Giuseppe Lamanna

Influence of PCL on mechanical properties and bioactivity of ZrO2-based hybrid coatings synthesized by sol–gel dip coating technique

The biological properties of medical implants can be enhanced through surface modifications such as to provide a firm attachment of the implant. In this study, organic-inorganic hybrid coatings have been synthesized via sol-gel dip coating. They consist of an inorganic ZrO2 matrix in which different amounts of poly(ε-caprolactone) have been entrapped to improve the mechanical properties of the films. The influence of the PCL amount on the microstructural, biological and mechanical properties of the coating has been investigated. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses have shown that the hybrids used for the coating are homogenous and totally amorphous materials; Fourier transform infrared spectroscopy (FT-IR) has demonstrated that hydrogen bonds arise between the organic and inorganic phases. SEM and atomic force microscopy (AFM) have highlighted the nanostructured nature of the film. SEM and EDS analyses, after soaking the samples in a simulated body fluid (SBF), have pointed out the apatite formation on the coating surface, which proves the bone-bonding ability of the nanocomposite bioactive films. Scratch and nano-indentation tests have shown that the coating hardness, stiffness and Youngs modulus decrease in the presence of large amounts of the organic phase.

Investigation of the sample preparation and curing treatment effects on mechanical properties and bioactivity of silica rich metakaolin geopolymer.

In many biomedical applications both the biological and mechanical behaviours of implants are of relevant interest; in the orthopaedic field, for example, favourable bioactivity and biocompatibility capabilities are necessary, but at the same time the mechanical characteristics of the implants must be such as to allow one to support the body weight. In the present work, the authors have examined the application of geopolymers with composition H24AlK7Si31O79 and ratio Si/Al=31 to be used in biomedical field, considering two different preparation methods: one of the activators (KOH) has been added as pellets in the potassium silicate solution, in the other as a water solution with 8M concentration. Moreover, a different water content was used and only some of the synthesized samples were heat treated. The chemical and microstructural characterizations of those materials have been carried out by Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM). Subsequently, the effects of the adopted preparation on the mechanical and biological properties have been studied: compressive strength tests have demonstrated that more fragile specimens were obtained when KOH was added as a solution. The bioactivity was successfully evaluated with the soaking of the samples in a simulated body fluid (SBF) for 3 weeks. The formation of a layer of hydroxyapatite on the surface of the materials has been shown both by SEM micrographs and EDS analyses.

Geopolymer/PEG Hybrid Materials Synthesis and Investigation of the Polymer Influence on Microstructure and Mechanical Behavior

Geopolymers are aluminosilicate inorganic polymers, obtained from the alkali activation of powders containing SiO2+Al2O3>80wt%, mainly proposed as environmentally friendly building materials. In this work, metakaolin-based geopolymers have been prepared and a water-soluble polymer, polyethylene glycol (PEG), has been added in different percentages to obtain organic-inorganic hybrid geopolymers. The influence of both the polymer amount and aging time on the structure and the mechanical behavior of the materials were investigated. FTIR spectroscopy allowed us to follow the evolution of the aluminosilicate framework during the geopolymerization process. This analysis revealed that PEG leads to a network which is rich in Al-O-Si bonds and forms H-bonds with the inorganic phase. SEM microscope showed that the two phases are interpenetrated on micrometric scales. Traction and bending tests have been carried out on appropriate samples to investigate the mechanical behavior of the obtained hybrids, showing that both PEG content and aging time affect the material behavior.

Numerical Procedures for Damage Mechanisms Analysis in CFRP Composites

Damage after impact often involves aeronautic structures. The aircraft can be involved in impacts during the assembly stage and operative life. Typical impacts can be related to falling tools, hailstones, debris on the take-off strip thrown against the aircraft by the rolling tyres, maintenance operations. There are two categories of damage impact: Low and High Velocity Impact (LVI, HVI). Damages coming from low velocity impacts are difficult to identify because they are often within the composite structure and the use of non-destructive testing, e.g. ultrasonic test, is not convenient. In order to prevent catastrophic events the designers must increase the safety margin and thereby the weight of the aircraft. The present study shows two different numerical procedures based on finite elements method to investigate on some damage mechanisms of a carbon fibre reinforced plastic (CFRP) structures (e.g. interface debonding, fibre or matrix cracking) and the residual strength of such structures under live loads.

Numerical simulation of LVI test onto composite plates

The aim of the proposed research activity is to investigate on the structural behaviour of laminated composite plates under low velocity impacts. Analytical closed-form methods are generally unable to describe simultaneously different composite failure modes, as well as experimental tests are unable to be applied to complex boundary conditions or component geometries. Within this work it is shown that numerical simulation appears a reliable tool to describe and forecast the damage onset and growth in composite components. A numerical procedure, based on explicit finite element methods, has been proposed and applied to the simulation of drop mass impacts on composite plates, by taking in account both intra-lamina and inter-laminates damages onset and propagation up to component failure. A global/local modelling approach has been employed to create the model and its validation has been performed by considering results from different sessions of experimental tests.

Tensile Testing of Hybrid Composite Joints

In the present paper, results of experimental tests carried out on hybrid (bonded/bolted) and adhesive composite single-lap joints are showed. The laminate adherends were made by unidirectional carbon fiber/epoxy with symmetric stacking sequence. In particular, the tests were carried out to evaluate strength and failure mode of the different joints. These joints were subjected to quasi-static tensile displacement and tests were conducted using a universal testing machine. The maximum tension load that the specimen can bear is determined and the failure process is correlated to the lay-up of the composite and joint type.

Geometrical Parameters Influencing a Hybrid Mechanical Coupling

Coupling techniques for components of different materials is spreading in mechanical industry; the test case studied in this work deals with the connection of an aluminium alloy component with a carbon fibre composite one. In particular, the first component is made of an aluminium-zinc alloy and exhibits an isotropic behaviour, while the second is made of a carbon fibre reinforced polymer (CFRP) and shows a strongly anisotropic behaviour; both materials are widely used in engineering applications. A titanium bolt connects the parts. This work is focused on the influence of the geometrical parameters which characterize the coupling between the components. In particular, a study has been carried out on the influence of the shank-hole clearance, the bolt head size, the bolt preload and the shape of the bolt head. A numerical model has been built and statically tested; the results have been compared with the experimental ones from literature. Once validated, the same numerical model has been used to evaluate the performance of the joint in presence of a change of the above mentioned characteristic parameters. The required numerical analyses have been performed using Abaqus/Standard® numerical code.

Effects of Tolerances on the Structural Behavior of a Bolted Hybrid Joint

In this work, results from a study on bolted joints made of unidirectional, quasi isotropic Carbon Fiber Reinforced Polymer (CFRP) composites, subjected to tensile loads, are reported. CFRP composite materials are widely used in the mechanical industry, such as that of aerospace, where requirements of weight reduction and structural high performances are very compelling. Composite materials generally present a high resistance to fatigue and corrosion; however, the presence of joints produces the major problems and a poor design of joints leads to a drastic reduction of the reliability of structures made of these materials. A hybrid bolted joint involving a metal plate, made of aluminum alloy, and a CFRP composite plate has been considered; the plates are held together by a titanium bolt. Experimental results from literature are compared with those obtained through a numerical analysis developed with Abaqus code. Once the CFRP composite has been analyzed and the numerical model validated through numerical-experimental correlations, other possible configurations have been numerically analyzed in order to ensure the highest strength of the examined hybrid joint. Afterwards the effects of bolt-hole clearance on the stiffness and strength of the same joint have been investigated.

Evaluation by FEM of the Influence of the Preheating and Post-Heating Treatments on Residual Stresses in Welding

During the last few years various experimental destructive and non-destructive methods were developed to evaluate residual stresses. However it is impossible to obtain a full residual stress distribution in welded structures by means of experimental methods. This disadvantage can be solved by means of computational analysis which allows to determine the whole stress and strain fields in complex structures. In this paper the temperature distribution and residual stresses were determined in a single-pass butt joint welded by GMAW (Gas Metal Arc Welding) process by finite element model (FEM). A 3D finite parametric element model has been carried out to analyze temperature distribution in butt weld joints and thermo-mechanical analyses were performed to evaluate resulting residual stresses. Temperature fields have been investigated by varying an initial preheating treatment. Moreover the technique of “element birth and death” was adopted to simulate the process of filler metal addition The high stresses were evaluated, with particular regard to fusion zone and heat affected zone. The influence of preheating and post-heating treatment on residual stresses was investigated. The residual stresses decrease when preheating temperature increases. The maximum value of longitudinal residual stresses without pre-heating can be reduced about 12% and 38% by using the preheating and post-heating process respectively.

Energy Absorption Capabilities of a Square Tube System

In the present paper the authors refer about a series of experimental tests, where an aluminium alloy square tube, filled with an aluminium foam, was crushed by a longitudinal load at a speed of 10 m/s. The test apparatus consisted of a sled installed on a very stiff frame moving on appropriate guides, as the specimen was set on a home-made fixture. Two arrangements of square tubes were considered as specimens: a “standard” one and an “optimized” one. Both crushing behaviours and energy absorption capabilities were analyzed experimentally and numerically simulated by means of the explicit FE code LS-DYNA®; the complete numerical model consisted of the striker, the assemblage of square tubes and the base. A high-speed video recording system was used to capture the images from the physical test. The results from the numerical analyses were compared to those obtained from the experiments: those results showed that the force–deflection response had been overestimated by the numerical model. The authors attempted to justify this inconsistency by considering the influence of the strain rate parameters of the considered Cowper-Symonds analytical model on the results. It was shown that the “optimized” energy absorber exhibited a more desirable force–deflection response than the standard one due to some easy design changes, which involved the insertion of aluminium foam dampers.