Gerhard Barmen

A preliminary analysis of the groundwater recharge to the Karoo formations, mid-Zambezi basin, Zimbabwe

A multi-disciplinary study is being carried out on recharge to the Karoo sandstone aquifer in the western part of Zimbabwe, where recharge is controlled by the presence of a thick, confining basalt layer. The aquifer is geographically extensive, and has been identified throughout the southern part of the mid-Zambezi basin (Fig. 1). The potential for groundwater abstraction seems to be huge. The key issues in this part of the study are the extent of the recharge area and the recharge rates. The direct recharge area has previously been considered to be the area of outcrop of Karoo Forest sandstone, before it dips below an impervious basalt cover. However,, resistivity profiling shows that the basalt at the basin margin is weathered and fractured, and probably permeable, while the basalt deeper into the basin is fresh, solid and impermeable. Field and laboratory analysis of 22 groundwater samples support this extension of the recharge area to include a large area below the fractured basalt. CO2 gas pressures, calculated with the code PHREEQC using field measurements of pH and alkalinity, show that below the fractured basalt the groundwater is an open system in contact with atmospheric CO2. The C-14 and nitrate concentrations in this groundwater also indicate that recent infiltration takes place. The chloride contents of the rainfall and the groundwater in the recharge area have been measured to calculate direct recharge from rainfall. These data indicate that the direct recharge is in the range of 10-130 mm/yr, with an average value of 25 mm/yr. Preliminary results of recharge estimate using Cl-36 data suggests lower direct infiltration rates, but further studies are needed. The combination of hydro-chemical, isotopic and geophysical investigations show that the recharge area extends well beyond the sandstone outcrop area, northwards beneath the basalt some 20 km beyond the basalt margin. (Less)

Ecological, Groundwater, and Human Health Risk Assessment in a Mining Region of Nicaragua

The objective of the present study was to integrate the relative risk from mercury exposure to stream biota, groundwater, and humans in the Río Artiguas (Sucio) river basin, Nicaragua, where local gold mining occurs. A hazard quotient was used as a common exchange rate in probabilistic estimations of exposure and effects by means of Monte Carlo simulations. The endpoint for stream organisms was the lethal no-observed-effect concentration (NOECs), for groundwater the WHO guideline and the inhibitory Hg concentrations in bacteria (IC), and for humans the tolerable daily intake (TDI) and the benchmark dose level with an uncertainty factor of 10 (BMDLs(0.1)). Macroinvertebrates and fish in the contaminated river are faced with a higher risk to suffer from exposure to Hg than humans eating contaminated fish and bacteria living in the groundwater. The river sediment is the most hazardous source for the macroinvertebrates, and macroinvertebrates make up the highest risk for fish. The distribution of body concentrations of Hg in fish in the mining areas of the basin may exceed the distribution of endpoint values with close to 100% probability. Similarly, the Hg concentration in cord blood of humans feeding on fish from the river was predicted to exceed the BMDLs(0.1) with about 10% probability. Most of the risk to the groundwater quality is confined to the vicinity of the gold refining plants and along the river, with a probability of about 20% to exceed the guideline value.