Gerhard Thiel

Metallkomplexe mit biologisch wichtigen Liganden, XXVII [1] Palladium(II)-und Platin(II)-Komplexe mit Aminomonosacchariden / Metal Complexes with Biological Important Ligands, XXVII [1] Palladium(II) and Platinum(II) Complexes with Aminomonosaccharides

Abstract A series of dihalo palladium and platinum complexes X2PtL2 (X = Cl, I) with aminosugars L = 2-amino-2-deoxy-1,3,4,6-tetra-O-acetyl-β-D-glucopyranose, 1-O-methyl-2-amino-2-deoxy-4,6-O-benzyliden-a,β-D-glucopyranoside, 1-O-methyl-2-amino-2-deoxya-α,β-D-glucopyranoside, 6-amino-6-deoxy-1,2:3,4-di -O-isopropyliden-a-D-galactopyranose has been prepared and characterized by their IR, 1H and 13C NMR spectra. Monosaccharides and aminomonosaccharides have been attached to the complex via the carboxy group of α-amino acid PtII complexes to give esters or amides with the monosaccharides as the alcohol or amine components, respectively.