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Dive into the research topics where Gerard A. Crispino is active.

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Featured researches published by Gerard A. Crispino.


Tetrahedron Letters | 1992

Asymmetric dihydroxylation of squalene

Gerard A. Crispino; K. Barry Sharpless

Abstract The asymmetric dihydroxylation of squalene was studied using the new ligand (DHQD) 2 -PHAL. Moderate positional selectivity for the 2,3-olefin was observed with high % ee.


Tetrahedron Letters | 1994

A comparison of ligands proposed for the asymmetric dihydroxylation

Gerard A. Crispino; Atsushi Makita; Zhi-Min Wang; K. Barry Sharpless

Abstract Comparative data for several ligands proposed recently for use in the osmium-catalyzed asymmetric dihydroxylation (AD) are presented.


Tetrahedron Letters | 1991

TRIPYRIDYLCYCLOPROPENE DERIVATIVES AND THEIR CONVERSION TO HEXAPYRIDYLBENZENE

Ronald Breslow; Gerard A. Crispino

Abstract 1,2,3-tris(4-pyridyl)cyclopropene carrying a 3-benzenesulfonyl group has been synthesized, and other cyclopropenes carrying pyridine and pyridinium rings. Some of these can be converted to hexa(4-pyridyl)benzene and its pyridinium analog.


Journal of Organic Chemistry | 1992

The osmium-catalyzed asymmetric dihydroxylation: a new ligand class and a process improvement

K. Barry Sharpless; Willi Amberg; Youssef L. Bennani; Gerard A. Crispino; Jens Hartung; Kyu-Sung Jeong; Hoi-Lun Kwong; Kouhei Morikawa; Zhi Min Wang


Journal of the American Chemical Society | 1992

Selective asymmetric dihydroxylation (AD) of dienes

Daqiang Xu; Gerard A. Crispino; K. Barry Sharpless


Journal of Organic Chemistry | 1993

Improved enantioselectivity in asymmetric dihydroxylations of terminal olefins using pyrimidine ligands

Gerard A. Crispino; Kyu-Sung Jeong; Hartmuth C. Kolb; Zhi Min Wang; Daqiang Xu; K. Barry Sharpless


Journal of Organic Chemistry | 1993

Syntheses and crystal structures of the cinchona alkaloid derivatives used as ligands in the osmium-catalyzed asymmetric dihydroxylation of olefins

Willi Amberg; Youssef L. Bennani; Raj K. Chadha; Gerard A. Crispino; William Davis; Jens Hartung; Kyu-Sung Jeong; Yasukazu Ogino; Tomoyuki Shibata; K. Barry Sharpless


Journal of the American Chemical Society | 1993

On "The origin of high enantioselectivity in the dihydroxylation of olefins using osmium tetraoxide and cinchona alkaloid catalysts"

Hartmuth C. Kolb; Pher G. Andersson; Youssef L. Bennani; Gerard A. Crispino; Kyu-Sung Jeong; Hoi-Lun Kwong; K. Barry Sharpless


Synthesis | 1993

Enantioselective synthesis of juvenile hormone III in three steps from methyl farnesoate

Gerard A. Crispino; K. Barry Sharpless


Journal of Organic Chemistry | 1989

Interannular diastereoselectivity in the hydroboration of functionalized 1-cyclohexylcyclohexenes

Thomas W. Bell; J. Ramon Vargas; Gerard A. Crispino

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Jens Hartung

Scripps Research Institute

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Willi Amberg

Scripps Research Institute

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Daqiang Xu

Scripps Research Institute

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Hartmuth C. Kolb

Scripps Research Institute

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Zhi Min Wang

Scripps Research Institute

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Hoi-Lun Kwong

City University of Hong Kong

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