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Dive into the research topics where Glenn H. McGall is active.

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Featured researches published by Glenn H. McGall.


Journal of The Chemical Society, Chemical Communications | 1985

Reversible ring-opening in the hydrolysis of spirophosphoranes

Glenn H. McGall; Robert A. McClelland

The spirophosphorane (1b)(5-phenyloctamethyl-1,4,6,9-tetraoxa-5-phosphaspiro[4.4]nonane) undergoes acid-catalysed ligand exchange 107 times faster than acid-catalysed hydrolysis; these two processes have a common phosphonium ion intermediate which has a large preference for reaction with its internal hydroxy group over capture by an external water molecule.


Journal of The Chemical Society, Chemical Communications | 1982

Ligand rearrangement in a spirophosphorane via a catalysed dissociation–association mechanism

Glenn H. McGall; Robert A. McClelland

The spirobicyclic bisethlenedioxyphosphorane (1) undergoes ligand isomerization in the presence of methyl trifluoromethanesulphonate; this is an example of an irregular exchange involving a phosphonium ion intermediate.


Journal of Organic Chemistry | 1998

Proofing of Photolithographic DNA Synthesis with 3‘,5‘-Dimethoxybenzoinyloxycarbonyl-Protected Deoxynucleoside Phosphoramidites

Michael C. Pirrung; Lara Fallon; Glenn H. McGall


Journal of Organic Chemistry | 1982

Hydration of the flavylium ion. 2. The 4'-hydroxyflavylium ion

Robert A. McClelland; Glenn H. McGall


Journal of the American Chemical Society | 1990

Identification of the source of oxygen in the alkaline-labile product accompanying cytosine release druing bleomycin-mediated oxidative degradation of d(CGCGCG)

Lois E. Rabow; Glenn H. McGall; JoAnne Stubbe; John W. Kozarich


Journal of the American Chemical Society | 1987

Incorporation of 18O into glycolic acid obtained from the bleomycin-mediated degradation of DNA: evidence for 4'-radical trapping by 18O2

Glenn H. McGall; Lois E. Rabow; JoAnne Stubbe; John W. Kozarich


Journal of the American Chemical Society | 1985

Kinetics and mechanism of the hydrolysis of acyclic oxyphosphonium salts

Robert A. McClelland; Glenn H. McGall; Geeta Patel


Journal of the American Chemical Society | 1986

Equilibrium constants and rate constants for the transformations in aqueous solution of a spirocyclic hydroxyphosphorane.

Robert A. McClelland; David Cramm; Glenn H. McGall


Journal of Organic Chemistry | 1991

Acyl migration in the production of thymine. Propenal from 3'-O-benzoyl-5'-deoxy-4'-(hydroperoxy)thymidine: a reinterpretation of a putative model for bleomycin-mediated DNA degradation

Glenn H. McGall; JoAnne Stubbe; John W. Kozarich


Journal of the American Chemical Society | 1985

Oxyphosphorane hydrolysis. Reversible ring opening of spirophosphoranes containing six-atom rings

Glenn H. McGall; Robert A. McClelland

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JoAnne Stubbe

Massachusetts Institute of Technology

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Lois E. Rabow

University of Wisconsin-Madison

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