Giacinto Cornacchia

Pyrolysis process for the treatment of scrap tyres: Preliminary experimental results

The aim of this work is the evaluation, on a pilot scale, of scrap tyre pyrolysis process performance and the characteristics of the products under different process parameters, such as temperature, residence time, pressure, etc. In this frame, a series of tests were carried out at varying process temperatures between 550 and 680 degrees C, other parameters being equal. Pyrolysis plant process data are collected by an acquisition system; scrap tyre samples used for the treatment, solid and liquid by-products and produced syngas were analysed through both on-line monitoring (for gas) and laboratory analyses. Results show that process temperature, in the explored range, does not seem to seriously influence the volatilisation reaction yield, at least from a quantitative point of view, while it observably influences the distribution of the volatile fraction (liquid and gas) and by-products characteristics.

Steam gasification of waste tyre: Influence of process temperature on yield and product composition

An experimental survey of waste tyre gasification with steam as oxidizing agent has been conducted in a continuous bench scale reactor, with the aim of studying the influence of the process temperature on the yield and the composition of the products; the tests have been performed at three different temperatures, in the range of 850-1000°C, holding all the other operational parameters (pressure, carrier gas flow, solid residence time). The experimental results show that the process seems promising in view of obtaining a good quality syngas, indicating that a higher temperature results in a higher syngas production (86 wt%) and a lower char yield, due to an enhancement of the solid-gas phase reactions with the temperature. Higher temperatures clearly result in higher hydrogen concentrations: the hydrogen content rapidly increases, attaining values higher than 65% v/v, while methane and ethylene gradually decrease over the range of the temperatures; carbon monoxide and dioxide instead, after an initial increase, show a nearly constant concentration at 1000°C. Furthermore, in regards to the elemental composition of the synthesis gas, as the temperature increases, the carbon content continuously decreases, while the oxygen content increases; the hydrogen, being the main component of the gas fraction and having a small atomic weight, is responsible for the progressive reduction of the gas density at higher temperature.

Energy recovery from sugarcane biomass residues: Challenges and opportunities of bio-oil production in the light of second generation biofuels

The lack of an alternative energy carrier to electricity with storage capability for use in off-season has to date been an unsolvable question for the sugar agroindustry. The improvement in cogeneration capacity via implementation of condensing extraction steam turbines or biomass integrated gasifier/gas turbine combined cycle and the barriers for their implementation were analyzed. The introduction of a fast pyrolysis (3 tons/h) module (FPM3) as a solution for off-season energy demand in the sugarcane agroindustry was also analyzed. The production cost of 1 ton of bio-oil for FPM3 condition was calculated at 87 USD/ton of bio-oil (0.104 USD/l of bio-oil). The economic feasibility of the FPM3 was estimated, comparing the added values for two alternatives: first alternative regarding the sugar and bioethanol simultaneous production (first generation biofuel production) and second alternative regarding the sugar and bio-oil simultaneous production (second generation biofuel production). Although the highest...

Cogeneration and Bio-Oil Production Starting from Sugarcane Biomass Residues: Barriers, Challenges and Opportunities

There are more than 70 sugar producer countries around the world. Most of them are underdeveloped and poor. Especially for the underdeveloped, 3 rd world, the sugarcane residues disposal has first order priority. The lack of an alternative energy carrier to electricity with storage capability for use in off-season has to date been an unsolvable question for the sugar agro-industry. The improvement of cogeneration capacity via implementation of more efficient cogeneration systems and the barriers for their implementation were analyzed. A techno-economic assessment was carried out regarding the three most probable scenarios of sugar producer countries today. The biomass availability and high investment costs continue to be the main barriers to overcome in order to produce Bio-oil starting from sugarcane biomass solid residues.

Pyrolysis of automotive shredder residue in a bench scale rotary kiln

Automotive shredder residue (ASR) can create difficulties when managing, with its production increasing. It is made of different type of plastics, foams, elastomers, wood, glasses and textiles. For this reason, it is complicated to dispose of in a cost effective way, while also respecting the stringent environmental restrictions. Among thermal treatments, pyrolysis seems to offer an environmentally attractive method for the treatment of ASR; it also allows for the recovery of valuable secondary materials/fuels such as pyrolysis oils, chars, and gas. While, there is a great deal of significant research on ASR pyrolysis, the literature on higher scale pyrolysis experiments is limited. To improve current literature, the aim of the study was to investigate the pyrolysis of ASR in a bench scale rotary kiln. The Italian ASR was separated by dry-sieving into two particle size fractions: d<30mm and d>30mm. Both the streams were grounded, pelletized and then pyrolyzed in a continuous bench scale rotary kiln at 450, 550 and 650°C. The mass flow rate of the ASR pellets was 200-350g/h and each test ran for about 4-5h. The produced char, pyrolysis oil and syngas were quantified to determine product distribution. They were thoroughly analyzed with regard to their chemical and physical properties. The results show how higher temperatures increase the pyrolysis gas yield (44wt% at 650°C) as well as its heating value. The low heating value (LHV) of syngas ranges between 18 and 26MJ/Nm3dry. The highest pyrolysis oil yield (33wt.%) was observed at 550°C and its LHV ranges between 12.5 and 14.5MJ/kg. Furthermore, only two out of the six produced chars respect the LHV limit set by the Italian environmental regulations for landfilling. The obtained results in terms of product distribution and their chemical-physical analyses provide useful information for plant scale-up.