events (but not >0.035 mg total reactive P L(-1)) and this process is similar to other catchments where the predominant transfer is via episodic, surface flow pathways; but with high buffering potential over karst due to delayed and attenuated runoff. These data suggest that the current definitions of risk and vulnerability for P delivery to receiving surface waters should be re-evaluated as high source risk need not necessarily result in a water quality impact. Also, inclusion of conduit flows from sparse water quality data in these systems may over-emphasise their influence on the overall status of the groundwater body.

Influence of stormflow and baseflow phosphorus pressures on stream ecology in agricultural catchments

Stormflow and baseflow phosphorus (P) concentrations and loads in rivers may exert different ecological pressures during different seasons. These pressures and subsequent impacts are important to disentangle in order to target and monitor the effectiveness of mitigation measures. This study investigated the influence of stormflow and baseflow P pressures on stream ecology in six contrasting agricultural catchments. A five-year high resolution dataset was used consisting of stream discharge, P chemistry, macroinvertebrate and diatom ecology, supported with microbial source tracking and turbidity data. Total reactive P (TRP) loads delivered during baseflows were low (1-7% of annual loads), but TRP concentrations frequently exceeded the environmental quality standard (EQS) of 0.035mgL-1 during these flows (32-100% of the time in five catchments). A pilot microbial source tracking exercise in one catchment indicated that both human and ruminant faecal effluents were contributing to these baseflow P pressures but were diluted at higher flows. Seasonally, TRP concentrations tended to be highest during summer due to these baseflow P pressures and corresponded well with declines in diatom quality during this time (R2=0.79). Diatoms tended to recover by late spring when storm P pressures were most prevalent and there was a poor relationship between antecedent TRP concentrations and diatom quality in spring (R2=0.23). Seasonal variations were less apparent in the macroinvertebrate indices; however, there was a good relationship between antecedent TRP concentrations and macroinvertebrate quality during spring (R2=0.51) and summer (R2=0.52). Reducing summer point source discharges may be the quickest way to improve ecological river quality, particularly diatom quality in these and similar catchments. Aligning estimates of P sources with ecological impacts and identifying ecological signals which can be attributed to storm P pressures are important next steps for successful management of agricultural catchments at these scales.